Synthesis of Sub-10 nm Two-Dimensional Covalent Organic Thin Film with Sharp Molecular Sieving Nanofiltration

We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water...

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Published inACS applied materials & interfaces Vol. 10; no. 15; pp. 12295 - 12299
Main Authors Gadwal, Ikhlas, Sheng, Guan, Thankamony, Roshni Lilly, Liu, Yang, Li, Huifang, Lai, Zhiping
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 18.04.2018
Subjects
air
atomic force microscopy
desalination
imines
light microscopy
magnesium sulfate
materials science
molecular weight
nanofiltration
porosity
scanning electron microscopy
seawater
sieving
sodium chloride
transmission electron microscopy
imine bond
Langmuir−Blodgett
separation
two-dimensional (2D) membranes
nanofiltration
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Abstract We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir–Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO4, respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.
AbstractList We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir–Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO4, respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.
We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir–Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO₄, respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.
We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir-Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO , respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.
We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir-Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO4, respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic and substituted heptacyclic truxene based triamine and a simple dialdehyde as building blocks by dynamic imine bond formation at the air/water interface using Langmuir-Blodgett (LB) method. Optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM), all unanimously showed the formation of large, molecularly thin and free-standing membrane that can be easily transferred on different substrate surfaces. The 2D membrane supported on a porous polysulfone showed a rejection rate of 64 and 71% for NaCl and MgSO4, respectively, and a clear molecular sieving at molecular size around 1.3 nm, which demonstrated a great potential in the application of pretreatment of seawater desalination and separation of organic molecules.
Author Sheng, Guan
Liu, Yang
Li, Huifang
Gadwal, Ikhlas
Lai, Zhiping
Thankamony, Roshni Lilly
AuthorAffiliation King Abdullah University of Science and Technology
Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering
AuthorAffiliation_xml – name: King Abdullah University of Science and Technology
– name: Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering
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  givenname: Ikhlas
  surname: Gadwal
  fullname: Gadwal, Ikhlas
– sequence: 2
  givenname: Guan
  surname: Sheng
  fullname: Sheng, Guan
– sequence: 3
  givenname: Roshni Lilly
  surname: Thankamony
  fullname: Thankamony, Roshni Lilly
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  givenname: Yang
  orcidid: 0000-0003-4313-0932
  surname: Liu
  fullname: Liu, Yang
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  givenname: Huifang
  surname: Li
  fullname: Li, Huifang
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  givenname: Zhiping
  orcidid: 0000-0001-9555-6009
  surname: Lai
  fullname: Lai, Zhiping
  email: zhiping.lai@kaust.edu.sa
BackLink https://www.ncbi.nlm.nih.gov/pubmed/29620857$$D View this record in MEDLINE/PubMed
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Cites_doi 10.1021/ar500037v
10.1021/ja408121p
10.1039/C5CC10221A
10.1002/anie.201506048
10.1039/C4RA11559G
10.1002/smll.201002264
10.1021/ja403464h
10.1021/acsnano.5b00184
10.1002/anie.201100669
10.1002/anie.200801863
10.1002/anie.201508473
10.1038/nchem.2007
10.1021/cr500006j
10.1039/C4CC05665E
10.1021/ja408243n
10.1038/nchem.1628
10.1038/nchem.2008
10.1038/nchem.695
10.1039/C5CC04679C
10.1038/nchem.1265
10.1021/ja512018j
10.1039/C2CE26394G
10.1002/anie.201308896
10.1002/adma.201304705
10.1021/ja510788b
10.1021/acsnano.7b06871
10.1146/annurev.pc.41.100190.002301
10.1039/C2CS35072F
10.1021/ja409421d
10.1126/science.1254227
10.1039/C4PY01383B
10.1016/j.desal.2004.05.001
10.1002/adma.201401857
10.1039/c1cc12510a
10.1080/15583724.2014.963235
10.1039/C5CC07381B
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References ref9/cit9
ref6/cit6
ref36/cit36
ref3/cit3
ref27/cit27
ref18/cit18
ref11/cit11
ref25/cit25
ref16/cit16
ref29/cit29
ref32/cit32
ref23/cit23
ref14/cit14
ref8/cit8
ref5/cit5
ref31/cit31
ref2/cit2
ref34/cit34
ref28/cit28
ref20/cit20
ref17/cit17
ref10/cit10
ref26/cit26
ref35/cit35
ref19/cit19
ref21/cit21
ref12/cit12
ref15/cit15
ref22/cit22
ref13/cit13
ref33/cit33
ref4/cit4
ref30/cit30
ref1/cit1
ref24/cit24
ref7/cit7
References_xml – ident: ref29/cit29
  doi: 10.1021/ar500037v
– ident: ref19/cit19
  doi: 10.1021/ja408121p
– ident: ref35/cit35
  doi: 10.1039/C5CC10221A
– ident: ref26/cit26
  doi: 10.1002/anie.201506048
– ident: ref27/cit27
  doi: 10.1039/C4RA11559G
– ident: ref18/cit18
  doi: 10.1002/smll.201002264
– ident: ref32/cit32
  doi: 10.1021/ja403464h
– ident: ref4/cit4
  doi: 10.1021/acsnano.5b00184
– ident: ref25/cit25
  doi: 10.1002/anie.201100669
– ident: ref13/cit13
  doi: 10.1002/anie.200801863
– ident: ref31/cit31
  doi: 10.1002/anie.201508473
– ident: ref16/cit16
  doi: 10.1038/nchem.2007
– ident: ref28/cit28
  doi: 10.1021/cr500006j
– ident: ref7/cit7
  doi: 10.1039/C4CC05665E
– ident: ref20/cit20
  doi: 10.1021/ja408243n
– ident: ref3/cit3
  doi: 10.1038/nchem.1628
– ident: ref17/cit17
  doi: 10.1038/nchem.2008
– ident: ref6/cit6
  doi: 10.1038/nchem.695
– ident: ref8/cit8
  doi: 10.1039/C5CC04679C
– ident: ref15/cit15
  doi: 10.1038/nchem.1265
– ident: ref24/cit24
  doi: 10.1021/ja512018j
– ident: ref30/cit30
  doi: 10.1039/C2CE26394G
– ident: ref1/cit1
  doi: 10.1002/anie.201308896
– ident: ref23/cit23
  doi: 10.1002/adma.201304705
– ident: ref12/cit12
  doi: 10.1021/ja510788b
– ident: ref33/cit33
  doi: 10.1021/acsnano.7b06871
– ident: ref34/cit34
  doi: 10.1146/annurev.pc.41.100190.002301
– ident: ref2/cit2
  doi: 10.1039/C2CS35072F
– ident: ref5/cit5
  doi: 10.1021/ja409421d
– ident: ref22/cit22
  doi: 10.1126/science.1254227
– ident: ref11/cit11
  doi: 10.1039/C4PY01383B
– ident: ref36/cit36
  doi: 10.1016/j.desal.2004.05.001
– ident: ref9/cit9
  doi: 10.1002/adma.201401857
– ident: ref21/cit21
  doi: 10.1039/c1cc12510a
– ident: ref10/cit10
  doi: 10.1080/15583724.2014.963235
– ident: ref14/cit14
  doi: 10.1039/C5CC07381B
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Snippet We demonstrated here a novel and facile synthesis of two-dimensional (2D) covalent organic thin film with pore size around 1.5 nm using a planar, amphiphilic...
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SubjectTerms air
atomic force microscopy
desalination
imines
light microscopy
magnesium sulfate
materials science
molecular weight
nanofiltration
porosity
scanning electron microscopy
seawater
sieving
sodium chloride
transmission electron microscopy
Title Synthesis of Sub-10 nm Two-Dimensional Covalent Organic Thin Film with Sharp Molecular Sieving Nanofiltration
URI http://dx.doi.org/10.1021/acsami.7b19450
https://www.ncbi.nlm.nih.gov/pubmed/29620857
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