On How Experimental Conditions Affect the Electrochemical Response of Disordered Nickel Oxyhydroxide Films
An electrochemical conditioning protocol was developed for studying amorphous phases of nickel hydroxide films (NiO x ) that renders congruent and reproducible redox behavior that enables more standardized mechanistic studies. Dynamic oxidative behavior was measured for the conditioned films, where...
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Published in | Chemistry of materials Vol. 28; no. 16; pp. 5635 - 5642 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
23.08.2016
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Abstract | An electrochemical conditioning protocol was developed for studying amorphous phases of nickel hydroxide films (NiO x ) that renders congruent and reproducible redox behavior that enables more standardized mechanistic studies. Dynamic oxidative behavior was measured for the conditioned films, where the initial peak associated with the oxidation of NiO x contains 1.3–2.0 times the charge for that measured in subsequent oxidative scans and the corresponding reductive peak. It is shown that charge trapping does not fully account for this excess charge. The magnitude of excess anodic charge is affected by pH, OH– diffusion through the film, and voltammetric scan rates. |
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AbstractList | An electrochemical conditioning protocol was developed for studying amorphous phases of nickel hydroxide films (NiO x ) that renders congruent and reproducible redox behavior that enables more standardized mechanistic studies. Dynamic oxidative behavior was measured for the conditioned films, where the initial peak associated with the oxidation of NiO x contains 1.3–2.0 times the charge for that measured in subsequent oxidative scans and the corresponding reductive peak. It is shown that charge trapping does not fully account for this excess charge. The magnitude of excess anodic charge is affected by pH, OH– diffusion through the film, and voltammetric scan rates. |
Author | Berlinguette, Curtis P Dettelbach, Kevan E Sherbo, Rebecca S Smith, Rodney D. L |
AuthorAffiliation | Departments of Chemistry and Chemical & Biological Engineering The University of British Columbia |
AuthorAffiliation_xml | – name: The University of British Columbia – name: Departments of Chemistry and Chemical & Biological Engineering |
Author_xml | – sequence: 1 givenname: Rodney D. L surname: Smith fullname: Smith, Rodney D. L – sequence: 2 givenname: Rebecca S surname: Sherbo fullname: Sherbo, Rebecca S – sequence: 3 givenname: Kevan E surname: Dettelbach fullname: Dettelbach, Kevan E – sequence: 4 givenname: Curtis P surname: Berlinguette fullname: Berlinguette, Curtis P email: cberling@chem.ubc.ca |
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