Ruthenium-Catalyzed C–H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles

Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.

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Bibliographic Details
Published inOrganic letters Vol. 14; no. 4; pp. 1154 - 1157
Main Authors Ackermann, Lutz, Diers, Emelyne, Manvar, Atul
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 17.02.2012
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
FUNCTIONALIZATION
SYSTEM
PRELIGANDS
PALLADIUM
ACTIVATION
PHENOLS
ARYL
PHOSPHINE OXIDES
BROMIDES
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Summary:Ruthenium-catalyzed direct arylations of phenols bearing removable directing groups were accomplished through carboxylate assistance via six-membered ruthenacycles as key intermediates.
Bibliography:ObjectType-Article-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol3000876