Vanadia/silica xerogels and nanocomposites

The application of the sol-gel process to the synthesis of dense oxide glasses and ceramics has been the subject of escalating interest because of the low temperatures and compositional flexibility inherent in this purely chemical approach. More recently it has been realized that undensified silica...

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Published inChemistry of materials Vol. 5; no. 11; pp. 1591 - 1594
Main Authors Stiegman, A. E, Eckert, Hellmut, Plett, Gary, Kim, Soon Sam, Anderson, Mark, Yavrouian, Andre
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.11.1993
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Abstract The application of the sol-gel process to the synthesis of dense oxide glasses and ceramics has been the subject of escalating interest because of the low temperatures and compositional flexibility inherent in this purely chemical approach. More recently it has been realized that undensified silica [open quotes]xerogel[close quotes] materials possess unique properties precisely because of their porous nature. The authors report the synthesis of a new transparent metal containing silica gel by the co-condensation of low concentrations of oxovanadium triisopropoxide with tetraethylorthosilicate (TEOS) via the sol-gel process.
AbstractList The application of the sol-gel process to the synthesis of dense oxide glasses and ceramics has been the subject of escalating interest because of the low temperatures and compositional flexibility inherent in this purely chemical approach. More recently it has been realized that undensified silica [open quotes]xerogel[close quotes] materials possess unique properties precisely because of their porous nature. The authors report the synthesis of a new transparent metal containing silica gel by the co-condensation of low concentrations of oxovanadium triisopropoxide with tetraethylorthosilicate (TEOS) via the sol-gel process.
Author Eckert, Hellmut
Stiegman, A. E
Anderson, Mark
Plett, Gary
Kim, Soon Sam
Yavrouian, Andre
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  surname: Plett
  fullname: Plett, Gary
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  givenname: Soon Sam
  surname: Kim
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  givenname: Mark
  surname: Anderson
  fullname: Anderson, Mark
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  givenname: Andre
  surname: Yavrouian
  fullname: Yavrouian, Andre
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Issue 11
Keywords NMR spectrum
Xerogel
Sol gel process
Silicon Organic compounds
Composite material
Language English
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SubjectTerms 400201 - Chemical & Physicochemical Properties
CHALCOGENIDES
CHEMICAL PREPARATION
Chemistry
Colloidal gels. Colloidal sols
Colloidal state and disperse state
COLLOIDS
COMPOSITE MATERIALS
DISPERSIONS
Exact sciences and technology
GELS
General and physical chemistry
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MATERIALS
OXIDES
OXYGEN COMPOUNDS
SILICON COMPOUNDS
SILICON OXIDES
STOICHIOMETRY
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM OXIDES
Title Vanadia/silica xerogels and nanocomposites
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