Recycled carbonates in the mantle sources of natural kamafugites; a zinc isotope perspective

• Published in: The American mineralogist Vol. 108; no. 5; pp. 987 - 998
• Main Authors: Ma Lei, Ma Lei, Liu Shengao, Liu Shengao, Zhao Zhidan, Zhao Zhidan, Yu Xuehui, Yu Xuehui
• Format: Journal Article
• Language: English
• Published: Washington Mineralogical Society of America 01.05.2023; Walter de Gruyter GmbH
• Subjects: Aluminum oxide; Asia; Carbon dioxide; Carbonates; Cenozoic; chain silicates; China; clinopyroxene; Correlation; diopside; Far East; framework silicates; geochemical cycle; Geochemistry; igneous and metamorphic rocks; igneous rocks; Isotopes; kamafugite; Kamafugites; leucite; magmas; magmatic differentiation; mantle; Melting; Melts; metals; Modelling; nepheline; nepheline group; Orogeny; oxides; Peridotite; perovskite; Petrology; plate tectonics; pyroxene group; Qinling Mountains; recycled carbonates; rich source; Silica; Silicates; Silicon dioxide; stable isotopes; subduction; Tracers; Volcanic rocks; West Qinling; Zinc; Zinc isotopes; Zn isotopes; Zn-66
• ISSN: 0003-004X; 1945-3027
• DOI: 10.2138/am-2022-8382

Kamafugites are strongly silica-undersaturated melts that are difficult to produce by partial melting of volatile-free peridotites but can be produced experimentally in the presence of CO2. Nevertheless, there is not yet direct evidence for a CO2-rich mantle source and the possible presence of recycled carbonates in the source of natural kamafugites. Marine carbonates have a heavier zinc isotopic composition (δ66Zn) than that of the mantle by up to 1.0 per mille, making zinc isotopes a sensitive tracer for recycled carbonates in the sources of mantle-derived magmas. Here we take Cenozoic kamafugites from the West Qinling orogen in China as an example to address the origin of this rare volcanic rock. The West Qinling kamafugites are strongly silica-undersaturated (SiO2 = 37.0 to 43.0 wt%) and have significantly higher δ66Zn (0.30 per mille to 0.47 per mille) than that of the normal mantle (0.18±0.05 per mille). No correlation δ66Zn and MgO or SiO2 contents is observed, indicating that δ66Zn was not a result of magmatic differentiation. Modeling of melting indicates that even at extremely low degree (∼0.5%), partial melting of a normal peridotitic source is still unlikely to produce silicate δ66Zn values exceeding 0.30 per mille. Thus, the elevated δ66Zn of the West Qinling kamafugites demonstrates the presence of recycled carbonates in their mantle sources. Binary-mixing modeling suggests that the source contains ∼5 to 15% recycled carbonates, which is supported by the positive correlation between 2D66Zn and CaO/Al2O3. Overall, the West Qinling kamafugites represent the products of low-degree partial melting of a recycled carbonate-bearing peridotite source, which provides evidence for an important role of recycled carbonates in the origin of natural kamafugite suites.