Parallel Synthesis of Terminal Alkynes Using a ROMPgel-Supported Ethyl 1-Diazo-2-oxopropylphosphonate

ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate has been prepared, and the supported reagent has been effectively employed in the conversion of a variety of aldehydes into terminal alkynes under mild reaction conditions. The influence of cross-link structure, comonomers, and polymer structure...

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Bibliographic Details
Published inOrganic letters Vol. 6; no. 5; pp. 835 - 837
Main Authors Barrett, Anthony G. M, Hopkins, Brian T, Love, Andrew C, Tedeschi, Livio
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 04.03.2004
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CARBONYL-COMPOUNDS
OLEFINS
POLYMERIZATION
REAGENTS
AMINES
RING
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Summary:ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate has been prepared, and the supported reagent has been effectively employed in the conversion of a variety of aldehydes into terminal alkynes under mild reaction conditions. The influence of cross-link structure, comonomers, and polymer structure on reaction efficiency has been examined.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol049915z