Meso-Substituted Corroles from Nitrosoalkenes and Dipyrromethanes

• Published in: Journal of organic chemistry Vol. 85; no. 5; pp. 3328 - 3335
• Main Authors: Lopes, Susana M. M, Pinho e Melo, Teresa M. V. D
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 06.03.2020; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; ELECTROCHEMISTRY; OXIDATION; ORGANIC-SYNTHESIS; COMPLEXES; AZOALKENES; PORPHYRIN; ON-WATER; DERIVATIVES; CANCER

The synthesis of bilanes and hexapyrroles containing an oxime functionality, prepared by two and three consecutive hetero-Diels–Alder reactions (or conjugated additions) between nitrosoalkenes and dipyrromethanes, is described. Bilanes underwent oxidative macrocyclization to afford a new class of tr...