Flexible Polypropylene-Supported ZIF‑8 Membranes for Highly Efficient Propene/Propane Separation

Metal–organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membr...

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Published in	Journal of the American Chemical Society Vol. 142; no. 50; pp. 20915 - 20919
Main Authors	Zhao, Yali, Wei, Yanying, Lyu, Luxi, Hou, Qianqian, Caro, Jürgen, Wang, Haihui
Format	Journal Article
Language	English
Published	United States American Chemical Society 16.12.2020
Subjects	brittleness coordination polymers industrial applications polypropylenes propane propylene
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Abstract	Metal–organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C3H6–C3H8 mixtures combined with excellent flexibility behavior. The C3H6/C3H8 separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m–1. This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability.
AbstractList	Metal–organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C3H6–C3H8 mixtures combined with excellent flexibility behavior. The C3H6/C3H8 separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m–1. This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability. Metal-organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C3H6-C3H8 mixtures combined with excellent flexibility behavior. The C3H6/C3H8 separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m-1. This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability.Metal-organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C3H6-C3H8 mixtures combined with excellent flexibility behavior. The C3H6/C3H8 separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m-1. This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability. Metal–organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C₃H₆–C₃H₈ mixtures combined with excellent flexibility behavior. The C₃H₆/C₃H₈ separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m–¹. This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability. Metal-organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed for scale-up, but their brittleness hampers any industrial application. Herein, intergrown continuous polypropylene (PP)-supported ZIF-8 membranes have been successfully synthesized via fast current-driven synthesis (FCDS) within 1 h. The PP-supported ZIF-8 membranes exhibit a promising separation factor of 122 ± 13 for binary C H -C H mixtures combined with excellent flexibility behavior. The C H /C H separation performance of the PP-supported ZIF-8 membrane was found to be constant after bending the supported ZIF-8 film with a curvature of 92 m . This outstanding mechanical property is crucial for practical applications. Moreover, we further synthesized ZIF-8 membranes on various polymer substrates and even polymer hollow fibers to demonstrate the production scalability.
Author	Wei, Yanying Lyu, Luxi Zhao, Yali Wang, Haihui Hou, Qianqian Caro, Jürgen
AuthorAffiliation	Beijing Key Laboratory of Membrane Materials and Engineering, Department of Chemical Engineering School of Chemistry & Chemical Engineering Tsinghua University Institute of Physical Chemistry and Electrochemistry
AuthorAffiliation_xml	– name: Institute of Physical Chemistry and Electrochemistry – name: Tsinghua University – name: School of Chemistry & Chemical Engineering – name: Beijing Key Laboratory of Membrane Materials and Engineering, Department of Chemical Engineering
Author_xml	– sequence: 1 givenname: Yali surname: Zhao fullname: Zhao, Yali organization: School of Chemistry & Chemical Engineering – sequence: 2 givenname: Yanying surname: Wei fullname: Wei, Yanying email: ceyywei@scut.edu.cn organization: School of Chemistry & Chemical Engineering – sequence: 3 givenname: Luxi surname: Lyu fullname: Lyu, Luxi organization: School of Chemistry & Chemical Engineering – sequence: 4 givenname: Qianqian surname: Hou fullname: Hou, Qianqian organization: School of Chemistry & Chemical Engineering – sequence: 5 givenname: Jürgen orcidid: 0000-0003-0931-085X surname: Caro fullname: Caro, Jürgen email: juergen.caro@pci.uni-hannover.de organization: Institute of Physical Chemistry and Electrochemistry – sequence: 6 givenname: Haihui orcidid: 0000-0002-2917-4739 surname: Wang fullname: Wang, Haihui email: cehhwang@tsinghua.edu.cn organization: Tsinghua University
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Snippet	Metal–organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed... Metal-organic framework (MOF) membranes have enormous potential in separation applications. There are several MOF membranes grown on polymer substrates aimed...
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SubjectTerms	brittleness coordination polymers industrial applications polypropylenes propane propylene
Title	Flexible Polypropylene-Supported ZIF‑8 Membranes for Highly Efficient Propene/Propane Separation
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