High Magnetic Field Magneto-optics on Plasmonic Silica-Embedded Silver Nanoparticles

Tuning the plasmonic response with an external magnetic field is extremely promising to achieve active magnetoplasmonic devices, such as next generation refractometric sensors or tunable optical components. Noble metal nanostructures represent an ideal platform for studying and modeling magnetoplasm...

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Published inJournal of physical chemistry. C Vol. 126; no. 4; pp. 1939 - 1945
Main Authors Gabbani, Alessio, Campo, Giulio, Bonanni, Valentina, van Rhee, Peter, Bottaro, Gregorio, de Julián Fernández, César, Bello, Valentina, Fantechi, Elvira, Biccari, Francesco, Gurioli, Massimo, Armelao, Lidia, Sangregorio, Claudio, Mattei, Giovanni, Christianen, Peter, Pineider, Francesco
Format Journal Article
LanguageEnglish
Published American Chemical Society 03.02.2022
Subjects
absorption
C: Spectroscopy and Dynamics of Nano, Hybrid, and Low-Dimensional Materials
circular dichroism spectroscopy
energy
magnetic fields
nanosilver
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Abstract Tuning the plasmonic response with an external magnetic field is extremely promising to achieve active magnetoplasmonic devices, such as next generation refractometric sensors or tunable optical components. Noble metal nanostructures represent an ideal platform for studying and modeling magnetoplasmonic effects through the interaction of free electrons with external magnetic fields, even though their response is relatively low at the magnetic field intensities commonly applied in standard magneto-optical spectroscopies. Here we demonstrate a large magnetoplasmonic response of silver nanoparticles by performing magnetic circular dichroism spectroscopy at high magnetic fields, revealing a linear response to the magnetic field up to 30 T. The exploitation of such high fields allowed us to probe directly the field-induced splitting of circular plasmonic modes by performing absorption spectra with static circular polarizations, giving direct experimental evidence that the magneto-optical activity of plasmonic nanoparticles arises from the energy shift of field-split circular magnetoplasmonic modes.
AbstractList Tuning the plasmonic response with an external magnetic field is extremely promising to achieve active magnetoplasmonic devices, such as next generation refractometric sensors or tunable optical components. Noble metal nanostructures represent an ideal platform for studying and modeling magnetoplasmonic effects through the interaction of free electrons with external magnetic fields, even though their response is relatively low at the magnetic field intensities commonly applied in standard magneto-optical spectroscopies. Here we demonstrate a large magnetoplasmonic response of silver nanoparticles by performing magnetic circular dichroism spectroscopy at high magnetic fields, revealing a linear response to the magnetic field up to 30 T. The exploitation of such high fields allowed us to probe directly the field-induced splitting of circular plasmonic modes by performing absorption spectra with static circular polarizations, giving direct experimental evidence that the magneto-optical activity of plasmonic nanoparticles arises from the energy shift of field-split circular magnetoplasmonic modes.
Author Bonanni, Valentina
Pineider, Francesco
Gabbani, Alessio
Gurioli, Massimo
Bello, Valentina
Sangregorio, Claudio
Campo, Giulio
Biccari, Francesco
Christianen, Peter
de Julián Fernández, César
Mattei, Giovanni
van Rhee, Peter
Armelao, Lidia
Bottaro, Gregorio
Fantechi, Elvira
AuthorAffiliation CNR-ICCOM
INSTM and Department of Chemistry
High Field Magnet Laboratory (HFML - EMFL)
Department of Physics and Astronomy
INSTM and Dipartimento di Scienze Chimiche
Dipartimento di Scienze Chimiche e Tecnologie dei Materiali (DSCTM)
INSTM and Department of Chemistry and Industrial Chemistry
Università di Padova
University of Padova
Department of Physics
Consiglio-Nazionale delle Ricerche
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Snippet Tuning the plasmonic response with an external magnetic field is extremely promising to achieve active magnetoplasmonic devices, such as next generation...
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SubjectTerms absorption
C: Spectroscopy and Dynamics of Nano, Hybrid, and Low-Dimensional Materials
circular dichroism spectroscopy
energy
magnetic fields
nanosilver
Title High Magnetic Field Magneto-optics on Plasmonic Silica-Embedded Silver Nanoparticles
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