Retention and Transport of Nitrate and Ammonium in Loamy Sand Amended with Clinoptilolite Zeolite

AbstractAgricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large amounts of N to shallow groundwater. Adsorption and leaching experiments were conducted to investigate the use of clinoptilolite zeolite (CZ)...

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Published inJournal of irrigation and drainage engineering Vol. 139; no. 9; pp. 755 - 765
Main Authors Piñón-Villarreal, Aldo R, Bawazir, A. Salim, Shukla, Manoj K, Hanson, Adrian T
Format Journal Article
LanguageEnglish
Published Reston, VA American Society of Civil Engineers 01.09.2013
Subjects
Agricultural and forest climatology and meteorology. Irrigation. Drainage
Agronomy. Soil science and plant productions
Biological and medical sciences
Fundamental and applied biological sciences. Psychology
General agronomy. Plant production
Irrigation. Drainage
Technical Papers
United States
New Mexico
North America
America
USA, New Mexico
Irrigation
Ammonium
Nitrate leaching
Sand
Retardation
Soil amendment
Anion exclusion
Solutes
Sand (soil type)
Amendment
Anions
Urea-ammonium-nitrate (UAN 32)
Clinoptilolite zeolite
Soil types
Agriculture
Underground leaching
Zeolite
Nitrogen
Ammonium-nitrogen
Soil management
Nitrate
Adsorption
Solute transport
New Mexico
Clinoptilolite
Ammonium nitrate
Nitrate-nitrogen
Water pollution
Loamy sand soil
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Abstract AbstractAgricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large amounts of N to shallow groundwater. Adsorption and leaching experiments were conducted to investigate the use of clinoptilolite zeolite (CZ) as an amendment to sandy soils to increase N retention and reduce nitrate (NO3−) leaching. Urea-ammonium-nitrate (UAN 32) fertilizer was applied to four soil treatments to simulate crop irrigation. The treatments were composed of 100% CZ, 100% loamy sand (LS), a mixture of 80∶20% (LS:CZ), and a mixture 60∶40% (LS:CZ) by mass, respectively. Results from the experiments showed an inverse relationship between nitrate-nitrogen (NO3−-N) adsorption and the amount of CZ added to soil caused by anion exclusion and a direct relationship between ammonium-nitrogen (NH4+-N) adsorption and the amount of CZ mixed with LS due to NH4+-N entrapment by the CZ molecules. It is therefore recommended to use other types of fertilizers that do not include NO3– to LS soils amended with CZ in order to reduce the risk of leaching. Otherwise, it is suggested to apply fertilizers containing ammonium nitrate in LS soils amended with CZ at reduced rates but at higher frequencies to meet plant demands.
AbstractList AbstractAgricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large amounts of N to shallow groundwater. Adsorption and leaching experiments were conducted to investigate the use of clinoptilolite zeolite (CZ) as an amendment to sandy soils to increase N retention and reduce nitrate (NO3−) leaching. Urea-ammonium-nitrate (UAN 32) fertilizer was applied to four soil treatments to simulate crop irrigation. The treatments were composed of 100% CZ, 100% loamy sand (LS), a mixture of 80∶20% (LS:CZ), and a mixture 60∶40% (LS:CZ) by mass, respectively. Results from the experiments showed an inverse relationship between nitrate-nitrogen (NO3−-N) adsorption and the amount of CZ added to soil caused by anion exclusion and a direct relationship between ammonium-nitrogen (NH4+-N) adsorption and the amount of CZ mixed with LS due to NH4+-N entrapment by the CZ molecules. It is therefore recommended to use other types of fertilizers that do not include NO3– to LS soils amended with CZ in order to reduce the risk of leaching. Otherwise, it is suggested to apply fertilizers containing ammonium nitrate in LS soils amended with CZ at reduced rates but at higher frequencies to meet plant demands.
Agricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large amounts of N to shallow groundwater. Adsorption and leaching experiments were conducted to investigate the use of clinoptilolite zeolite (CZ) as an amendment to sandy soils to increase N retention and reduce nitrate (NO3-) leaching. Urea-ammonium-nitrate (UAN registered 32) fertilizer was applied to four soil treatments to simulate crop irrigation. The treatments were composed of 100% CZ, 100% loamy sand (LS), a mixture of 80%:20% (LS:CZ), and a mixture 60%:40% (LS:CZ) by mass, respectively. Results from the experiments showed an inverse relationship between nitrate-nitrogen (NC3--N) adsorption and the amount of CZ added to soil caused by anion exclusion, and a direct relationship between ammonium-nitrogen (NH4+-N) adsorption and the amount of CZ mixed with LS due to NH4+-N entrapment by the CZ molecules. It is therefore recommended to use other types of fertilizers that do not include NO3- to LS soils amended with CZ in order to reduce the risk of leaching. Otherwise, it is suggested to apply fertilizers containing ammonium nitrate in LS soils amended with CZ at reduced rates but at higher frequencies to meet plant demands.
Author Hanson, Adrian T
Piñón-Villarreal, Aldo R
Shukla, Manoj K
Bawazir, A. Salim
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  organization: New Mexico State Univ. Professor, Dept. of Civil Engineering, , MSC 3CE, PO Box 30001, Las Cruces, NM 88003-0083. E-mail
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Issue 9
Keywords Irrigation
Ammonium
Nitrate leaching
Sand
Retardation
Soil amendment
Anion exclusion
Solutes
Sand (soil type)
Amendment
Anions
Urea-ammonium-nitrate (UAN 32)
Clinoptilolite zeolite
Soil types
Agriculture
Underground leaching
Zeolite
Nitrogen
Ammonium-nitrogen
Soil management
Nitrate
Adsorption
Solute transport
New Mexico
Clinoptilolite
Ammonium nitrate
Nitrate-nitrogen
Water pollution
Loamy sand soil
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Snippet AbstractAgricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large...
Agricultural soils of southern New Mexico, especially sand and sandy loams receiving numerous nitrogen (N) fertilizations, are prone to leaching large amounts...
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SubjectTerms Agricultural and forest climatology and meteorology. Irrigation. Drainage
Agronomy. Soil science and plant productions
Biological and medical sciences
Fundamental and applied biological sciences. Psychology
General agronomy. Plant production
Irrigation. Drainage
Technical Papers
Title Retention and Transport of Nitrate and Ammonium in Loamy Sand Amended with Clinoptilolite Zeolite
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