An Elastic Hydrogen-Bonded Cross-Linked Organic Framework for Effective Iodine Capture in Water

A crystalline microporous hydrogen-bonded cross-linked organic framework has been developed through covalent photo-cross-linking of molecular monomers that are assembled in a crystalline state. The elastic framework expands its void space to adsorb iodine rapidly with a high uptake capacity in an aq...

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Published inJournal of the American Chemical Society Vol. 139; no. 21; pp. 7172 - 7175
Main Authors Lin, Yunxiao, Jiang, Xuanfeng, Kim, Samuel T, Alahakoon, Sampath B, Hou, Xisen, Zhang, Zhiyun, Thompson, Christina M, Smaldone, Ronald A, Ke, Chenfeng
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 31.05.2017
Subjects
crosslinking
hydrogen bonding
iodine
porous media
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Summary:A crystalline microporous hydrogen-bonded cross-linked organic framework has been developed through covalent photo-cross-linking of molecular monomers that are assembled in a crystalline state. The elastic framework expands its void space to adsorb iodine rapidly with a high uptake capacity in an aqueous environment as well as recovering its crystalline form after the release of iodine.
Bibliography:ObjectType-Article-1
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content type line 23
ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/jacs.7b03204