Incorporating Photochromic Triphenylamine into a Zirconium–Organic Framework for Highly Effective Photocatalytic Aerobic Oxidation of Sulfides

• Published in: ACS applied materials & interfaces Vol. 13; no. 17; pp. 20137 - 20144
• Main Authors: Zou, Xin-Nan, Zhang, Deshan, Luan, Tian-Xiang, Li, Qiang, Li, Lei, Li, Pei-Zhou, Zhao, Yanli
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 05.05.2021
• Subjects: air; blue light; coordination polymers; Energy, Environmental, and Catalysis Applications; irradiation; ligands; methanol; nerve agents; oxidants; oxidation; oxygen; photocatalysis; photocatalysts; sulfides; aerobic oxidation; triphenylamine; photocatalysis; metal−organic frameworks; sulfides
• ISSN: 1944-8244; 1944-8252; 1944-8252
• DOI: 10.1021/acsami.1c03083

A zirconium-based metal–organic framework (MOF) was successfully constructed via solvothermal assembly of a triphenylamine-based tricarboxylate ligand and Zr­(IV) salt, the structure simulation of which revealed that it possesses a two-dimensional layered framework with a relatively rare dodecnuclea...