Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States

Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. T...

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Published inACS applied materials & interfaces Vol. 12; no. 1; pp. 914 - 924
Main Authors Gualdrón-Reyes, Andrés F, Rodríguez-Pereira, Jhonatan, Amado-González, Eliseo, Rueda-P, Jorge, Ospina, Rogelio, Masi, Sofia, Yoon, Seog Joon, Tirado, Juan, Jaramillo, Franklin, Agouram, Said, Muñoz-Sanjosé, Vicente, Giménez, Sixto, Mora-Seró, Iván
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 08.01.2020
Subjects
hot-injection
degradation pathways
photocatalytic activity
superoxide ions
iodide vacancies
anion-exchange
surface chemical states
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Abstract Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. This feature has drawn the attention of analogous hot topics as photocatalysis for carrying out more efficiently the degradation of organic compounds. However, the photo-oxidation ability of perovskite depends not only on its excellent light-harvesting properties but also on the surface chemical environment provided during its synthesis. Accordingly, we studied the role of surface chemical states of MHP-based nanocrystals (NCs) synthesized by hot-injection (H-I) and anion-exchange (A-E) approaches on their photocatalytic (PC) activity for the oxidation of β-naphthol as a model system. We concluded that iodide vacancies are the main surface chemical states that facilitate the formation of superoxide ions, O2 ●–, which are responsible for the PC activity in A-E-MHP. Conversely, the PC performance of H-I-MHP is related to the appropriate balance between band gap and a highly oxidizing valence band. This work offers new insights on the surface properties of MHP related to their catalytic activity in photochemical applications.
AbstractList Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. This feature has drawn the attention of analogous hot topics as photocatalysis for carrying out more efficiently the degradation of organic compounds. However, the photo-oxidation ability of perovskite depends not only on its excellent light-harvesting properties but also on the surface chemical environment provided during its synthesis. Accordingly, we studied the role of surface chemical states of MHP-based nanocrystals (NCs) synthesized by hot-injection (H-I) and anion-exchange (A-E) approaches on their photocatalytic (PC) activity for the oxidation of β-naphthol as a model system. We concluded that iodide vacancies are the main surface chemical states that facilitate the formation of superoxide ions, O , which are responsible for the PC activity in A-E-MHP. Conversely, the PC performance of H-I-MHP is related to the appropriate balance between band gap and a highly oxidizing valence band. This work offers new insights on the surface properties of MHP related to their catalytic activity in photochemical applications.
Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of their optoelectronic properties, balancing both the light-harvesting efficiency and the charge extraction into highly efficient solar devices. This feature has drawn the attention of analogous hot topics as photocatalysis for carrying out more efficiently the degradation of organic compounds. However, the photo-oxidation ability of perovskite depends not only on its excellent light-harvesting properties but also on the surface chemical environment provided during its synthesis. Accordingly, we studied the role of surface chemical states of MHP-based nanocrystals (NCs) synthesized by hot-injection (H-I) and anion-exchange (A-E) approaches on their photocatalytic (PC) activity for the oxidation of β-naphthol as a model system. We concluded that iodide vacancies are the main surface chemical states that facilitate the formation of superoxide ions, O2 ●–, which are responsible for the PC activity in A-E-MHP. Conversely, the PC performance of H-I-MHP is related to the appropriate balance between band gap and a highly oxidizing valence band. This work offers new insights on the surface properties of MHP related to their catalytic activity in photochemical applications.
Author Jaramillo, Franklin
Tirado, Juan
Agouram, Said
Yoon, Seog Joon
Muñoz-Sanjosé, Vicente
Amado-González, Eliseo
Gualdrón-Reyes, Andrés F
Masi, Sofia
Rodríguez-Pereira, Jhonatan
Giménez, Sixto
Rueda-P, Jorge
Mora-Seró, Iván
Ospina, Rogelio
AuthorAffiliation Materials for Renewable Energy (MAER)
Unitat Mixta d’Investigació UV-UJI
Department of Chemistry, College of Natural Science
Department of Applied Physics and Electromagnetism
Laboratorio de Biocombustibles Lab-IBEAR, Facultad de Ciencias Básicas
Centro de Investigación, Innovación y Desarrollo de Materiales CIDEMAT
University of Valencia (UV)
Universidad de Pamplona
Institute of Advanced Materials (INAM)
Centro de Investigación Científica y Tecnológica en Materiales y Nanociencias (CMN)
Grupo de Óptica Moderna, Facultad de Ciencias Básicas
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  email: sero@uji.es
  organization: Unitat Mixta d’Investigació UV-UJI
BackLink https://www.ncbi.nlm.nih.gov/pubmed/31805231$$D View this record in MEDLINE/PubMed
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Keywords hot-injection
degradation pathways
photocatalytic activity
superoxide ions
iodide vacancies
anion-exchange
surface chemical states
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Snippet Within the most mesmerizing materials in the world of optoelectronics, mixed halide perovskites (MHPs) have been distinguished because of the tunability of...
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Title Unravelling the Photocatalytic Behavior of All-Inorganic Mixed Halide Perovskites: The Role of Surface Chemical States
URI http://dx.doi.org/10.1021/acsami.9b19374
https://www.ncbi.nlm.nih.gov/pubmed/31805231
https://search.proquest.com/docview/2322711175
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