The [2+1] Cycloadditions of Dichlorocarbene, Silylene, Germylene, and Oxycarbonylnitrene onto the Sidewall of Armchair (5,5) Single-Wall Carbon Nanotube

• Published in: The journal of physical chemistry. B Vol. 107; no. 33; pp. 8388 - 8391
• Main Authors: Lu, Xin, Tian, Feng, Zhang, Qianer
• Format: Journal Article
• Language: English
• Published: American Chemical Society 21.08.2003

The [2+1] cycloadditions of dichlorocarbene, silylene, germylene, and oxycarbonylnitrene onto the sidewall of an armchair (5,5) single-wall carbon nanotube (SWNT) have been investigated by means of a two-layered ONIOM (MO:MO) approach. It is shown that (i) the [2+1] cycloaddition on the nanotube sid...