Hydrogen Spillover Accelerates Electrocatalytic Semi-hydrogenation of Acetylene in Membrane Electrode Assembly Reactor

Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical de...

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Published inACS applied materials & interfaces Vol. 16; no. 7; pp. 8668 - 8678
Main Authors Lv, Xue-Hui, Huang, Huan, Cui, Li-Ting, Zhou, Zhi-You, Wu, Wenkun, Wang, Yu-Cheng, Sun, Shi-Gang
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 21.02.2024
Subjects
acetylene
alloys
catalysts
economic feasibility
economic sustainability
electrodes
Energy, Environmental, and Catalysis Applications
feedstocks
hydrogen
hydrogenation
Raman spectroscopy
synthesis
PdCu alloy catalysts
hydrogen spillover
semi-hydrogenation of acetylene
electrochemical synthesis
membrane electrode assembly reactor
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Abstract Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm−2 in a zero-gap membrane electrode assembly (MEA) reactor, with the C2H4 selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C2H4 production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.
AbstractList Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C₂H₄, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm⁻² in a zero-gap membrane electrode assembly (MEA) reactor, with the C₂H₄ selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C₂H₄ production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.
Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C H , a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm in a zero-gap membrane electrode assembly (MEA) reactor, with the C H selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C H production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.
Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm-2 in a zero-gap membrane electrode assembly (MEA) reactor, with the C2H4 selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C2H4 production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm-2 in a zero-gap membrane electrode assembly (MEA) reactor, with the C2H4 selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C2H4 production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.
Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used petrochemical feedstock. While the economic feasibility of this route has been demonstrated in three-electrode systems, its viability in practical device remains unverified. In this study, we designed a highly efficient electrocatalyst based on a PdCu alloy system utilizing the hydrogen spillover mechanism. The catalyst achieved an operational current density of 600 mA cm−2 in a zero-gap membrane electrode assembly (MEA) reactor, with the C2H4 selectivity exceeding 85%. This data confirms the economic feasibility of EASH in real-world applications. Furthermore, through in situ Raman spectroscopy and theoretical calculations, we elucidated the catalytic mechanism involving interfacial hydrogen spillover. Our findings underscore the economic viability and potential of EASH as a greener and scalable approach for C2H4 production, thus advancing the field of electrocatalysis in sustainable chemical synthesis.
Author Lv, Xue-Hui
Zhou, Zhi-You
Huang, Huan
Cui, Li-Ting
Wang, Yu-Cheng
Wu, Wenkun
Sun, Shi-Gang
AuthorAffiliation Chinese Academy of Sciences
Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM)
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics
Department of Materials Science and Engineering
College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces
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hydrogen spillover
semi-hydrogenation of acetylene
electrochemical synthesis
membrane electrode assembly reactor
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Snippet Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C2H4, a widely used...
Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C H , a widely used...
Electrocatalytic acetylene semi-hydrogenation (EASH) offers a promising and environmentally friendly pathway for the production of C₂H₄, a widely used...
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SubjectTerms acetylene
alloys
catalysts
economic feasibility
economic sustainability
electrodes
Energy, Environmental, and Catalysis Applications
feedstocks
hydrogen
hydrogenation
Raman spectroscopy
synthesis
Title Hydrogen Spillover Accelerates Electrocatalytic Semi-hydrogenation of Acetylene in Membrane Electrode Assembly Reactor
URI http://dx.doi.org/10.1021/acsami.3c15925
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