Activation of Group 14 El−H Bonds at Platinum(0)

• Published in: Organometallics Vol. 26; no. 8; pp. 1996 - 2004
• Main Authors: White, Colin P, Braddock-Wilking, Janet, Corey, Joyce Y, Xu, Huan, Redekop, Evgeniy, Sedinkin, Sergey, Rath, Nigam P
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 09.04.2007; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Chemistry, Organic; Physical Sciences; Science & Technology; DIPALLADIUM COMPLEXES; LIGANDS; CLUSTER COMPLEXES; SI; SILICON; DIPLATINUM COMPLEXES; DINUCLEAR COMPLEXES; OXIDATIVE ADDITION; REDUCTIVE ELIMINATION; RAY CRYSTAL-STRUCTURE

Acyclic hydrogermanes [Ar2GeH2; Ar = Ph (1), Mes (8)] and a hydrostannane (Ph2SnH2, 5) were reacted with the Pt(0) precursor (Ph3P)2Pt(η2-C2H4) (2). The mononuclear complexes (Ph3P)2Pt(H)(GePh2H) (3), (Ph3P)2Pt(H)(SnPh2H) (6), and (Ph3P)2Pt(H)(GeMes2H) (9) and the dinuclear complexes [(Ph3P)Pt(μ-η-H...