δ‑Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer
We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination–LMCT–homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic...
Saved in:
| Published in | Journal of the American Chemical Society Vol. 140; no. 5; pp. 1612 - 1616 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
07.02.2018
Amer Chemical Soc |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0002-7863 1520-5126 1520-5126 |
| DOI | 10.1021/jacs.7b13131 |
Cover
| Abstract | We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination–LMCT–homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C–H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols. |
|---|---|
| AbstractList | We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination-LMCT-homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols. We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination-LMCT-homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols.We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination-LMCT-homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols. We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination LMCT homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for delta-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalizaton, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols. |
| Author | Pan, Hui Guo, Jing-Jing Hu, Anhua Tang, Haoming Gao, Zhaobo Zuo, Zhiwei |
| AuthorAffiliation | School of Physical Science and Technology |
| AuthorAffiliation_xml | – name: School of Physical Science and Technology |
| Author_xml | – sequence: 1 givenname: Anhua surname: Hu fullname: Hu, Anhua organization: School of Physical Science and Technology – sequence: 2 givenname: Jing-Jing surname: Guo fullname: Guo, Jing-Jing organization: School of Physical Science and Technology – sequence: 3 givenname: Hui surname: Pan fullname: Pan, Hui organization: School of Physical Science and Technology – sequence: 4 givenname: Haoming surname: Tang fullname: Tang, Haoming organization: School of Physical Science and Technology – sequence: 5 givenname: Zhaobo surname: Gao fullname: Gao, Zhaobo – sequence: 6 givenname: Zhiwei orcidid: 0000-0002-3361-3220 surname: Zuo fullname: Zuo, Zhiwei email: zuozhw@shanghaitech.edu.cn organization: School of Physical Science and Technology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29381061$$D View this record in MEDLINE/PubMed |
| BookMark | eNqNks1u1DAUhS1URKctO9YoSyRI8U_i2MsqaqHSIBa0bCPHuWk9eOxiO0VlxSvwLjwHD8GT4OmkXSBQkRc-1_7OlXx99tCO8w4QekbwIcGUvF4pHQ-bnrC8HqEFqSkua0L5DlpgjGnZCM520V6Mq1xWVJAnaJdKJgjmZIHWP3_8-vb9A1jQyVxDcTK5LLxT1nxVG1H4sTiyn5TzNhbHTvUWhqK_KT6aaLIul-biMpWnbph0vsiVckOZfPkOkrJFe6nCBRRnQbk4QjhAj0dlIzyd9310fnJ81r4tl-_fnLZHy1KxukklrZTEuBmpHFlfcZ533gCWDPoqP0dWvG6qRmIhtNCMjTAMVTOqoaEwSFpLto9ebPteBf95gpi6tYkarFUO_BQ7SggXnNTsYZRIyTAWHIuMPp_RqV_D0F0Fs1bhprubZgZeboEv0PsxagNOwz12O_5K1KTOitBMi_-nW5Nuv6P1k0vZ-mpr1cHHGGC8txHcbVLRbVLRzanIOP0D13O7FJSx_zLNg9kcrvwUcibi39Hf51_GXg |
| CitedBy_id | crossref_primary_10_1039_D1SC05517H crossref_primary_10_1016_j_chempr_2024_12_005 crossref_primary_10_1021_acs_orglett_2c00138 crossref_primary_10_1039_C8QO00893K crossref_primary_10_1039_D2CC03234A crossref_primary_10_1002_ejoc_202101036 crossref_primary_10_1002_chem_201806138 crossref_primary_10_1021_acs_accounts_4c00510 crossref_primary_10_1021_acs_orglett_9b02234 crossref_primary_10_1039_D1RA04130D crossref_primary_10_1021_acs_organomet_3c00210 crossref_primary_10_1021_jacs_4c16449 crossref_primary_10_1021_acscatal_4c07252 crossref_primary_10_1002_anie_202205562 crossref_primary_10_1039_D2QO00332E crossref_primary_10_1021_acs_jpclett_2c03836 crossref_primary_10_1039_D2TA09523H crossref_primary_10_1002_anie_201906080 crossref_primary_10_1002_chem_202403841 crossref_primary_10_1002_chem_201901762 crossref_primary_10_1002_anie_201809879 crossref_primary_10_1038_s41467_024_45875_y crossref_primary_10_1002_open_201900041 crossref_primary_10_1039_D2GC03344E crossref_primary_10_1002_anie_202100270 crossref_primary_10_1016_j_checat_2021_05_005 crossref_primary_10_1016_j_tet_2022_133172 crossref_primary_10_1021_jacs_9b04189 crossref_primary_10_1021_jacs_9b12918 crossref_primary_10_1039_D4OB00876F crossref_primary_10_1016_j_jallcom_2020_156431 crossref_primary_10_1126_science_aat9750 crossref_primary_10_1039_D1QO01373D crossref_primary_10_1002_ange_202009995 crossref_primary_10_1039_C8CC07434H crossref_primary_10_1038_s41467_022_35344_9 crossref_primary_10_1016_j_ccr_2023_215522 crossref_primary_10_1002_ange_202012720 crossref_primary_10_1021_acs_orglett_0c02475 crossref_primary_10_1021_jacs_8b05962 crossref_primary_10_1039_D3CC00439B crossref_primary_10_1002_ange_201804022 crossref_primary_10_1039_D0QO01238F crossref_primary_10_2174_1385272825666211126123928 crossref_primary_10_1002_anie_202007825 crossref_primary_10_1021_acs_orglett_9b02255 crossref_primary_10_1002_ange_202204515 crossref_primary_10_1002_bkcs_12234 crossref_primary_10_1002_adsc_201801198 crossref_primary_10_1039_D0QO00952K crossref_primary_10_1002_anie_201813356 crossref_primary_10_1038_s41467_023_41956_6 crossref_primary_10_1021_acs_chemrev_1c00256 crossref_primary_10_1038_s41467_022_28441_2 crossref_primary_10_1055_a_2131_4126 crossref_primary_10_1002_anie_201911660 crossref_primary_10_1002_ange_201806434 crossref_primary_10_1002_anie_202012720 crossref_primary_10_1021_acs_orglett_1c01385 crossref_primary_10_1021_acscatal_4c03799 crossref_primary_10_1002_anie_201812927 crossref_primary_10_1002_ajoc_202300234 crossref_primary_10_1007_s11426_018_9399_2 crossref_primary_10_1039_D4QO01522C crossref_primary_10_1021_jacs_8b08781 crossref_primary_10_1039_D4QO02146K crossref_primary_10_1055_a_2044_2140 crossref_primary_10_1002_anie_202000632 crossref_primary_10_1021_acs_orglett_8b02022 crossref_primary_10_1002_chem_201901079 crossref_primary_10_1002_ejoc_202300993 crossref_primary_10_1021_acs_chemrev_2c00478 crossref_primary_10_1039_D3QO00896G crossref_primary_10_1039_D4QO00797B crossref_primary_10_1021_acs_joc_3c00170 crossref_primary_10_1021_jacs_9b05932 crossref_primary_10_1002_adsc_202200059 crossref_primary_10_1002_ajoc_202300160 crossref_primary_10_1021_acs_joc_0c00237 crossref_primary_10_1002_adsc_202201149 crossref_primary_10_1039_C8CC09208G crossref_primary_10_1016_j_isci_2019_100755 crossref_primary_10_1080_00032719_2022_2122062 crossref_primary_10_1515_psr_2017_0172 crossref_primary_10_1002_ange_201906112 crossref_primary_10_1021_acs_orglett_4c00911 crossref_primary_10_1021_acs_orglett_9b02394 crossref_primary_10_1038_s41570_022_00422_5 crossref_primary_10_1002_anie_202002900 crossref_primary_10_1002_ange_202007825 crossref_primary_10_3762_bjoc_17_121 crossref_primary_10_1002_ange_202000632 crossref_primary_10_1002_anie_201804022 crossref_primary_10_1016_j_poly_2023_116773 crossref_primary_10_1002_adsc_201900283 crossref_primary_10_1039_C9SC04987H crossref_primary_10_1016_j_cej_2020_125045 crossref_primary_10_1021_acssuschemeng_0c07850 crossref_primary_10_1039_D2QO00607C crossref_primary_10_1021_acs_orglett_0c00287 crossref_primary_10_1039_D4SC07048H crossref_primary_10_1039_D2DT00856D crossref_primary_10_1039_D1GC01210J crossref_primary_10_1039_D2SC01548J crossref_primary_10_1039_D3SC01118F crossref_primary_10_1002_adsc_202300119 crossref_primary_10_1021_acs_orglett_9b01734 crossref_primary_10_1021_jacs_4c12432 crossref_primary_10_1021_acs_inorgchem_0c03105 crossref_primary_10_1021_acs_orglett_8b04104 crossref_primary_10_1039_D1OB01002F crossref_primary_10_1039_D4QO01339E crossref_primary_10_1002_chem_202400642 crossref_primary_10_1021_jacs_1c00618 crossref_primary_10_1002_anie_201806434 crossref_primary_10_1002_cctc_202300311 crossref_primary_10_1039_C8SC01788C crossref_primary_10_1021_acs_orglett_3c03401 crossref_primary_10_1002_ange_201809879 crossref_primary_10_1002_chem_202404200 crossref_primary_10_1039_D3OB00664F crossref_primary_10_1016_j_chempr_2022_10_011 crossref_primary_10_1039_D1CC06885G crossref_primary_10_1021_acscatal_2c02997 crossref_primary_10_1039_D0RA10739E crossref_primary_10_1016_j_ccr_2019_213129 crossref_primary_10_1021_jacs_1c05859 crossref_primary_10_1021_acsnano_2c08652 crossref_primary_10_1039_D0RA03211E crossref_primary_10_1002_cctc_202301075 crossref_primary_10_1039_D4QO01607F crossref_primary_10_1016_j_joule_2019_06_023 crossref_primary_10_1039_D1QO01859K crossref_primary_10_1002_ejoc_202400935 crossref_primary_10_1002_cssc_202201241 crossref_primary_10_1002_anie_202009995 crossref_primary_10_1021_acs_orglett_9b00540 crossref_primary_10_1039_D3CC05331H crossref_primary_10_1126_science_abd8408 crossref_primary_10_1002_adma_202100843 crossref_primary_10_1002_ange_202002900 crossref_primary_10_1039_D4GC05951D crossref_primary_10_1021_acs_joc_1c03021 crossref_primary_10_1021_acs_orglett_3c04395 crossref_primary_10_1002_adsc_201800736 crossref_primary_10_1021_acscatal_4c07845 crossref_primary_10_1002_adsc_202300939 crossref_primary_10_1021_acs_orglett_2c01505 crossref_primary_10_1039_D2SC03590A crossref_primary_10_1039_D0CS00493F crossref_primary_10_1002_chem_202304012 crossref_primary_10_1002_ejic_201900077 crossref_primary_10_1039_C9CC00492K crossref_primary_10_1039_D3SC06857A crossref_primary_10_1016_j_jlumin_2020_117391 crossref_primary_10_1039_C9QO00786E crossref_primary_10_1002_ange_201813356 crossref_primary_10_1021_acs_orglett_1c04365 crossref_primary_10_1002_cctc_202200916 crossref_primary_10_1016_j_tetlet_2023_154837 crossref_primary_10_1021_acs_orglett_8b03865 crossref_primary_10_1016_j_scib_2019_08_014 crossref_primary_10_1126_science_aau5379 crossref_primary_10_1002_ange_202010801 crossref_primary_10_1038_s41467_018_05522_9 crossref_primary_10_1016_j_tetlet_2018_04_060 crossref_primary_10_1002_anie_201806522 crossref_primary_10_1002_anie_201914557 crossref_primary_10_1021_acscatal_3c00238 crossref_primary_10_1002_ange_202007187 crossref_primary_10_1016_j_tet_2020_131153 crossref_primary_10_1002_anie_202204515 crossref_primary_10_1021_jacs_9b13171 crossref_primary_10_1039_C8CC02642D crossref_primary_10_1002_ajoc_201800733 crossref_primary_10_1021_jacsau_4c00880 crossref_primary_10_1039_D1CC04540G crossref_primary_10_1039_D1OB00196E crossref_primary_10_1021_acs_orglett_2c01750 crossref_primary_10_1021_jacs_0c00679 crossref_primary_10_1021_acs_orglett_1c00556 crossref_primary_10_1021_acscatal_9b03352 crossref_primary_10_1039_D0SC01471K crossref_primary_10_1002_ange_202100270 crossref_primary_10_1002_cjoc_202100420 crossref_primary_10_1021_jacs_4c15627 crossref_primary_10_1021_acscatal_2c00250 crossref_primary_10_1002_ange_201812927 crossref_primary_10_1039_D0CC01720E crossref_primary_10_1002_ange_202205562 crossref_primary_10_1002_ejoc_202500158 crossref_primary_10_1007_s41981_020_00077_7 crossref_primary_10_1002_ajoc_202200131 crossref_primary_10_1021_acs_joc_0c00250 crossref_primary_10_1021_acs_joc_4c00425 crossref_primary_10_1002_ejoc_202200417 crossref_primary_10_1016_j_chempr_2019_11_009 crossref_primary_10_3762_bjoc_19_81 crossref_primary_10_1039_D4CC01324G crossref_primary_10_1021_acs_accounts_8b00336 crossref_primary_10_1039_D0CS00774A crossref_primary_10_1002_anie_201906112 crossref_primary_10_1016_j_xcrp_2022_100763 crossref_primary_10_1021_acs_orglett_0c03058 crossref_primary_10_1063_5_0086718 crossref_primary_10_1002_ejic_202000659 crossref_primary_10_1038_s41467_022_35249_7 crossref_primary_10_1021_jacs_8b08822 crossref_primary_10_1038_s41467_018_05014_w crossref_primary_10_1039_D0OB00091D crossref_primary_10_1039_D2SC05976B crossref_primary_10_1039_D0CC03619F crossref_primary_10_1039_D0SC01340D crossref_primary_10_1039_C9CC06410A crossref_primary_10_1039_C9GC00414A crossref_primary_10_1055_a_1966_3271 crossref_primary_10_1039_D4CS01275E crossref_primary_10_1002_ejoc_202301205 crossref_primary_10_1021_jacs_4c05052 crossref_primary_10_1002_ange_202101266 crossref_primary_10_1002_anie_202001200 crossref_primary_10_1002_adsc_201901041 crossref_primary_10_1002_ange_201906080 crossref_primary_10_1002_adsc_202201176 crossref_primary_10_1039_C9CC04785A crossref_primary_10_1039_D1CC03466A crossref_primary_10_1002_ange_201911660 crossref_primary_10_1002_chem_202404063 crossref_primary_10_1002_cjoc_202200511 crossref_primary_10_1039_D4CC03189J crossref_primary_10_59761_RCR5123 crossref_primary_10_1021_acssuschemeng_2c02597 crossref_primary_10_1021_acs_orglett_0c03147 crossref_primary_10_1021_jacs_8b08933 crossref_primary_10_1039_D0SC04542J crossref_primary_10_1039_C9DT04555D crossref_primary_10_1055_s_0040_1720388 crossref_primary_10_1039_C8SC04134B crossref_primary_10_1021_acs_orglett_0c03944 crossref_primary_10_1021_jacs_1c02889 crossref_primary_10_1002_ange_202001200 crossref_primary_10_1021_acs_orglett_9b03524 crossref_primary_10_1039_D1QO01095F crossref_primary_10_1002_anie_202101266 crossref_primary_10_1039_D4CC04036H crossref_primary_10_1039_C9CC00282K crossref_primary_10_1039_D1CC01858B crossref_primary_10_1002_anie_202010801 crossref_primary_10_1002_slct_202404657 crossref_primary_10_1021_acscentsci_1c01109 crossref_primary_10_1016_j_checat_2023_100530 crossref_primary_10_1039_D4QO01245C crossref_primary_10_1021_jacs_2c10126 crossref_primary_10_1039_D2GC01144A crossref_primary_10_1039_D4CC00916A crossref_primary_10_1055_s_0042_1751518 crossref_primary_10_3390_org4040033 crossref_primary_10_1039_C8SC05685D crossref_primary_10_1016_j_gresc_2024_05_005 crossref_primary_10_1021_acscatal_3c00848 crossref_primary_10_1039_D3NJ02065G crossref_primary_10_1002_cjoc_202300493 crossref_primary_10_1002_slct_202202973 crossref_primary_10_1039_C9QO00017H crossref_primary_10_1002_ange_201914557 crossref_primary_10_1038_s41467_022_32467_x crossref_primary_10_1002_ange_201806522 crossref_primary_10_1021_acs_chemrev_1c00220 crossref_primary_10_1007_s11426_019_9527_5 crossref_primary_10_1021_acscatal_9b00563 crossref_primary_10_1039_D1CY00488C crossref_primary_10_1021_acs_orglett_9b00271 crossref_primary_10_1039_D4SC00692E crossref_primary_10_1002_chem_201902918 crossref_primary_10_1021_jacs_1c00687 crossref_primary_10_1039_D0MH01274B crossref_primary_10_1039_D4CC01574F crossref_primary_10_1021_acs_chemrev_2c00664 crossref_primary_10_1002_ange_202306015 crossref_primary_10_1002_cssc_202100682 crossref_primary_10_1002_anie_202114490 crossref_primary_10_1038_s41467_019_08413_9 crossref_primary_10_1021_jacs_8b00742 crossref_primary_10_1039_D2QO00528J crossref_primary_10_6023_cjoc202406040 crossref_primary_10_1039_D4OB01874E crossref_primary_10_1021_acs_orglett_1c03488 crossref_primary_10_1039_C9OB02676B crossref_primary_10_1055_a_1868_8092 crossref_primary_10_1021_jacs_0c00212 crossref_primary_10_1021_acscatal_3c05150 crossref_primary_10_1021_acs_orglett_4c03697 crossref_primary_10_1039_D0OB00964D crossref_primary_10_1038_s41570_022_00403_8 crossref_primary_10_6023_cjoc202406034 crossref_primary_10_1039_D0QO01042A crossref_primary_10_1016_S1872_2067_19_63278_X crossref_primary_10_1038_s41467_024_49557_7 crossref_primary_10_1002_ange_202114490 crossref_primary_10_1002_anie_202007187 crossref_primary_10_1002_anie_202306015 |
| Cites_doi | 10.1126/science.1239176 10.1021/ja01495a061 10.1016/S0040-4039(01)90085-1 10.1021/ja4126609 10.1021/jacs.6b05712 10.1021/ja00091a063 10.1002/anie.201604704 10.1002/anie.201609035 10.1038/nature19811 10.1021/ol025580e 10.1002/anie.201510014 10.1021/ja802491q 10.1021/ol060952v 10.1016/S0010-8545(98)00160-X 10.1021/ja5056774 10.1039/C4OB00469H 10.1038/nature19810 10.1021/jacs.6b02248 10.1039/B913880N 10.1126/science.aac8555 10.1021/jo301840e 10.1002/anie.201405418 10.1016/S0040-4020(01)98365-6 10.1016/0040-4020(95)00406-X 10.1021/jacs.5b05411 10.1016/S0040-4020(03)01202-X 10.1021/jo00171a066 10.1002/anie.201703611 10.1039/jr9560002260 10.1021/j100881a021 10.1021/cr300503r 10.1021/acs.inorgchem.7b00828 10.1021/jacs.5b08452 10.1021/ja01026a022 10.1126/science.1226458 10.1021/acs.accounts.6b00272 10.1002/anie.201611463 10.1039/C7CC04941B 10.1021/ja4060806 10.1021/jacs.7b05214 10.1021/ic00320a018 10.1021/ar020230d 10.1002/anie.201709025 10.1039/C6RA17524D 10.1055/s-2002-33335 10.1021/ja01046a021 10.1021/jacs.6b06517 10.1021/jacs.5b03192 10.1021/jacs.6b08397 10.1039/b613443m 10.1039/c3ee43147a 10.1126/science.1255525 10.1039/a904451e 10.1002/anie.201501122 10.1021/cr60221a004 10.1021/jo026314h 10.1021/ic00033a017 10.1039/b000705f 10.1002/anie.201607305 10.1021/ol401061v 10.1016/S1010-6030(01)00588-3 10.1021/jacs.7b09306 10.1021/acs.orglett.5b00582 10.1016/j.ica.2006.05.025 10.1021/acs.accounts.6b00339 10.1021/acs.organomet.5b00568 10.1126/science.aad8313 10.1021/ja9807892 10.1039/c4ob00469h 10.1039/c6ra17524d 10.1039/b913880n 10.1039/c7cc04941b |
| ContentType | Journal Article |
| Copyright | Copyright © 2018 American Chemical Society |
| Copyright_xml | – notice: Copyright © 2018 American Chemical Society |
| DBID | AAYXX CITATION 17B 1KM 1KN BLEPL DTL EGQ HBEAY NPM 7X8 7S9 L.6 |
| DOI | 10.1021/jacs.7b13131 |
| DatabaseName | CrossRef Web of Knowledge Index Chemicus Current Chemical Reactions Web of Science Core Collection Science Citation Index Expanded Web of Science Primary (SCIE, SSCI & AHCI) Web of Science - Science Citation Index Expanded - 2018 PubMed MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef Web of Science PubMed MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | PubMed AGRICOLA MEDLINE - Academic Web of Science |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: 1KN name: Current Chemical Reactions url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.CCR sourceTypes: Enrichment Source Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5126 |
| EndPage | 1616 |
| ExternalDocumentID | 29381061 000424851500012 10_1021_jacs_7b13131 a639868233 |
| Genre | Journal Article |
| GrantInformation_xml | – fundername: National Natural Science Foundation of China; National Natural Science Foundation of China (NSFC) grantid: 21772121 – fundername: "Thousand Plan" Youth Program |
| GroupedDBID | - .K2 02 53G 55A 5GY 5RE 5VS 7~N 85S AABXI ABFLS ABMVS ABPPZ ABPTK ABUCX ABUFD ACGFS ACJ ACNCT ACS AEESW AENEX AETEA AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH BKOMP CS3 DU5 DZ EBS ED ED~ EJD ET F5P GNL IH9 JG JG~ K2 LG6 P2P ROL RXW TAE TN5 UHB UI2 UKR UPT VF5 VG9 VQA W1F WH7 X XFK YZZ ZHY --- -DZ -ET -~X .DC 4.4 AAHBH AAYXX ABBLG ABJNI ABLBI ABQRX ACBEA ACGFO ADHLV AGXLV AHDLI AHGAQ CITATION CUPRZ GGK IH2 XSW YQT ZCA ~02 17B 1KM 1KN AAYWT BLEPL DTL GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED GROUPED_WOS_WEB_OF_SCIENCE NPM YIN 7X8 7S9 L.6 |
| ID | FETCH-LOGICAL-a357t-24a9007f29f3b46629f67e093eb478694657479088c8c33fedd47fad72ed92593 |
| IEDL.DBID | ACS |
| ISICitedReferencesCount | 303 |
| ISICitedReferencesURI | https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000424851500012 |
| ISSN | 0002-7863 1520-5126 |
| IngestDate | Thu Sep 04 20:36:27 EDT 2025 Fri Sep 05 14:39:25 EDT 2025 Wed Feb 19 02:43:29 EST 2025 Tue Jul 22 03:14:42 EDT 2025 Sat Sep 06 05:27:29 EDT 2025 Tue Jul 01 03:21:27 EDT 2025 Thu Apr 24 22:56:06 EDT 2025 Thu Aug 27 13:42:28 EDT 2020 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 5 |
| Keywords | OXIDATION INTRAMOLECULAR HYDROGEN ABSTRACTION C(SP)-H BONDS AMINATION ALKYLATION COMPLEXES SATURATED ALCOHOLS RADICALS EFFICIENT PHOTOREDOX CATALYSIS |
| Language | English |
| LinkModel | DirectLink |
| LogoURL | https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg |
| MergedId | FETCHMERGED-LOGICAL-a357t-24a9007f29f3b46629f67e093eb478694657479088c8c33fedd47fad72ed92593 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0002-3361-3220 0000-0003-0838-702X |
| PMID | 29381061 |
| PQID | 1993008608 |
| PQPubID | 23479 |
| PageCount | 5 |
| ParticipantIDs | crossref_primary_10_1021_jacs_7b13131 pubmed_primary_29381061 acs_journals_10_1021_jacs_7b13131 proquest_miscellaneous_2116861539 proquest_miscellaneous_1993008608 webofscience_primary_000424851500012CitationCount crossref_citationtrail_10_1021_jacs_7b13131 webofscience_primary_000424851500012 |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N ACJ VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2018-02-07 |
| PublicationDateYYYYMMDD | 2018-02-07 |
| PublicationDate_xml | – month: 02 year: 2018 text: 2018-02-07 day: 07 |
| PublicationDecade | 2010 |
| PublicationPlace | WASHINGTON |
| PublicationPlace_xml | – name: WASHINGTON – name: United States |
| PublicationTitle | Journal of the American Chemical Society |
| PublicationTitleAbbrev | J AM CHEM SOC |
| PublicationTitleAlternate | J. Am. Chem. Soc |
| PublicationYear | 2018 |
| Publisher | American Chemical Society Amer Chemical Soc |
| Publisher_xml | – name: American Chemical Society – name: Amer Chemical Soc |
| References | ref2/cit2e ref2/cit2d ref12/cit12c ref12/cit12b ref12/cit12a ref2/cit2c ref2/cit2b ref2/cit2a ref1/cit1a ref1/cit1c ref1/cit1b ref5/cit5b ref17/cit17 ref5/cit5c ref5/cit5a ref16/cit16b ref16/cit16a ref3/cit3b ref11/cit11c ref3/cit3c ref11/cit11b ref11/cit11e ref3/cit3a ref11/cit11d ref3/cit3f ref3/cit3g ref3/cit3d ref11/cit11a ref3/cit3e ref13/cit13 ref3/cit3h ref5/cit5f ref5/cit5g ref5/cit5d ref5/cit5e ref10/cit10h ref18/cit18 ref10/cit10i ref15/cit15a ref10/cit10j ref9/cit9c ref10/cit10d ref15/cit15d ref9/cit9b ref10/cit10e ref10/cit10f ref15/cit15b ref10/cit10g ref15/cit15c ref8/cit8a ref10/cit10a ref10/cit10b ref8/cit8b ref10/cit10c ref4/cit4a ref4/cit4b ref4/cit4c ref14/cit14a ref14/cit14c ref14/cit14b Balzani V. (ref9/cit9a) 2014 ref4/cit4d ref4/cit4e ref6/cit6a ref4/cit4f ref6/cit6b ref4/cit4g ref6/cit6c ref7/cit7 Prier, CK (WOS:000321810600018) 2013; 113 MIHAILOVIC, ML (WOS:A19656814200009) 1965; 21 Reddy, LR (WOS:000238284500041) 2006; 8 Kainz, QM (WOS:000369810000033) 2016; 351 WOLFF, ME (WOS:A19638640A00005) 1963; 63 Zhang, MJ (WOS:000386242500029) 2016; 6 Yin, HL (WOS:000358896600010) 2015; 137 Tsunoi, S (WOS:000075741300015) 1998; 120 Hartung, J (WOS:000177737000001) 2002 Musacchio, AJ (WOS:000341226000006) 2014; 136 Yin, HL (WOS:000390729500020) 2016; 138 Yuan, W (WOS:000407169500007) 2017; 53 TSUNOI, S (WOS:A1994NR60500063) 1994; 116 Betancor, C (WOS:000174997600014) 2002; 4 Zuo, ZW (WOS:000339655100039) 2014; 345 Tanielian, C (WOS:000077809500009) 1998; 178 Zard, SZ (WOS:000257839100014) 2008; 37 Do, HQ (WOS:000331493700070) 2014; 136 Yayla, HG (WOS:000382513300020) 2016; 138 NATARAJAN, E (WOS:A1992HM33900017) 1992; 31 Shields, BJ (WOS:000384952100003) 2016; 138 Robertson, J (WOS:000167044500002) 2001; 30 Zhang, J (WOS:000369854000052) 2016; 55 Ryu, I (WOS:000319720900058) 2013; 15 Vogler, A (WOS:000240489200044) 2006; 359 Gentry, EC (WOS:000381654700011) 2016; 49 Ratani, TS (WOS:000364355900033) 2015; 137 Balzani, V. (000424851500012.2) 2014 Hu, XQ (WOS:000397323300002) 2017; 56 Schultz, DM (WOS:000332309600033) 2014; 343 Wappes, EA (WOS:000383373000028) 2016; 55 Hwang, SJ (WOS:000355383500013) 2015; 137 BARTON, DHR (WOS:A1960WB33700061) 1960; 82 BETANCOR, C (WOS:A1983RR87700066) 1983; 48 EVANS, WJ (WOS:A1989AW24900018) 1989; 28 Hwang, SJ (WOS:000362863600017) 2015; 34 Chu, JCK (WOS:000387318500041) 2016; 539 Chen, DF (WOS:000414115800020) 2017; 139 SHELDON, RA (WOS:A1968C120800022) 1968; 90 Wu, XX (WOS:000423494500038) 2018; 57 RYAN, JL (WOS:A19668256000021) 1966; 70 Martinez, C (WOS:000357209000050) 2015; 54 Wang, CY (WOS:000385718300022) 2016; 55 Creutz, SE (WOS:000310516000048) 2012; 338 Friedrich, J (WOS:000405972200056) 2017; 56 Zhang, G (WOS:000333203900008) 2014; 7 Amaoka, Y (WOS:000311073000003) 2012; 77 MAJETICH, G (WOS:A1995RE87800001) 1995; 51 Choi, GJ (WOS:000387318500040) 2016; 539 Wappes, EA (WOS:000407089500010) 2017; 139 Qin, QX (WOS:000353314800020) 2015; 17 Hartshorn, RM (WOS:000083147800010) 1999 Becker, P (WOS:000403839000060) 2017; 56 Chiba, S (WOS:000336844400002) 2014; 12 Ziegler, DT (WOS:000330163100033) 2013; 135 CONCEPCION, JI (WOS:A1984SP58500026) 1984; 25 Francisco, CG (WOS:000180834600045) 2003; 68 Ravelli, D (WOS:000385908100019) 2016; 49 Kunkely, H (WOS:000172629800008) 2001; 146 Shi, YB (WOS:000342677000021) 2014; 53 Narayanam, JMR (WOS:000285390900008) 2011; 40 Blanksby, SJ (WOS:000182343300004) 2003; 36 Cekovic, Z (WOS:000185774000001) 2003; 59 Chen, K (WOS:000256550600038) 2008; 130 Guo, JJ (WOS:000389224000023) 2016; 55 Yin, HL (WOS:000375889100040) 2016; 138 YOUNG, LB (WOS:A1969D986100021) 1969; 91 BRADLEY, DC (WOS:A1956WK65200062) 1956 Jeffrey, JL (WOS:000361707000046) 2015; 349 |
| References_xml | – ident: ref1/cit1c doi: 10.1126/science.1239176 – ident: ref3/cit3a doi: 10.1021/ja01495a061 – ident: ref10/cit10d doi: 10.1016/S0040-4039(01)90085-1 – ident: ref11/cit11c doi: 10.1021/ja4126609 – ident: ref12/cit12c doi: 10.1021/jacs.6b05712 – ident: ref10/cit10e doi: 10.1021/ja00091a063 – ident: ref5/cit5e doi: 10.1002/anie.201604704 – ident: ref13/cit13 doi: 10.1002/anie.201609035 – ident: ref2/cit2d doi: 10.1038/nature19811 – ident: ref4/cit4c doi: 10.1021/ol025580e – ident: ref5/cit5c doi: 10.1002/anie.201510014 – ident: ref4/cit4f doi: 10.1021/ja802491q – ident: ref4/cit4e doi: 10.1021/ol060952v – ident: ref10/cit10a doi: 10.1016/S0010-8545(98)00160-X – ident: ref2/cit2a doi: 10.1021/ja5056774 – ident: ref3/cit3g doi: 10.1039/C4OB00469H – ident: ref2/cit2e doi: 10.1038/nature19810 – ident: ref12/cit12b doi: 10.1021/jacs.6b02248 – ident: ref1/cit1a doi: 10.1039/B913880N – ident: ref2/cit2c doi: 10.1126/science.aac8555 – ident: ref16/cit16a doi: 10.1021/jo301840e – ident: ref4/cit4g doi: 10.1002/anie.201405418 – ident: ref10/cit10c doi: 10.1016/S0040-4020(01)98365-6 – ident: ref3/cit3c doi: 10.1016/0040-4020(95)00406-X – ident: ref12/cit12a doi: 10.1021/jacs.5b05411 – ident: ref3/cit3e doi: 10.1016/S0040-4020(03)01202-X – ident: ref4/cit4b doi: 10.1021/jo00171a066 – ident: ref5/cit5g doi: 10.1002/anie.201703611 – ident: ref15/cit15a doi: 10.1039/jr9560002260 – ident: ref17/cit17 doi: 10.1021/j100881a021 – ident: ref1/cit1b doi: 10.1021/cr300503r – ident: ref15/cit15d doi: 10.1021/acs.inorgchem.7b00828 – ident: ref11/cit11d doi: 10.1021/jacs.5b08452 – ident: ref14/cit14b doi: 10.1021/ja01026a022 – ident: ref11/cit11a doi: 10.1126/science.1226458 – ident: ref8/cit8a doi: 10.1021/acs.accounts.6b00272 – ident: ref3/cit3h doi: 10.1002/anie.201611463 – ident: ref6/cit6b doi: 10.1039/C7CC04941B – ident: ref11/cit11b doi: 10.1021/ja4060806 – ident: ref5/cit5f doi: 10.1021/jacs.7b05214 – ident: ref15/cit15c doi: 10.1021/ic00320a018 – ident: ref7/cit7 doi: 10.1021/ar020230d – ident: ref6/cit6c doi: 10.1002/anie.201709025 – ident: ref18/cit18 doi: 10.1039/C6RA17524D – ident: ref3/cit3d doi: 10.1055/s-2002-33335 – ident: ref15/cit15b doi: 10.1021/ja01046a021 – ident: ref8/cit8b doi: 10.1021/jacs.6b06517 – ident: ref10/cit10h doi: 10.1021/jacs.5b03192 – ident: ref10/cit10j doi: 10.1021/jacs.6b08397 – ident: ref3/cit3f doi: 10.1039/b613443m – ident: ref10/cit10g doi: 10.1039/c3ee43147a – ident: ref2/cit2b doi: 10.1126/science.1255525 – ident: ref9/cit9c doi: 10.1039/a904451e – ident: ref5/cit5b doi: 10.1002/anie.201501122 – ident: ref3/cit3b doi: 10.1021/cr60221a004 – ident: ref4/cit4d doi: 10.1021/jo026314h – ident: ref9/cit9b doi: 10.1021/ic00033a017 – ident: ref4/cit4a doi: 10.1039/b000705f – ident: ref5/cit5d doi: 10.1002/anie.201607305 – ident: ref16/cit16b doi: 10.1021/ol401061v – ident: ref14/cit14c doi: 10.1016/S1010-6030(01)00588-3 – ident: ref6/cit6a doi: 10.1021/jacs.7b09306 – ident: ref5/cit5a doi: 10.1021/acs.orglett.5b00582 – ident: ref14/cit14a doi: 10.1016/j.ica.2006.05.025 – volume-title: Photochemistry and Photophysics: Concepts, Research, Applications year: 2014 ident: ref9/cit9a – ident: ref10/cit10b doi: 10.1021/acs.accounts.6b00339 – ident: ref10/cit10i doi: 10.1021/acs.organomet.5b00568 – ident: ref11/cit11e doi: 10.1126/science.aad8313 – ident: ref10/cit10f doi: 10.1021/ja9807892 – volume: 137 start-page: 13902 year: 2015 ident: WOS:000364355900033 article-title: Photoinduced, Copper-Catalyzed Carbon-Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.5b08452 – volume: 12 start-page: 4051 year: 2014 ident: WOS:000336844400002 article-title: sp(3) C-H oxidation by remote H-radical shift with oxygen- and nitrogen-radicals: a recent update publication-title: ORGANIC & BIOMOLECULAR CHEMISTRY doi: 10.1039/c4ob00469h – volume: 130 start-page: 7247 year: 2008 ident: WOS:000256550600038 article-title: 1,3-diol synthesis via controlled, radical-mediated C-H functionalization publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja802491q – volume: 138 start-page: 12719 year: 2016 ident: WOS:000384952100003 article-title: Direct C(sp(3))-H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b08397 – volume: 136 start-page: 2162 year: 2014 ident: WOS:000331493700070 article-title: Photoinduced, Copper-Catalyzed Alkylation of Amides with Unactivated Secondary Alkyl Halides at Room Temperature publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja4126609 – volume: 4 start-page: 1295 year: 2002 ident: WOS:000174997600014 article-title: A convenient synthesis of C-22 and C-25 stereoisomers of cephalostatin north 1 side chain from spirostan sapogenins publication-title: ORGANIC LETTERS doi: 10.1021/ol025580e – volume: 8 start-page: 2819 year: 2006 ident: WOS:000238284500041 article-title: Efficient method for selective introduction of substituents as C(5) of isoleucine and other alpha-amino acids publication-title: ORGANIC LETTERS doi: 10.1021/ol060952v – volume: 17 start-page: 1894 year: 2015 ident: WOS:000353314800020 article-title: Visible-Light-Promoted Remote C(sp(3))-H Amidation and Chlorination publication-title: ORGANIC LETTERS doi: 10.1021/acs.orglett.5b00582 – volume: 55 start-page: 15319 year: 2016 ident: WOS:000389224000023 article-title: Photocatalytic C-C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201609035 – volume: 51 start-page: 7095 year: 1995 ident: WOS:A1995RE87800001 article-title: REMOTE INTRAMOLECULAR FREE-RADICAL FUNCTIONALIZATIONS - AN UPDATE publication-title: TETRAHEDRON – volume: 31 start-page: 1215 year: 1992 ident: WOS:A1992HM33900017 article-title: PHOTOCHEMICALLY PRODUCED COBALT(II) COMPLEXES WITH COORDINATED FREE-RADICALS - INTRAMOLECULAR OXIDATION OF THE METAL CENTER BY THE COORDINATED ALKYL RADICAL publication-title: INORGANIC CHEMISTRY – volume: 49 start-page: 2232 year: 2016 ident: WOS:000385908100019 article-title: Decatungstate Anion for Photocatalyzed "Window Ledge" Reactions publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/acs.accounts.6b00339 – volume: 59 start-page: 8073 year: 2003 ident: WOS:000185774000001 article-title: Reactions of delta-carbon radicals generated by 1,5-hydrogen transfer to alkoxyl radicals publication-title: TETRAHEDRON doi: 10.1016/S0040-4020(03)01202-X – volume: 539 start-page: 268 year: 2016 ident: WOS:000387318500040 article-title: Catalytic alkylation of remote C-H bonds enabled by proton-coupled electron transfer publication-title: NATURE doi: 10.1038/nature19811 – volume: 82 start-page: 2640 year: 1960 ident: WOS:A1960WB33700061 article-title: A NEW PHOTOCHEMICAL REACTION publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 138 start-page: 5984 year: 2016 ident: WOS:000375889100040 article-title: Cerium Photosensitizers: Structure-Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b02248 – volume: 53 start-page: 9539 year: 2014 ident: WOS:000342677000021 article-title: Total Synthesis of Gracilamine publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201405418 – volume: 359 start-page: 4130 year: 2006 ident: WOS:000240489200044 article-title: Excited state properties of lanthanide complexes: Beyond ff states publication-title: INORGANICA CHIMICA ACTA doi: 10.1016/j.ica.2006.05.025 – volume: 56 start-page: 8004 year: 2017 ident: WOS:000403839000060 article-title: Cooperative Light-Activated Iodine and Photoredox Catalysis for the Amination of C-sp3-H Bonds publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201703611 – volume: 351 start-page: 681 year: 2016 ident: WOS:000369810000033 article-title: Asymmetric copper-catalyzed C-N cross-couplings induced by visible light publication-title: SCIENCE doi: 10.1126/science.aad8313 – volume: 30 start-page: 94 year: 2001 ident: WOS:000167044500002 article-title: Radical translocation reactions in synthesis publication-title: CHEMICAL SOCIETY REVIEWS – volume: 55 start-page: 13495 year: 2016 ident: WOS:000385718300022 article-title: Catalytic Asymmetric C-sp3-H Functionalization under Photoredox Conditions by Radical Translocation and Stereocontrolled Alkene Addition publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201607305 – volume: 55 start-page: 1872 year: 2016 ident: WOS:000369854000052 article-title: Generation of Alkoxyl Radicals by Photoredox Catalysis Enables Selective C(sp(3))-H Functionalization under Mild Reaction Conditions publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201510014 – volume: 178 start-page: 1165 year: 1998 ident: WOS:000077809500009 article-title: Decatungstate photocatalysis publication-title: COORDINATION CHEMISTRY REVIEWS – volume: 539 start-page: 272 year: 2016 ident: WOS:000387318500041 article-title: Amide-directed photoredox-catalysed C-C bond formation at unactivated sp(3) C-H bonds publication-title: NATURE doi: 10.1038/nature19810 – volume: 349 start-page: 1532 year: 2015 ident: WOS:000361707000046 article-title: O-H hydrogen bonding promotes H-atom transfer from alpha C-H bonds for C-alkylation of alcohols publication-title: SCIENCE doi: 10.1126/science.aac8555 – volume: 6 start-page: 96693 year: 2016 ident: WOS:000386242500029 article-title: Visible light-mediated decarboxylative amination of indoline-2-carboxylic acids catalyzed by Rose Bengal publication-title: RSC ADVANCES doi: 10.1039/c6ra17524d – volume: 54 start-page: 8287 year: 2015 ident: WOS:000357209000050 article-title: An Iodine-Catalyzed Hofmann-Loffler Reaction publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201501122 – volume: 15 start-page: 2554 year: 2013 ident: WOS:000319720900058 article-title: Efficient C-H/C-N and C-H/C-CO-N Conversion via Decatungstate-Photoinduced Alkylation of Diisopropyl Azodicarboxylate publication-title: ORGANIC LETTERS doi: 10.1021/ol401061v – volume: 57 start-page: 1640 year: 2018 ident: WOS:000423494500038 article-title: Tertiary-Alcohol-Directed Functionalization of Remote C(sp(3))-H Bonds by Sequential Hydrogen Atom and Heteroaryl Migrations publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201709025 – volume: 70 start-page: 2845 year: 1966 ident: WOS:A19668256000021 article-title: ABSORPTION SPECTRA OF OCTAHEDRAL LANTHANIDE HEXAHALIDES publication-title: JOURNAL OF PHYSICAL CHEMISTRY – volume: 91 start-page: 5060 year: 1969 ident: WOS:A1969D986100021 article-title: OXIDATION OF ORGANIC COMPOUNDS WITH CERIUM(4) .7. FORMATION CONSTANTS FOR 1 - 1 CERIUM(4)-ALCOHOL COMPLEXES publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 28 start-page: 4027 year: 1989 ident: WOS:A1989AW24900018 article-title: SYNTHETIC AND STRUCTURAL STUDIES OF A SERIES OF SOLUBLE CERIUM(IV) ALKOXIDE AND ALKOXIDE NITRATE COMPLEXES publication-title: INORGANIC CHEMISTRY – volume: 77 start-page: 9959 year: 2012 ident: WOS:000311073000003 article-title: Radical Amination of C(sp(3))-H Bonds Using N-Hydroxyphthalimide and Dialkyl Azodicarboxylate publication-title: JOURNAL OF ORGANIC CHEMISTRY doi: 10.1021/jo301840e – volume: 21 start-page: 2799 year: 1965 ident: WOS:A19656814200009 article-title: LEAD TETRAACETATE OXIDATION OF SATURATED ALIPHATIC ALCOHOLS .3. UNBRANCHED PRIMARY AND SECONDARY ALCOHOLS publication-title: TETRAHEDRON – volume: 116 start-page: 5473 year: 1994 ident: WOS:A1994NR60500063 article-title: REMOTE CARBONYLATION - THE SYNTHESIS OF DELTA-LACTONES FROM SATURATED ALCOHOLS AND CARBON-MONOXIDE publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 56 start-page: 1960 year: 2017 ident: WOS:000397323300002 article-title: Controllable Remote C-H Bond Functionalization by Visible-Light Photocatalysis publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201611463 – start-page: 3565 year: 1999 ident: WOS:000083147800010 article-title: Use of a radical clock to study the photodecarboxylation of amino acidatocobalt(III) complexes publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS – volume: 338 start-page: 647 year: 2012 ident: WOS:000310516000048 article-title: Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway publication-title: SCIENCE doi: 10.1126/science.1226458 – volume: 136 start-page: 12217 year: 2014 ident: WOS:000341226000006 article-title: Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C-N Bond Formation publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja5056774 – volume: 138 start-page: 10794 year: 2016 ident: WOS:000382513300020 article-title: Catalytic Ring-Opening of Cyclic Alcohols Enabled by PCET Activation of Strong O-H Bonds publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b06517 – volume: 113 start-page: 5322 year: 2013 ident: WOS:000321810600018 article-title: Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis publication-title: CHEMICAL REVIEWS doi: 10.1021/cr300503r – volume: 139 start-page: 10204 year: 2017 ident: WOS:000407089500010 article-title: Directed beta C-H Amination of Alcohols via Radical Relay Chaperones publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.7b05214 – volume: 48 start-page: 4430 year: 1983 ident: WOS:A1983RR87700066 article-title: INTRAMOLECULAR FUNCTIONALIZATION OF PHOSPHORAMIDATE RADICALS - SYNTHESIS OF 1,4-EPIMINE COMPOUNDS publication-title: JOURNAL OF ORGANIC CHEMISTRY – volume: 146 start-page: 63 year: 2001 ident: WOS:000172629800008 article-title: Excited state behavior of tetrakis(2,2,6,6-tetramethyl-3,5-heptane-dionato)cerium(IV) - Emission and photoredox reaction from ligand-to-metal charge transfer states publication-title: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY – volume: 7 start-page: 954 year: 2014 ident: WOS:000333203900008 article-title: Visible light driven photocatalysis mediated via ligand-to-metal charge transfer (LMCT): an alternative approach to solar activation of titania publication-title: ENERGY & ENVIRONMENTAL SCIENCE doi: 10.1039/c3ee43147a – volume: 34 start-page: 4766 year: 2015 ident: WOS:000362863600017 article-title: Halogen Photoelimination from Monomeric Nickel(III) Complexes Enabled by the Secondary Coordination Sphere publication-title: ORGANOMETALLICS doi: 10.1021/acs.organomet.5b00568 – start-page: 2260 year: 1956 ident: WOS:A1956WK65200062 article-title: STRUCTURAL CHEMISTRY OF THE ALKOXIDES .6. PRIMARY ALKOXIDES OF QUADRIVALENT CERIUM AND THORIUM publication-title: JOURNAL OF THE CHEMICAL SOCIETY – volume: 90 start-page: 6688 year: 1968 ident: WOS:A1968C120800022 article-title: PHOTOCHEMICAL AND THERMAL REDUCTION OF CERIUM(4) CARBOXYLATES . FORMATION AND OXIDATION OF ALKYL RADICALS publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 63 start-page: 55 year: 1963 ident: WOS:A19638640A00005 article-title: CYCLIZATION OF N-HALOGENATED AMINES (HOFMANN-LOFFLER REACTION publication-title: CHEMICAL REVIEWS – volume: 345 start-page: 437 year: 2014 ident: WOS:000339655100039 article-title: Merging photoredox with nickel catalysis: Coupling of alpha-carboxyl sp(3)-carbons with aryl halides publication-title: SCIENCE doi: 10.1126/science.1255525 – volume: 40 start-page: 102 year: 2011 ident: WOS:000285390900008 article-title: Visible light photoredox catalysis: applications in organic synthesis publication-title: CHEMICAL SOCIETY REVIEWS doi: 10.1039/b913880n – volume: 137 start-page: 9234 year: 2015 ident: WOS:000358896600010 article-title: Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.5b05411 – year: 2014 ident: 000424851500012.2 publication-title: Photochemistry and Photophysics: Concepts, Research, Applications – volume: 36 start-page: 255 year: 2003 ident: WOS:000182343300004 article-title: Bond dissociation energies of organic molecules publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/ar020230d – volume: 137 start-page: 6472 year: 2015 ident: WOS:000355383500013 article-title: Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.5b03192 – volume: 138 start-page: 16266 year: 2016 ident: WOS:000390729500020 article-title: The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.6b05712 – volume: 49 start-page: 1546 year: 2016 ident: WOS:000381654700011 article-title: Synthetic Applications of Proton-Coupled Electron Transfer publication-title: ACCOUNTS OF CHEMICAL RESEARCH doi: 10.1021/acs.accounts.6b00272 – volume: 135 start-page: 13107 year: 2013 ident: WOS:000330163100033 article-title: A Versatile Approach to Ullmann C-N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper-Catalyzed Processes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/ja4060806 – volume: 343 start-page: 985 year: 2014 ident: WOS:000332309600033 article-title: Solar Synthesis: Prospects in Visible Light Photocatalysis publication-title: SCIENCE doi: 10.1126/science.1239176 – volume: 120 start-page: 8692 year: 1998 ident: WOS:000075741300015 article-title: New strategies in carbonylation chemistry: The synthesis of delta-lactones from saturated alcohols and CO publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – start-page: 1469 year: 2002 ident: WOS:000177737000001 article-title: Selectivity in the chemistry of oxygen-centered radicals - The formation of carbon-oxygen bonds publication-title: SYNTHESIS-STUTTGART – volume: 139 start-page: 14897 year: 2017 ident: WOS:000414115800020 article-title: Directed gamma-C(sp(3))-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY doi: 10.1021/jacs.7b09306 – volume: 68 start-page: 1012 year: 2003 ident: WOS:000180834600045 article-title: Intramolecular hydrogen abstraction reaction promoted by N-radicals in carbohydrates. Synthesis of chiral 7-oxa-2-azabicyclo[2.2.1]heptane and 8-oxa-6-azabicyclo[3.2.1]octane ring systems publication-title: JOURNAL OF ORGANIC CHEMISTRY doi: 10.1021/jo026314h – volume: 37 start-page: 1603 year: 2008 ident: WOS:000257839100014 article-title: Recent progress in the generation and use of nitrogen-centred radicals publication-title: CHEMICAL SOCIETY REVIEWS doi: 10.1039/b613443m – volume: 25 start-page: 1953 year: 1984 ident: WOS:A1984SP58500026 article-title: INTRAMOLECULAR HYDROGEN ABSTRACTION - IODOSOBENZENE DIACETATE, AN EFFICIENT AND CONVENIENT REAGENT FOR ALKOXY RADICAL GENERATION publication-title: TETRAHEDRON LETTERS – volume: 56 start-page: 8114 year: 2017 ident: WOS:000405972200056 article-title: Cerium(IV) Neopentoxide Complexes publication-title: INORGANIC CHEMISTRY doi: 10.1021/acs.inorgchem.7b00828 – volume: 53 start-page: 8964 year: 2017 ident: WOS:000407169500007 article-title: Asymmetric alkylation of remote C(sp(3))-H bonds by combining proton-coupled electron transfer with chiral Lewis acid catalysis publication-title: CHEMICAL COMMUNICATIONS doi: 10.1039/c7cc04941b – volume: 55 start-page: 9974 year: 2016 ident: WOS:000383373000028 article-title: Triiodide-Mediated delta-Amination of Secondary C-H Bonds publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION doi: 10.1002/anie.201604704 |
| SSID | ssj0004281 |
| Score | 2.6481783 |
| Snippet | We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy... |
| Source | Web of Science |
| SourceID | proquest pubmed webofscience crossref acs |
| SourceType | Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 1612 |
| SubjectTerms | alcohols carbon-hydrogen bond activation catalysts cerium chemical bonding Chemistry Chemistry, Multidisciplinary free radicals Physical Sciences Science & Technology |
| Title | δ‑Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer |
| URI | http://dx.doi.org/10.1021/jacs.7b13131 http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000424851500012 https://www.ncbi.nlm.nih.gov/pubmed/29381061 https://www.proquest.com/docview/1993008608 https://www.proquest.com/docview/2116861539 |
| Volume | 140 |
| WOS | 000424851500012 |
| WOSCitedRecordID | wos000424851500012 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1LT-MwELYQHODCa1koLxkJTshV4zh2ckRVC0KwF5YVt8rxY7VqSRBND3DiL_Bf-B38CH4JYydpeVXLKUoyeXgyznzjeSG0z6wD8iklSkhFGJURkTrVBORFg8IMWon0AbK_-MklO72KriYBsh89-NTVB1LDpkiDMHDp0nOUg4Q5CNS-mOQ_0jioYa6IeVgFuH-82ikgNXyvgD6hyi8VkFc23SV0XKfslDEm_eaoSJvq_nMFx_-MYxktVngTH5UCsoJmTLaK5tt1m7cf6Pr56eXh8cK3w4E_H-6CoivXB6sMTZxbfDToyywfDHHHp1ppnN7hP_9gNg0MOfOlSFwLEAUnYE9mmhQ5OTeA67Fz5_812KtEa27X0GW387t9QqoeDESGkSgIZTIBGGFpYsOUcQ5bLkwrCU3KgNUJ4xEYJC5YSsUqDK3RmgkrtaBGJ2BahT_RbJZnZgPhgNookoJxuDOLQQ-6yj0cDDShbGB40kB7wKJeNYeGPe8ep2CeuKMV4xrosP54PVUVMXe9NAZTqA_G1Ddl8Y4pdHu1HPSA-85lIjOTj-AdAL45q68VT6cBE5rHDjfDCNZLIRo_DcBU7IzuBtp_K1Xj8154GaDeyC8JNlDwHbJ2NXJXtqDY_AbbttACAL3YR5uLbTRb3I7MDoCpIt31M-kVBOMWyA |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3JbtswECWK5JBeui_uygDpqWBgURQpHQ0jhts6viQpchMoLkERVyoi-dCe-gv9l3xHPiJf0hmadtq0BnwSRI0ocjTUvBFnIWRPeATyFWdGacME1xnTtrIM5MWCwkz6hQ4OslM5PhEfT7PTGKyOsTAwiBZ6asMm_k12AUwTBI2qStIEo6a3AYdwrNQwGB7dhEHyPFmiXZXLNPq5374b9ZBp_9ZD_4DL_-qhoHNG98l0NdrganK-P--qffPjViLHjafzgNyL6JMOFuLykNxx9SOyM1wWfXtMvl5dXv_8dRSK48B3kI5A7S3-FsZ4Tdp4Opid67qZtfQgBF5ZWn2nn7_A2po5NgmJSbAgiIELcKZry7qGHTpA-RQ3988cDQrSu4sn5GR0cDwcs1iRgek0Ux3jQhcAKjwvfFoJKeEolesXqasEcLwQMgPzBF2nTG7S1DtrhfLaKu5sAYZW-pRs1U3tnhOacJ9lWgkJPYsctCLm8ZFgrinjEyeLHtkFFpVxRbVl2CznYKxga2Rcj7xfvsPSxJTmWFljtob63Yr62yKVxxq63aU4lMB93EDRtWvmMAYAc2gD9vP1NGBQyxxRNMzg2UKWVk8DaJWjCd4je38K1-p6kGEBGDgLPwh7JNmEbBhnjkkMuhcbsO0t2RkfH07KyYfpp5fkLkDAPPihq1dkq7uYu9cAs7rqTVhcvwGvbR8p |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NbtQwEB5VrQRcyj8sv65UTsjVJnHs5LhauipQKkQp6i1y_INQt0nVZA_tqa_Au_AcPARPwow3WaCwUjlFG0-y9mSc-SbzB7ApPAH5MuZGacNFrFOubWk5yotFhRkNcx0CZPfkzoF4c5gerkDU58LgJBq8UxOc-LSrT6zvKgxQqSAcUGWURJQ5vUYeO-rWMBrv_0qFjLOoR7wqk0kX6375atJFpvlTF_0FMP-pi4LemdyED4sZh3CTo61ZW26Z80vFHP9rSbdgvUOhbDQXm9uw4qo7cH3cN3-7C8ffv_24-LofmuTg-5BNUP3Nvxp2eZus9mw0PdJVPW3YdkjAsqw8Y5--4B6bOr4bCpRQYxCDA_hLV5a3NX_nEO0zcvJ_diwoSu9O78HBZPvjeId3nRm4TlLV8ljoHMGFj3OflEJKPErlhnniSoFczwU-GaEohMpkJkm8s1Yor62Knc3R4Eruw2pVV-4hsCj2aaqVkHhnkaF2pHo-Es02ZXzkZD6ADWRR0e2spghO8xiNFjrbMW4AL_vnWJiutDl12JguoX6xoD6Zl_RYQrfRi0SB3CdHiq5cPcM5IKgjW3CYLadBw1pmhKZxBQ_m8rT4N4RYGZniA9j8XcAW40GOBWLhNHwoHEB0FbJxt3IqZtA-ugLbnsO1968mxe7rvbeP4QYiwSyEo6snsNqeztxTRFtt-Szsr58AkCGs |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%CE%B4-Selective+Functionalization+of+Alkanols+Enabled+by+Visible-Light-Induced+Ligand-to-Metal+Charge+Transfer&rft.jtitle=Journal+of+the+American+Chemical+Society&rft.au=Hu%2C+Anhua&rft.au=Guo%2C+Jing-Jing&rft.au=Pan%2C+Hui&rft.au=Tang%2C+Haoming&rft.date=2018-02-07&rft.issn=0002-7863&rft.eissn=1520-5126&rft.volume=140&rft.issue=5&rft.spage=1612&rft.epage=1616&rft_id=info:doi/10.1021%2Fjacs.7b13131&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_jacs_7b13131 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0002-7863&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0002-7863&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0002-7863&client=summon |