Appraisal of the Mass Spectrometry/Mass Spectrometry of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans Using New Data
A comprehensive set of data on the mass spectrometry/mass spectrometry (MS/MS) of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs and PCDFs) is presented.
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Published in | Environmental science & technology Vol. 29; no. 7; pp. 1741 - 1747 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
01.07.1995
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Subjects | |
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Abstract | A comprehensive set of data on the mass spectrometry/mass spectrometry (MS/MS) of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs and PCDFs) is presented. |
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AbstractList | A comprehensive set of data on the mass spectrometry/mass spectrometry (MS/MS) of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs and PCDFs) is presented. The optimization of mass spectrometry/mass spectrometry methods for the quantification of PCDDs and PCDFs was studied. New data were generated concerning the collision energy optima between PCDD and PCDF isomers, linearity and reproducibility of an analyte to an internal standard, and ion abundance ratios required for compound identification. Collision energy optima are not influenced by the number or position of chlorine atoms on the molecule. Analysis of 17 compounds shows that the response of an analyte to its isotopically-labeled internal standard is linear in the 2.5-1000 pg/ mu l range. |
Author | Marbury, G. Dean Green, William C Charles, M. Judith |
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Snippet | A comprehensive set of data on the mass spectrometry/mass spectrometry (MS/MS) of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDDs and PCDFs) is... The optimization of mass spectrometry/mass spectrometry methods for the quantification of PCDDs and PCDFs was studied. New data were generated concerning the... |
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SubjectTerms | Analytical chemistry Chemistry Dioxins Environmental monitoring Exact sciences and technology Mass spectrometry PCB Polychlorinated biphenyls Scientific imaging Sediments Spectrometric and optical methods |
Title | Appraisal of the Mass Spectrometry/Mass Spectrometry of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans Using New Data |
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