Kinetic Modeling of the Heterogeneously Catalyzed Oxidation of Propene to Acrolein in a Catalytic Wall Reactor

• Published in: Industrial & engineering chemistry research Vol. 42; no. 22; pp. 5482 - 5488
• Main Authors: Redlingshöfer, Hubert, Fischer, Achim, Weckbecker, Christoph, Huthmacher, Klaus, Emig, Gerhard
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 29.10.2003
• Subjects: Applied sciences; Catalysis; Catalytic reactions; Chemical engineering; Chemistry; Exact sciences and technology; General and physical chemistry; Reactors; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Parameter estimation; Catalytic reaction; Catalytic reactor; Modeling; Acrolein; Propene; Statistical parameter; Water content; Oxidation; Kinetics; Kinetic parameter; Activation energy; Catalyst

Using data from isothermal investigations in a catalytic wall reactor (Redlingshöfer, H.; Kröcher, O.; Böck, W.; Huthmacher, K.; Emig, G. Ind. Eng. Chem. Res. 2002, 41, 1445), the kinetics of the highly exothermic vapor-phase oxidation of propene was determined by statistical parameter estimation. I...