Robust and Stretchable Polymer Semiconducting Networks: From Film Microstructure to Macroscopic Device Performance
Although stretchable polymer-based devices with promising electrical performance have been produced through the polymer blend strategy, the interplay between the blend film microstructure and macroscopic device performance under deformation has yet to be unambiguously articulated. Here, we discuss t...
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| Published in | Chemistry of materials Vol. 31; no. 17; pp. 6530 - 6539 |
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| Main Authors | , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
10.09.2019
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| Online Access | Get full text |
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| Abstract | Although stretchable polymer-based devices with promising electrical performance have been produced through the polymer blend strategy, the interplay between the blend film microstructure and macroscopic device performance under deformation has yet to be unambiguously articulated. Here, we discuss the formation of robust semiconducting networks in blended films through a thermodynamic perspective. Thermodynamic behavior along with the linear absorption and photoluminescence measurements predict the competition between polymer phase separation and semiconductor crystallization processes during film formation. Semiconducting films comprised of different pi-conjugated semiconductors were prepared and shown to have mechanical and electronic properties similar to those of films comprised of a model P3HT and PDMS blend. These results suggest that a film’s microstructure and therefore robustness can be refined by controlling the phase separation and crystallization behavior during film solidification. Fine-tuning a film’s electrical, mechanical, and optical properties during fabrication will allow for advanced next-generation of optoelectronic devices. |
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| AbstractList | Although stretchable polymer-based devices with promising electrical performance have been produced through the polymer blend strategy, the interplay between the blend film microstructure and macroscopic device performance under deformation has yet to be unambiguously articulated. Here, we discuss the formation of robust semiconducting networks in blended films through a thermodynamic perspective. Thermodynamic behavior along with the linear absorption and photoluminescence measurements predict the competition between polymer phase separation and semiconductor crystallization processes during film formation. Semiconducting films comprised of different pi-conjugated semiconductors were prepared and shown to have mechanical and electronic properties similar to those of films comprised of a model P3HT and PDMS blend. These results suggest that a film’s microstructure and therefore robustness can be refined by controlling the phase separation and crystallization behavior during film solidification. Fine-tuning a film’s electrical, mechanical, and optical properties during fabrication will allow for advanced next-generation of optoelectronic devices. |
| Author | Silva, Carlos Zhang, Guoyan Reichmanis, Elsa Lee, Savannah McBride, Michael Kwon, Yo Han Dunn, Tim J Savikhin, Victoria Valverde-Chávez, David A Buckley, Carolyn Xiong, Hao Toney, Michael F Gutiérrez-Meza, Elizabeth Yuan, Zhibo |
| AuthorAffiliation | School of Chemical and Biomolecular Engineering School of Chemistry and Biochemistry College of Materials Science and Engineering School of Material Science and Engineering School of Physics |
| AuthorAffiliation_xml | – name: School of Chemical and Biomolecular Engineering – name: School of Physics – name: School of Chemistry and Biochemistry – name: School of Material Science and Engineering – name: College of Materials Science and Engineering |
| Author_xml | – sequence: 1 givenname: Guoyan surname: Zhang fullname: Zhang, Guoyan organization: School of Chemical and Biomolecular Engineering – sequence: 2 givenname: Savannah surname: Lee fullname: Lee, Savannah organization: School of Chemical and Biomolecular Engineering – sequence: 3 givenname: Elizabeth surname: Gutiérrez-Meza fullname: Gutiérrez-Meza, Elizabeth organization: School of Chemistry and Biochemistry – sequence: 4 givenname: Carolyn surname: Buckley fullname: Buckley, Carolyn organization: School of Chemistry and Biochemistry – sequence: 5 givenname: Michael surname: McBride fullname: McBride, Michael organization: School of Chemical and Biomolecular Engineering – sequence: 6 givenname: David A surname: Valverde-Chávez fullname: Valverde-Chávez, David A organization: School of Chemistry and Biochemistry – sequence: 7 givenname: Yo Han surname: Kwon fullname: Kwon, Yo Han organization: School of Chemical and Biomolecular Engineering – sequence: 8 givenname: Victoria surname: Savikhin fullname: Savikhin, Victoria – sequence: 9 givenname: Hao surname: Xiong fullname: Xiong, Hao organization: College of Materials Science and Engineering – sequence: 10 givenname: Tim J surname: Dunn fullname: Dunn, Tim J – sequence: 11 givenname: Michael F orcidid: 0000-0002-7513-1166 surname: Toney fullname: Toney, Michael F – sequence: 12 givenname: Zhibo surname: Yuan fullname: Yuan, Zhibo organization: School of Chemistry and Biochemistry – sequence: 13 givenname: Carlos orcidid: 0000-0002-3969-5271 surname: Silva fullname: Silva, Carlos organization: School of Physics – sequence: 14 givenname: Elsa orcidid: 0000-0002-8205-8016 surname: Reichmanis fullname: Reichmanis, Elsa email: ereichmanis@chbe.gatech.edu organization: School of Material Science and Engineering |
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| Title | Robust and Stretchable Polymer Semiconducting Networks: From Film Microstructure to Macroscopic Device Performance |
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