High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene
Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(...
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| Published in | Macromolecules Vol. 43; no. 18; pp. 7577 - 7582 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Washington, DC
American Chemical Society
28.09.2010
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| Subjects | |
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| Abstract | Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics. |
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| AbstractList | Conjugated polymers derived from thiophene or 3,4-ethylenedioxythiophene derivatives have been widely investigated for use in organic thin-film transistors and organic photovoltaic devices. We describe here the synthesis of a series of conjugated microporous polymers formed by reaction of spiro-bis(2,5-dibromopropylenedioxythiophene) with one of three di- or triethynyl monomers. These polymers have surface areas up to 1631 m2/g and exhibit significant microporosity, suggesting possible applications in the fields of organic electronics or optoelectronics. |
| Author | Laybourn, Andrea Khimyak, Yaroslav Z Higgins, Simon J Adams, Dave J Cooper, Andrew I Jiang, Jia-Xing Bacsa, John Clowes, Rob |
| Author_xml | – sequence: 1 givenname: Jia-Xing surname: Jiang fullname: Jiang, Jia-Xing – sequence: 2 givenname: Andrea surname: Laybourn fullname: Laybourn, Andrea – sequence: 3 givenname: Rob surname: Clowes fullname: Clowes, Rob – sequence: 4 givenname: Yaroslav Z surname: Khimyak fullname: Khimyak, Yaroslav Z – sequence: 5 givenname: John surname: Bacsa fullname: Bacsa, John – sequence: 6 givenname: Simon J surname: Higgins fullname: Higgins, Simon J – sequence: 7 givenname: Dave J surname: Adams fullname: Adams, Dave J – sequence: 8 givenname: Andrew I surname: Cooper fullname: Cooper, Andrew I |
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| Keywords | Solution polycondensation Hydrogen Phenyleneethynylene copolymer Adsorption isotherm Experimental study Dimension spectrum Porous material Crosslinked copolymer Gas solid adsorption Spiran copolymer Pore size Microporosity Conjugated copolymer Preparation Surface area Thiophene derivative copolymer |
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| SubjectTerms | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts |
| Title | High Surface Area Contorted Conjugated Microporous Polymers Based on Spiro-Bipropylenedioxythiophene |
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