Synthesis, Characterization, and Reactivity of [(( i Pr)2P(CH2)3P( i Pr)2)(PCy3)PdH][OR]

• Published in: Organometallics Vol. 20; no. 2; pp. 337 - 345
• Main Authors: Perez, Pedro J, Calabrese, Joseph C, Bunel, Emilio E
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 22.01.2001; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; Physical Sciences; Science & Technology; PALLADIUM(I) HYDRIDE; CRYSTAL; BOND; COMPLEXES; STRUCTURAL CHARACTERIZATION

The preparation of (DIPPP)Pd(PR3) and [(DIPPP)(PR3)PdH][OR‘] (DIPPP = bis(1,3-diisopropylphosphino)propane; R = Cy, Et; R‘ = Ar, CF3SO2) is reported. (DIPPP)Pd(PCy3) and [(DIPPP)(PCy3)PdH][CF3SO3] have been structurally characterized. (DIPPP)Pd(PR3) complexes catalyze the reaction of ethylene with c...