Polymerization of Ethylene Terephthalate Cyclic Oligomers with a Cyclic Dibutyltin Initiator

To produce high-performance poly(ethylene terephthalate) (PET) composites from the polymerization of ethylene terephthalate cyclic oligomers (ETCs) prepared from PET waste, the viscosity, thermal stability, and crystallization of ETC melts were investigated, and ETC melt was polymerized with cyclic...

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Published inMacromolecules Vol. 33; no. 10; pp. 3600 - 3605
Main Authors Youk, Ji Ho, Boulares, Alya, Kambour, Roger P, MacKnight, William J
Format Journal Article
LanguageEnglish
Published American Chemical Society 16.05.2000
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Abstract To produce high-performance poly(ethylene terephthalate) (PET) composites from the polymerization of ethylene terephthalate cyclic oligomers (ETCs) prepared from PET waste, the viscosity, thermal stability, and crystallization of ETC melts were investigated, and ETC melt was polymerized with cyclic dibutyltin initiator (cyclic stannoxane 1). The melt viscosity of ETCs at 295 °C where all ETCs can be melted was about 30 cP initially. The viscosity of the completely molten ETCs remained sufficiently constant at 295 °C to allow time for infusion into large composite preforms, and nearly all of the ETC molten sample remains a liquid for tens of seconds when quenched to the most desirable polymerization/solidification temperature. From the polymerization and crystallization results, it was found that the optimum polymerization temperature is approximately 230 °C. PET polymerized at this temperature had enough crystallinity for a good composite matrix; however, the molecular weights of such PETs were too low to form sufficiently strong tough matrices for composites; this is probably due to small amounts of impurities which produce low molecular weight PET and inadequate thermal stability of the cyclic stannoxane 1 initiator at this temperature.
AbstractList To produce high-performance poly(ethylene terephthalate) (PET) composites from the polymerization of ethylene terephthalate cyclic oligomers (ETCs) prepared from PET waste, the viscosity, thermal stability, and crystallization of ETC melts were investigated, and ETC melt was polymerized with cyclic dibutyltin initiator (cyclic stannoxane 1). The melt viscosity of ETCs at 295 °C where all ETCs can be melted was about 30 cP initially. The viscosity of the completely molten ETCs remained sufficiently constant at 295 °C to allow time for infusion into large composite preforms, and nearly all of the ETC molten sample remains a liquid for tens of seconds when quenched to the most desirable polymerization/solidification temperature. From the polymerization and crystallization results, it was found that the optimum polymerization temperature is approximately 230 °C. PET polymerized at this temperature had enough crystallinity for a good composite matrix; however, the molecular weights of such PETs were too low to form sufficiently strong tough matrices for composites; this is probably due to small amounts of impurities which produce low molecular weight PET and inadequate thermal stability of the cyclic stannoxane 1 initiator at this temperature.
To produce high-performance poly(ethylene terephthalate) (PET) composites from the polymerization of ethylene terephthalate cyclic oligomers (ETCs) prepared from PET waste, the viscosity, thermal stability, and crystallization of ETC melts were investigated, and ETC melt was polymerized with cyclic dibutyltin initiator (cyclic stannoxane 1). The melt viscosity of ETCs at 295 deg C where all ETCs can be melted was about 30 cP initially. The viscosity of the completely molten ETCs remained sufficiently constant at 296 deg C to allow time for infusion into large composite preforms, and nearly all of the ETC molten sample remains a liquid for tens of seconds when quenched to the most desirable polymerization/solidification temperature. From the polymerization and crystallization results, it was found that the optimum polymerization temperature is approximately 230 deg C. PET polymerized at this temperature had enough crystallinity for a good composite matrix; however, the molecular weights of such PETs were too low to form sufficiently strong tough matrices for composites; this is probably due to small amounts of impurities which produce low molecular weight PET and inadequate thermal stability of the cyclic stannoxane 1 initiator at this temperature.
Author Boulares, Alya
MacKnight, William J
Youk, Ji Ho
Kambour, Roger P
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Cites_doi 10.1016/S0022-328X(00)93372-2
10.1021/ma00140a051
10.1002/app.1962.070062414
10.1002/pol.1960.1204815042
10.1016/0032-3861(60)90048-3
10.1002/app.1984.070291264
10.1002/macp.1962.020570101
10.1021/ma971491j
10.1021/ma971275a
10.1021/ma00063a014
10.1016/S0022-328X(00)94164-0
10.1016/S0022-328X(00)80364-2
10.1002/(SICI)1097-4628(19971219)66:12<2251::AID-APP6>3.0.CO;2-F
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This paper is dedicated to Dr. Karel Dusek on the occasion of his 65th birthday.
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References Kricheldorf H. R. (ma9918396b00027/ma9918396b00027_1) 1988; 21
Hubbard P. (ma9918396b00009/ma9918396b00009_1) 1996; 29
Bryant J. J. L. (ma9918396b00011/ma9918396b00011_1) 1997; 38
Goodman I. (ma9918396b00023/ma9918396b00023_1) 1960; 1
Kricheldorf H. R. (ma9918396b00029/ma9918396b00029_1) 1995; 28
Kricheldorf H. R. (ma9918396b00030/ma9918396b00030_1) 1996; 29
Brunelle D. J. (ma9918396b00019/ma9918396b00019_1) 1995
Brunelle D. J. (ma9918396b00005/ma9918396b00005_1) 1993
Considine W. J. (ma9918396b00021/ma9918396b00021_1) 1966; 5
Goodman I. (ma9918396b00025/ma9918396b00025_1) 1960
Goodman I. (ma9918396b00024/ma9918396b00024_1) 1960; 48
Van Krevelen D. (ma9918396b00032/ma9918396b00032_1) 1990
Kricheldorf H. R. (ma9918396b00028/ma9918396b00028_1) 1991; 24
Miller S. Ph.D. (ma9918396b00033/ma9918396b00033_1) 1998
Youk J. H. (ma9918396b00016/ma9918396b00016_1)
Brunelle D. J. (ma9918396b00004/ma9918396b00004_1) 1991
Kricheldorf H. R. (ma9918396b00031/ma9918396b00031_1) 1996; 29
Jiang H. (ma9918396b00008/ma9918396b00008_1) 1997; 30
Bryant J. J. L. (ma9918396b00012/ma9918396b00012_1) 1997; 38
Hubbard P. A. (ma9918396b00013/ma9918396b00013_1) 1998; 31
Brunelle D. (ma9918396b00006/ma9918396b00006_1) 1993
ma9918396b00003/ma9918396b00003_1
Kricheldorf H. R. (ma9918396b00026/ma9918396b00026_1) 1984; 17
Brunelle D. J. (ma9918396b00007/ma9918396b00007_1) 1993; 26
Schnell H. (ma9918396b00001/ma9918396b00001_1) 1962; 57
Solomon O. F. (ma9918396b00018/ma9918396b00018_1) 1962; 6
Berkowitz S. A. (ma9918396b00017/ma9918396b00017_1) 1984; 29
Mehrotra R. C. (ma9918396b00020/ma9918396b00020_1) 1965; 4
Smith P. J. (ma9918396b00022/ma9918396b00022_1) 1972; 40
ma9918396b00002/ma9918396b00002_1
Krabbenhoft H. O. (ma9918396b00010/ma9918396b00010_1) 1997; 66
Brunelle D. J. (ma9918396b00014/ma9918396b00014_1) 1998; 31
References_xml – volume: 29
  start-page: 8695
  year: 1996
  ident: ma9918396b00031/ma9918396b00031_1
  publication-title: Macromolecules
  contributor:
    fullname: Kricheldorf H. R.
– start-page: 121
  volume-title: Properties of Polymer
  year: 1990
  ident: ma9918396b00032/ma9918396b00032_1
  contributor:
    fullname: Van Krevelen D.
– volume: 40
  start-page: 353
  year: 1972
  ident: ma9918396b00022/ma9918396b00022_1
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)93372-2
  contributor:
    fullname: Smith P. J.
– volume: 17
  start-page: 2181
  year: 1984
  ident: ma9918396b00026/ma9918396b00026_1
  publication-title: Macromolecules
  doi: 10.1021/ma00140a051
  contributor:
    fullname: Kricheldorf H. R.
– volume: 6
  start-page: 686
  year: 1962
  ident: ma9918396b00018/ma9918396b00018_1
  publication-title: J. Appl. Polym. Sci.
  doi: 10.1002/app.1962.070062414
  contributor:
    fullname: Solomon O. F.
– volume-title: Patent 5,039,783
  year: 1991
  ident: ma9918396b00004/ma9918396b00004_1
  contributor:
    fullname: Brunelle D. J.
– volume-title: Patent 843,356
  year: 1960
  ident: ma9918396b00025/ma9918396b00025_1
  contributor:
    fullname: Goodman I.
– volume-title: Patent 5,214,158
  year: 1993
  ident: ma9918396b00005/ma9918396b00005_1
  contributor:
    fullname: Brunelle D. J.
– volume: 48
  start-page: 433
  year: 1960
  ident: ma9918396b00024/ma9918396b00024_1
  publication-title: J. Polym. Sci.
  doi: 10.1002/pol.1960.1204815042
  contributor:
    fullname: Goodman I.
– volume: 1
  start-page: 396
  year: 1960
  ident: ma9918396b00023/ma9918396b00023_1
  publication-title: Polymer
  doi: 10.1016/0032-3861(60)90048-3
  contributor:
    fullname: Goodman I.
– volume: 29
  start-page: 4361
  year: 1984
  ident: ma9918396b00017/ma9918396b00017_1
  publication-title: J. Appl. Polym. Sci.
  doi: 10.1002/app.1984.070291264
  contributor:
    fullname: Berkowitz S. A.
– volume-title: Patent 5,407,984
  year: 1995
  ident: ma9918396b00019/ma9918396b00019_1
  contributor:
    fullname: Brunelle D. J.
– volume: 38
  start-page: 4537
  year: 1997
  ident: ma9918396b00012/ma9918396b00012_1
  publication-title: Polymer
  contributor:
    fullname: Bryant J. J. L.
– volume: 28
  start-page: 6725
  year: 1995
  ident: ma9918396b00029/ma9918396b00029_1
  publication-title: Macromolecules
  contributor:
    fullname: Kricheldorf H. R.
– volume: 57
  start-page: 11
  year: 1962
  ident: ma9918396b00001/ma9918396b00001_1
  publication-title: Makromol. Chem.
  doi: 10.1002/macp.1962.020570101
  contributor:
    fullname: Schnell H.
– volume: 21
  start-page: 293
  year: 1988
  ident: ma9918396b00027/ma9918396b00027_1
  publication-title: Macromolecules
  contributor:
    fullname: Kricheldorf H. R.
– volume: 29
  start-page: 1381
  year: 1996
  ident: ma9918396b00030/ma9918396b00030_1
  publication-title: Macromolecules
  contributor:
    fullname: Kricheldorf H. R.
– volume: 31
  start-page: 4790
  year: 1998
  ident: ma9918396b00014/ma9918396b00014_1
  publication-title: Macromolecules
  doi: 10.1021/ma971491j
  contributor:
    fullname: Brunelle D. J.
– volume: 30
  start-page: 2842
  year: 1997
  ident: ma9918396b00008/ma9918396b00008_1
  publication-title: Macromolecules
  contributor:
    fullname: Jiang H.
– volume: 29
  start-page: 8307
  year: 1996
  ident: ma9918396b00009/ma9918396b00009_1
  publication-title: III Macromolecules
  contributor:
    fullname: Hubbard P.
– ident: ma9918396b00016/ma9918396b00016_1
  publication-title: J. Macromolecules, accepted.
  contributor:
    fullname: Youk J. H.
– volume: 31
  start-page: 1522
  year: 1998
  ident: ma9918396b00013/ma9918396b00013_1
  publication-title: J. Macromolecules
  doi: 10.1021/ma971275a
  contributor:
    fullname: Hubbard P. A.
– ident: ma9918396b00003/ma9918396b00003_1
– volume: 26
  start-page: 2729
  year: 1993
  ident: ma9918396b00007/ma9918396b00007_1
  publication-title: Macromolecules
  doi: 10.1021/ma00063a014
  contributor:
    fullname: Brunelle D. J.
– volume: 4
  start-page: 150
  year: 1965
  ident: ma9918396b00020/ma9918396b00020_1
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)94164-0
  contributor:
    fullname: Mehrotra R. C.
– volume: 5
  start-page: 266
  year: 1966
  ident: ma9918396b00021/ma9918396b00021_1
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)80364-2
  contributor:
    fullname: Considine W. J.
– volume-title: University of Massachusetts Amherst
  year: 1998
  ident: ma9918396b00033/ma9918396b00033_1
  contributor:
    fullname: Miller S. Ph.D.
– volume-title: Ring Opening Polymerization:  Mechanism, Catalysis, Structure, Utility
  year: 1993
  ident: ma9918396b00006/ma9918396b00006_1
  contributor:
    fullname: Brunelle D.
– ident: ma9918396b00002/ma9918396b00002_1
– volume: 24
  start-page: 1949
  year: 1991
  ident: ma9918396b00028/ma9918396b00028_1
  publication-title: Macromolecules
  contributor:
    fullname: Kricheldorf H. R.
– volume: 66
  start-page: 2255
  year: 1997
  ident: ma9918396b00010/ma9918396b00010_1
  publication-title: J. Appl. Polym. Sci.
  doi: 10.1002/(SICI)1097-4628(19971219)66:12<2251::AID-APP6>3.0.CO;2-F
  contributor:
    fullname: Krabbenhoft H. O.
– volume: 38
  start-page: 2482
  year: 1997
  ident: ma9918396b00011/ma9918396b00011_1
  publication-title: Polymer
  contributor:
    fullname: Bryant J. J. L.
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Title Polymerization of Ethylene Terephthalate Cyclic Oligomers with a Cyclic Dibutyltin Initiator
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