Volumetric Properties of Binary Mixtures Containing Ionic Liquids and Some Aprotic Solvents
Densities of six binary mixtures containing the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide or 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide mixed with tetrahydrofuran or acetonitrile or dimethyl sulfoxide were determined at atmospheric pressures in the...
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Published in | Journal of chemical and engineering data Vol. 55; no. 9; pp. 4114 - 4120 |
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Main Authors | , , , |
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Language | English |
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American Chemical Society
09.09.2010
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Abstract | Densities of six binary mixtures containing the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide or 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide mixed with tetrahydrofuran or acetonitrile or dimethyl sulfoxide were determined at atmospheric pressures in the temperature range between 293.15 K and 313.15 K. On the basis of the experimental densities, excess molar volumes were calculated. Comparison of excess molar volumes of six binary systems reveals the slight influence of the IL’s cation on these physical properties and the small temperature dependence of V E for systems containing dimethyl sulfoxide. |
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AbstractList | Densities of six binary mixtures containing the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide or 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide mixed with tetrahydrofuran or acetonitrile or dimethyl sulfoxide were determined at atmospheric pressures in the temperature range between 293.15 K and 313.15 K. On the basis of the experimental densities, excess molar volumes were calculated. Comparison of excess molar volumes of six binary systems reveals the slight influence of the IL’s cation on these physical properties and the small temperature dependence of V E for systems containing dimethyl sulfoxide. |
Author | Golus, Aleksandra Lehmann, Jochen K Geppert-Rybczyńska, Monika Heintz, Andreas |
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Keywords | Binary mixture Organic solvent Methyl sulfoxide Molar volume Acetonitrile Excess parameter Thermodynamic properties Density Aprotic solvent Tetrahydrofurane Ionic liquid |
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SubjectTerms | Chemical thermodynamics Chemistry Exact sciences and technology General and physical chemistry Mixtures Thermodynamic properties |
Title | Volumetric Properties of Binary Mixtures Containing Ionic Liquids and Some Aprotic Solvents |
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