Determination of the Rate Constants of an Irreversible Electrode Reaction by Using Double Potential Step Chronoamperometry

It is shown how the use of double potential step chromamperometry with a planar electrode can be used to determine the rate constants of electrode processes.

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Bibliographic Details
Published inAnalytical chemistry (Washington) Vol. 66; no. 18; pp. 2935 - 2942
Main Authors Galvez, Jesus, Alcaraz, Maria Luisa, Vera, Juan
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 15.09.1994
Subjects
Chemistry
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
Scientific imaging
Irreversible reaction
Theoretical study
Measurement method
Chronoamperometry
Rate constant
Electrochemical reaction
Charge transfer
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Summary:It is shown how the use of double potential step chromamperometry with a planar electrode can be used to determine the rate constants of electrode processes.
Bibliography:istex:BC4AC3A6500F3246D67ACDDA24D233D7FB41DC3D
ark:/67375/TPS-3RJFLKSQ-4
ISSN:0003-2700
1520-6882
DOI:10.1021/ac00090a022