Uranium in geologic fluids: Estimates of standard partial molal properties, oxidation potentials, and hydrolysis constants at high temperatures and pressures

• Published in: Geochimica et cosmochimica acta Vol. 61; no. 20; pp. 4245 - 4266
• Main Authors: Shock, Everett L., Sassani, David C., Betz, Heidi
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.1997

Theoretical methods are used with the available experimental data to provide estimates of parameters for the revised-HKF equations of state for aqueous uranium species. These parameters are used with standard state thermodynamic data at 25°C and 1 bar to calculate equilibrium constants for redox rea...