Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]

The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been re...

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Published inNano letters Vol. 4; no. 3; pp. 399 - 402
Main Authors Steckel, Jonathan S, Persky, Nicole S, Martinez, Chelsea R, Barnes, Calvin L, Fry, Elizabeth A, Kulkarni, Jaideep, Burgess, James D, Pacheco, Rachel B, Stoll, Sarah L
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.03.2004
Subjects
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Materials science
Methods of nanofabrication
Physics
Self-assembly
Inorganic compounds
Transition element compounds
Nanostructures
Metal clusters
Experimental study
Ellipsometry
Thin films
Thickness
Multilayers
Absorbance
Self-assembly
Monolayers
Manganese complexes
Online AccessGet full text
ISSN1530-6984
1530-6992
DOI10.1021/nl0343553

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Abstract The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been reported. Here we demonstrate a simple approach using functionalized self-assembled monolayers and short-chain polyelectrolytes to make monolayer and nanometer-scale multilayer films of Mn-12.
AbstractList The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been reported. Here we demonstrate a simple approach using functionalized self-assembled monolayers and short-chain polyelectrolytes to make monolayer and nanometer-scale multilayer films of Mn-12.
Author Barnes, Calvin L
Fry, Elizabeth A
Pacheco, Rachel B
Stoll, Sarah L
Steckel, Jonathan S
Martinez, Chelsea R
Burgess, James D
Persky, Nicole S
Kulkarni, Jaideep
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  surname: Barnes
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Issue 3
Keywords Inorganic compounds
Transition element compounds
Nanostructures
Metal clusters
Experimental study
Ellipsometry
Thin films
Thickness
Multilayers
Absorbance
Self-assembly
Monolayers
Manganese complexes
Language English
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Snippet The manganese oxo-cluster, [Mn12O12(O2CMe)16(H2O)4]·2(HO2CMe)·4(H2O), (Mn-12), has been the subject of intense interest for its novel magnetic properties....
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StartPage 399
SubjectTerms Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Materials science
Methods of nanofabrication
Physics
Self-assembly
Title Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]
URI http://dx.doi.org/10.1021/nl0343553
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