Spatial Extensions of Excited States of Metal Complexes. Tunability by Chemical Variation

• Published in: Inorganic chemistry Vol. 38; no. 25; pp. 5820 - 5831
• Main Authors: Yersin, Hartmut, Humbs, Werner
• Format: Journal Article
• Language: English
• Published: American Chemical Society 13.12.1999

The ligand−ligand coupling in excited states of homoleptic metal−organic and related compounds of the platinum metal group depends strongly on the metal d or MLCT character in these states. In particular, in triplet states, which mostly represent the lowest excited states, the metal participation is...