Sequential extraction and single-step cold-acid extraction: A feasibility study for use with freshwater-canal sediments
This investigation examines metal release from freshwater sediment using sequential extraction and single-step cold-acid leaching. The concentrations of Cd, Cr, Cu, Fe, Ni, Pb and Zn released using a standard 3-step sequential extraction (Rauret et al., 1999) are compared to those released using a 0...
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Published in | Water, air, and soil pollution Vol. 170; no. 1-4; pp. 95 - 105 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
Springer
01.02.2006
Springer Nature B.V |
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Abstract | This investigation examines metal release from freshwater sediment using sequential extraction and single-step cold-acid leaching. The concentrations of Cd, Cr, Cu, Fe, Ni, Pb and Zn released using a standard 3-step sequential extraction (Rauret et al., 1999) are compared to those released using a 0.5 M HCl; leach. The results show that the three sediments behave in very different ways when subject to the same leaching experiments: the cold-acid extraction appears to remove higher relative concentrations of metals from the iron-rich sediment than from the other two sediments. Cold-acid extraction appears to be more effective at removing metals from sediments with crystalline iron oxides than the “reducible” step of the sequential extraction. The results show that a single-step acid leach can be just as effective as sequential extractions at removing metals from sediment and are a great deal less time-consuming. |
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AbstractList | This investigation examines metal release from freshwater sediment using sequential extraction and single-step cold-acid leaching. The concentrations of Cd, Cr, Cu, Fe, Ni, Pb and Zn released using a standard 3-step sequential extraction (Rauret et al., 1999) are compared to those released using a 0.5 M HCl; leach. The results show that the three sediments behave in very different ways when subject to the same leaching experiments: the cold-acid extraction appears to remove higher relative concentrations of metals from the iron-rich sediment than from the other two sediments. Cold-acid extraction appears to be more effective at removing metals from sediments with crystalline iron oxides than the "reducible" step of the sequential extraction. The results show that a single-step acid leach can be just as effective as sequential extractions at removing metals from sediment and are a great deal less time-consuming. This investigation examines metal release from freshwater sediment using sequential extraction and single-step cold-acid leaching. The concentrations of Cd, Cr, Cu, Fe, Ni, Pb and Zn released using a standard 3-step sequential extraction (Rauret et al., 1999) are compared to those released using a 0.5 M HCl; leach. The results show that the three sediments behave in very different ways when subject to the same leaching experiments: the cold-acid extraction appears to remove higher relative concentrations of metals from the iron-rich sediment than from the other two sediments. Cold-acid extraction appears to be more effective at removing metals from sediments with crystalline iron oxides than the "reducible" step of the sequential extraction. The results show that a single-step acid leach can be just as effective as sequential extractions at removing metals from sediment and are a great deal less time-consuming.[PUBLICATION ABSTRACT] |
Author | Cook, S.R Parker, A |
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Cites_doi | 10.1039/a807854h 10.1039/an9760100761 10.1016/0375-6742(95)00050-X 10.1021/es001033h 10.1021/ac50043a017 10.1021/es9913030 10.1016/S0269-7491(00)00231-1 10.1021/es970415t 10.1021/es049212c 10.1016/S0165-9936(03)00303-0 10.1016/0269-7491(95)00049-6 10.1039/a705163h 10.1016/S0883-2927(01)00095-6 10.1021/es60126a007 10.1080/03067319508041330 |
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Keywords | Sediment water interaction Canal Surface water Sequential extraction Acid leaching metals Water pollution Measurement method leaching sediment Heavy metal |
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SubjectTerms | Acids Analysis methods Applied sciences Cadmium Chromium Cold Crystal structure Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Environmental monitoring Exact sciences and technology Extraction Feasibility studies France Heavy metals Iron oxides Leaching Lead (metal) Metal concentrations Metals methodology Natural water pollution Pollution Pollution, environment geology sediment contamination Sediments Soil and sediments pollution Soil pollution United Kingdom Water treatment and pollution |
Title | Sequential extraction and single-step cold-acid extraction: A feasibility study for use with freshwater-canal sediments |
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