Improved Catalytic Activity of Ruthenium–Arene Complexes in the Reduction of NAD

• Published in: Organometallics Vol. 31; no. 16; pp. 5958 - 5967
• Main Authors: Soldevila-Barreda, Joan J, Bruijnincx, Pieter C. A, Habtemariam, Abraha, Clarkson, Guy J, Deeth, Robert J, Sadler, Peter J
• Format: Journal Article
• Language: English
• Published: American Chemical Society 27.08.2012

A series of neutral RuII half-sandwich complexes of the type [(η6-arene)Ru(N,N′)Cl] where the arene is para-cymene (p-cym), hexamethylbenzene (hmb), biphenyl (bip), or benzene (bn) and N,N′ is N-(2-aminoethyl)-4-(trifluoromethyl)benzenesulfonamide (TfEn), N-(2-aminoethyl)-4-toluenesulfonamide (TsEn)...