Photoinduced Intramolecular Charge Transfer Reaction in (E)-3-(4-Methylamino-phenyl)-acrylic Acid Methyl Ester:  A Fluorescence Study in Combination with TDDFT Calculation

A donor−acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical behavior obtained spectroscopically has been compared with the theoretical results. The observed dual fluorescence from MAPAME has been assigned to...

Full description

Saved in:
Bibliographic Details
Published inThe journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 110; no. 44; pp. 12089 - 12095
Main Authors Chakraborty, Amrita, Kar, Samiran, Nath, D. N, Guchhait, Nikhil
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 09.11.2006
Online AccessGet full text

Cover

Abstract A donor−acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical behavior obtained spectroscopically has been compared with the theoretical results. The observed dual fluorescence from MAPAME has been assigned to emission from locally excited and twisted intramolecular charge transfer states. The donor and acceptor angular dependency on the ground and excited states potential energy surfaces have been calculated both in vacuo and in acetonitrile solvent using time dependent density functional theory (TDDFT) and TDDFT polarized continuum model (TDDFT-PCM), respectively. Calculation predicts that a stabilized twisted excited state is responsible for red shifted charge transfer emission.
AbstractList A donor-acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical behavior obtained spectroscopically has been compared with the theoretical results. The observed dual fluorescence from MAPAME has been assigned to emission from locally excited and twisted intramolecular charge transfer states. The donor and acceptor angular dependency on the ground and excited states potential energy surfaces have been calculated both in vacuo and in acetonitrile solvent using time dependent density functional theory (TDDFT) and TDDFT polarized continuum model (TDDFT-PCM), respectively. Calculation predicts that a stabilized twisted excited state is responsible for red shifted charge transfer emission.
A donor−acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical behavior obtained spectroscopically has been compared with the theoretical results. The observed dual fluorescence from MAPAME has been assigned to emission from locally excited and twisted intramolecular charge transfer states. The donor and acceptor angular dependency on the ground and excited states potential energy surfaces have been calculated both in vacuo and in acetonitrile solvent using time dependent density functional theory (TDDFT) and TDDFT polarized continuum model (TDDFT-PCM), respectively. Calculation predicts that a stabilized twisted excited state is responsible for red shifted charge transfer emission.
Author Chakraborty, Amrita
Kar, Samiran
Guchhait, Nikhil
Nath, D. N
Author_xml – sequence: 1
  givenname: Amrita
  surname: Chakraborty
  fullname: Chakraborty, Amrita
– sequence: 2
  givenname: Samiran
  surname: Kar
  fullname: Kar, Samiran
– sequence: 3
  givenname: D. N
  surname: Nath
  fullname: Nath, D. N
– sequence: 4
  givenname: Nikhil
  surname: Guchhait
  fullname: Guchhait, Nikhil
BackLink https://www.ncbi.nlm.nih.gov/pubmed/17078602$$D View this record in MEDLINE/PubMed
BookMark eNptkc1u1DAQxyNURD_gwAsgX0Ddg8HOh5P0tkp3t5UWsaIBpF4sx5kQL4m92IkgN648DC_Fk5CQVbmgOcxo5qf_jOZ_7p1oo8HznlPymhKfvtkfCPPTJGSPvDMa-QRHPo1OxpokKY5YkJ56587tCSE08MMn3imNSZww4p95v3a16YzSZS-hRLe6s6I1Dci-ERZltbCfAeVWaFeBRe9ByE4ZjZRGl6sFDvBliN9CVw-NaJU2-FCDHpoFFtIOjZJoKVWJZgCtXAf26vePn2iJ1k1vLDgJWgK66_pymCQz0xZKi78bvqmuRvn19TpHmWimc6b2U-9xJRoHz475wvuwXuXZDd6-29xmyy0WQUQ7XKRCFiIBxsAPY5-FYRCURPpVUSXMp0EIVBIRlfEUSRpIRguQoqoYjZKUVsGF92rWPVjztQfX8VaN1zaN0GB6x1lCCY0oHcHFDEprnLNQ8YNVrbADp4RP3vAHb0b2xVG0L1oo_5FHM0YAz4AaX_X9YS7sF87iII54vrvj283Hm_vNp3u-G_mXMy-k43vTWz3-5D-L_wAG8ai8
CitedBy_id crossref_primary_10_1002_cphc_200900161
crossref_primary_10_1016_j_jlumin_2012_03_036
crossref_primary_10_1016_j_jphotochem_2018_07_027
crossref_primary_10_1021_jp1095536
crossref_primary_10_1111_j_1751_1097_2009_00625_x
crossref_primary_10_1007_s10847_012_0146_4
crossref_primary_10_1016_j_molstruc_2011_05_022
crossref_primary_10_1021_acsomega_8b02717
crossref_primary_10_1016_j_molstruc_2009_05_049
crossref_primary_10_1016_j_jlumin_2010_02_036
crossref_primary_10_1016_j_chemphys_2008_10_002
crossref_primary_10_1007_s11224_012_9979_0
crossref_primary_10_1016_j_jphotochem_2012_04_002
crossref_primary_10_1039_C6RA00376A
crossref_primary_10_1016_j_jlumin_2016_01_029
crossref_primary_10_1016_j_jcis_2011_07_074
crossref_primary_10_1021_jp101862w
crossref_primary_10_1016_j_jphotochem_2019_112211
crossref_primary_10_1016_j_jphotochem_2013_04_005
crossref_primary_10_1134_S0036024409030194
crossref_primary_10_1021_jo100898a
crossref_primary_10_1016_j_jphotochem_2010_05_020
crossref_primary_10_1021_jp9007224
crossref_primary_10_1016_j_jlumin_2008_11_025
crossref_primary_10_1016_j_jphotobiol_2010_07_016
crossref_primary_10_1016_j_molstruc_2008_07_007
crossref_primary_10_1016_j_jlumin_2008_01_015
crossref_primary_10_1016_j_jlumin_2014_01_031
crossref_primary_10_1080_00958972_2013_864393
crossref_primary_10_1002_poc_3185
crossref_primary_10_1039_c2cp23879a
crossref_primary_10_1002_cphc_201000457
crossref_primary_10_1007_s10895_010_0707_0
crossref_primary_10_1007_s00214_015_1802_8
crossref_primary_10_1007_s12648_012_0041_2
crossref_primary_10_1016_j_jphotochem_2015_07_006
crossref_primary_10_1021_jp100004t
crossref_primary_10_1016_j_saa_2009_10_033
crossref_primary_10_1016_j_chemphys_2007_09_015
crossref_primary_10_1039_c9pp00108e
crossref_primary_10_1016_j_jphotochem_2007_08_030
crossref_primary_10_1016_j_dyepig_2013_10_040
crossref_primary_10_1016_j_jphotochem_2007_12_011
crossref_primary_10_1016_j_jphotobiol_2007_12_006
crossref_primary_10_1021_acs_jpca_3c07763
crossref_primary_10_1021_jp2094752
crossref_primary_10_1016_j_saa_2010_11_010
crossref_primary_10_1016_j_molstruc_2016_06_005
crossref_primary_10_1007_s10895_010_0660_y
crossref_primary_10_1007_s10876_016_1090_z
crossref_primary_10_1002_poc_1498
crossref_primary_10_1016_j_jlumin_2011_06_058
crossref_primary_10_1002_poc_3513
crossref_primary_10_1016_j_saa_2011_09_038
crossref_primary_10_1002_cphc_201100885
crossref_primary_10_1039_c0pp00309c
crossref_primary_10_1016_j_jphotochem_2010_04_011
crossref_primary_10_1016_j_saa_2014_08_130
crossref_primary_10_1021_jp0759731
Cites_doi 10.1002/(SICI)1097-461X(1998)70:4/5<933::AID-QUA39>3.0.CO;2-Z
10.1063/1.476878
10.1063/1.1318750
10.1021/ja0490572
10.1021/jp000156l
10.1016/S1010-6030(00)00423-8
10.1021/ja00426a036
10.1021/ja020361+
10.1002/ange.19610732103
10.1021/ja037806u
10.1351/pac199365081745
10.1016/j.cplett.2005.05.023
10.1007/978-1-4757-3061-6
10.1021/jp001665q
10.1063/1.1465404
10.1016/j.chemphys.2005.06.031
10.1021/jp026404q
10.1063/1.1850097
10.1021/cr940745l
10.1063/1.1498817
10.1016/0022-2313(92)90069-L
10.1063/1.2197829
10.1063/1.1394921
10.1021/j100625a025
10.1021/jp9625669
10.1021/j100205a041
10.1016/S1010-6030(98)00303-7
10.1246/bcsj.29.465
10.1016/0009-2614(96)00014-0
10.1016/0009-2614(96)00724-5
10.1016/0009-2614(73)80367-7
10.1016/j.chemphys.2005.12.032
10.1063/1.480544
10.1016/j.cplett.2005.03.018
10.1016/S0009-2614(97)00668-4
10.1021/ja991834o
10.1016/j.jphotochem.2005.12.004
10.1063/1.1627292
10.1063/1.1498818
10.1016/0022-2313(91)90048-Z
ContentType Journal Article
Copyright Copyright © 2006 American Chemical Society
Copyright_xml – notice: Copyright © 2006 American Chemical Society
DBID BSCLL
NPM
AAYXX
CITATION
7X8
DOI 10.1021/jp0629846
DatabaseName Istex
PubMed
CrossRef
MEDLINE - Academic
DatabaseTitle PubMed
CrossRef
MEDLINE - Academic
DatabaseTitleList MEDLINE - Academic
PubMed
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1520-5215
EndPage 12095
ExternalDocumentID 10_1021_jp0629846
17078602
ark_67375_TPS_LGVHZGWZ_P
c921905388
Genre Journal Article
GroupedDBID -
.K2
02
123
186
29L
4.4
53G
55A
5VS
7~N
85S
8RP
AABXI
ABFLS
ABMVS
ABPPZ
ABPTK
ABUCX
ACGFS
ACNCT
ACS
AEESW
AENEX
AETEA
AFEFF
AFFNX
ALMA_UNASSIGNED_HOLDINGS
ANTXH
AQSVZ
BAANH
CJ0
CS3
D0L
DU5
EBS
ED
ED~
EJD
F20
F5P
GNL
IH9
IHE
JG
JG~
K2
LG6
OHM
PZZ
RNS
ROL
TAE
TN5
UI2
UKR
UNC
UPT
UQL
VF5
VG9
VQA
VQP
W1F
WH7
X
XFK
YZZ
ZCG
ZHY
---
-~X
.DC
6TJ
ABFRP
ABJNI
ABQRX
ACBEA
ADHLV
AHGAQ
BSCLL
GGK
XSW
YQT
~02
CUPRZ
NPM
AAYXX
CITATION
7X8
ID FETCH-LOGICAL-a351t-b9acba8e66e247264433d0c2fbf862134e1c0a5d7d7d7893c61becaff615891f3
IEDL.DBID ACS
ISSN 1089-5639
IngestDate Sat Aug 17 02:05:45 EDT 2024
Fri Aug 23 01:05:40 EDT 2024
Thu May 23 23:11:19 EDT 2024
Wed Jan 17 04:53:41 EST 2024
Thu Aug 27 13:41:54 EDT 2020
IsPeerReviewed true
IsScholarly true
Issue 44
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a351t-b9acba8e66e247264433d0c2fbf862134e1c0a5d7d7d7893c61becaff615891f3
Notes istex:BAE088CFEDFD4285CF77A5BF1A20DB5D1A5F412B
ark:/67375/TPS-LGVHZGWZ-P
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
PMID 17078602
PQID 68101511
PQPubID 23479
PageCount 7
ParticipantIDs proquest_miscellaneous_68101511
crossref_primary_10_1021_jp0629846
pubmed_primary_17078602
istex_primary_ark_67375_TPS_LGVHZGWZ_P
acs_journals_10_1021_jp0629846
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
VG9
W1F
ANTXH
ACS
AEESW
AFEFF
.K2
ABMVS
ABUCX
IH9
BAANH
AQSVZ
ED~
UI2
PublicationCentury 2000
PublicationDate 2006-11-09
PublicationDateYYYYMMDD 2006-11-09
PublicationDate_xml – month: 11
  year: 2006
  text: 2006-11-09
  day: 09
PublicationDecade 2000
PublicationPlace United States
PublicationPlace_xml – name: United States
PublicationTitle The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
PublicationTitleAlternate J. Phys. Chem. A
PublicationYear 2006
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References jp0629846b00017/jp0629846b00017_1
Cossi M. (jp0629846b00029/jp0629846b00029_1) 2001; 115
Neugebauer J. (jp0629846b00032/jp0629846b00032_1) 2006; 124
Mataga N. (jp0629846b00039/jp0629846b00039_1) 1956; 29
Chakraborty A. (jp0629846b00016/jp0629846b00016_1) 2006; 324
Rotkiewicz K. (jp0629846b00006/jp0629846b00006_1) 1973; 19
Rappoport D. (jp0629846b00012/jp0629846b00012_1) 2004; 126
Cai Z. I. (jp0629846b00030/jp0629846b00030_1) 2000; 112
Kippelen B. (jp0629846b00003/jp0629846b00003_1) 1999
Fischer E. (jp0629846b00043/jp0629846b00043_1) 1973; 77
jp0629846b00037/jp0629846b00037_1
Chakraborty A. (jp0629846b00036/jp0629846b00036_1) 2006; 320
Zachariasse K. A. (jp0629846b00015/jp0629846b00015_1) 1993; 65
Jodicke C. J. (jp0629846b00018/jp0629846b00018_1) 2002; 117
Casida M. E. (jp0629846b00027/jp0629846b00027_1) 2002; 70
Chowdhury P. (jp0629846b00023/jp0629846b00023_1) 2003; 107
jp0629846b00038/jp0629846b00038_1
Cammi R. (jp0629846b00022/jp0629846b00022_1) 2000; 104
Testa A. C. (jp0629846b00042/jp0629846b00042_1) 1991; 50
Bosshard (jp0629846b00001/jp0629846b00001_1); 1995
Pal S. K. (jp0629846b00024/jp0629846b00024_1) 2005; 406
Catalan J. (jp0629846b00044/jp0629846b00044_1) 2000; 122
Kohn A. (jp0629846b00013/jp0629846b00013_1) 2004; 126
Bevington P. R. (jp0629846b00025/jp0629846b00025_1) 1969
Sobolewski A. L. (jp0629846b00008/jp0629846b00008_1) 1996; 250
Jodicke C. J. (jp0629846b00035/jp0629846b00035_1) 2002; 117
Jodicke C. J. (jp0629846b00020/jp0629846b00020_1) 2003; 125
Duan X.-H. (jp0629846b00021/jp0629846b00021_1) 2005; 122
Schuddeboom W. (jp0629846b00007/jp0629846b00007_1) 1992; 96
Lewis F. D. (jp0629846b00040/jp0629846b00040_1) 2000; 104
Das R. (jp0629846b00004/jp0629846b00004_1) 1997; 101
Jodicke C. J. (jp0629846b00019/jp0629846b00019_1) 2003; 119
Mennucci B. (jp0629846b00028/jp0629846b00028_1) 1998; 109
Lakowicz J. R. (jp0629846b00002/jp0629846b00002_1) 1999
Grabowski Z. (jp0629846b00011/jp0629846b00011_1) 2003; 103
Sobolewski A. L. (jp0629846b00009/jp0629846b00009_1) 1996; 259
Shen L. (jp0629846b00034/jp0629846b00034_1) 2005; 409
Frisch M. J. (jp0629846b00026/jp0629846b00026_1) 2003
Lippert E. (jp0629846b00005/jp0629846b00005_1) 1961; 73
Gritsenko O. V. (jp0629846b00031/jp0629846b00031_1) 2000; 113
Rotkiewicz K. (jp0629846b00014/jp0629846b00014_1) 1992; 54
Taft R. W. (jp0629846b00041/jp0629846b00041_1) 1976; 98
Jamorski C. (jp0629846b00033/jp0629846b00033_1) 2002; 116
Zachariasse K. A. (jp0629846b00010/jp0629846b00010_1) 1997; 274
References_xml – volume: 70
  start-page: 933
  year: 2002
  ident: jp0629846b00027/jp0629846b00027_1
  publication-title: J. Quantum Chem.
  doi: 10.1002/(SICI)1097-461X(1998)70:4/5<933::AID-QUA39>3.0.CO;2-Z
  contributor:
    fullname: Casida M. E.
– volume: 109
  start-page: 2798
  year: 1998
  ident: jp0629846b00028/jp0629846b00028_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.476878
  contributor:
    fullname: Mennucci B.
– volume: 113
  start-page: 8478
  year: 2000
  ident: jp0629846b00031/jp0629846b00031_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1318750
  contributor:
    fullname: Gritsenko O. V.
– volume: 126
  start-page: 7399
  year: 2004
  ident: jp0629846b00013/jp0629846b00013_1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja0490572
  contributor:
    fullname: Kohn A.
– volume: 104
  start-page: 5631
  year: 2000
  ident: jp0629846b00022/jp0629846b00022_1
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp000156l
  contributor:
    fullname: Cammi R.
– ident: jp0629846b00038/jp0629846b00038_1
  doi: 10.1016/S1010-6030(00)00423-8
– volume: 98
  start-page: 2886
  year: 1976
  ident: jp0629846b00041/jp0629846b00041_1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00426a036
  contributor:
    fullname: Taft R. W.
– volume: 125
  start-page: 252
  year: 2003
  ident: jp0629846b00020/jp0629846b00020_1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja020361+
  contributor:
    fullname: Jodicke C. J.
– volume: 73
  start-page: 695
  year: 1961
  ident: jp0629846b00005/jp0629846b00005_1
  publication-title: Angew. Chem.
  doi: 10.1002/ange.19610732103
  contributor:
    fullname: Lippert E.
– volume: 126
  start-page: 1277
  year: 2004
  ident: jp0629846b00012/jp0629846b00012_1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja037806u
  contributor:
    fullname: Rappoport D.
– volume: 65
  start-page: 1745
  year: 1993
  ident: jp0629846b00015/jp0629846b00015_1
  publication-title: Pure Appl. Chem.
  doi: 10.1351/pac199365081745
  contributor:
    fullname: Zachariasse K. A.
– volume: 409
  start-page: 300
  year: 2005
  ident: jp0629846b00034/jp0629846b00034_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/j.cplett.2005.05.023
  contributor:
    fullname: Shen L.
– volume-title: Principles of Fluorescence Spectroscopy
  year: 1999
  ident: jp0629846b00002/jp0629846b00002_1
  doi: 10.1007/978-1-4757-3061-6
  contributor:
    fullname: Lakowicz J. R.
– volume: 104
  start-page: 8146
  year: 2000
  ident: jp0629846b00040/jp0629846b00040_1
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp001665q
  contributor:
    fullname: Lewis F. D.
– volume: 116
  start-page: 8761
  year: 2002
  ident: jp0629846b00033/jp0629846b00033_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1465404
  contributor:
    fullname: Jamorski C.
– volume-title: Data Reduction and Error Analysis for the Physical Sciences
  year: 1969
  ident: jp0629846b00025/jp0629846b00025_1
  contributor:
    fullname: Bevington P. R.
– volume: 320
  start-page: 75
  year: 2006
  ident: jp0629846b00036/jp0629846b00036_1
  publication-title: Chem. Phys.
  doi: 10.1016/j.chemphys.2005.06.031
  contributor:
    fullname: Chakraborty A.
– volume: 107
  start-page: 83
  year: 2003
  ident: jp0629846b00023/jp0629846b00023_1
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp026404q
  contributor:
    fullname: Chowdhury P.
– volume: 122
  start-page: 84314
  year: 2005
  ident: jp0629846b00021/jp0629846b00021_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1850097
  contributor:
    fullname: Duan X.-H.
– volume: 103
  start-page: 3899
  year: 2003
  ident: jp0629846b00011/jp0629846b00011_1
  publication-title: Chem. Rev.
  doi: 10.1021/cr940745l
  contributor:
    fullname: Grabowski Z.
– volume: 117
  start-page: 4146
  year: 2002
  ident: jp0629846b00018/jp0629846b00018_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1498817
  contributor:
    fullname: Jodicke C. J.
– volume: 54
  start-page: 221
  year: 1992
  ident: jp0629846b00014/jp0629846b00014_1
  publication-title: J. Lumin.
  doi: 10.1016/0022-2313(92)90069-L
  contributor:
    fullname: Rotkiewicz K.
– volume: 124
  start-page: 214102
  year: 2006
  ident: jp0629846b00032/jp0629846b00032_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.2197829
  contributor:
    fullname: Neugebauer J.
– volume: 115
  start-page: 4708
  year: 2001
  ident: jp0629846b00029/jp0629846b00029_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1394921
  contributor:
    fullname: Cossi M.
– volume-title: Organic Nonlinear Optical Material and Devices
  year: 1999
  ident: jp0629846b00003/jp0629846b00003_1
  contributor:
    fullname: Kippelen B.
– volume: 1995
  volume-title: Organic Nonlinear Optical Materials
  ident: jp0629846b00001/jp0629846b00001_1
  contributor:
    fullname: Bosshard
– volume: 77
  start-page: 859
  year: 1973
  ident: jp0629846b00043/jp0629846b00043_1
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100625a025
  contributor:
    fullname: Fischer E.
– volume: 101
  start-page: 4042
  year: 1997
  ident: jp0629846b00004/jp0629846b00004_1
  publication-title: J. Phys. Chem. A
  doi: 10.1021/jp9625669
  contributor:
    fullname: Das R.
– volume: 96
  start-page: 10809
  year: 1992
  ident: jp0629846b00007/jp0629846b00007_1
  publication-title: J. Phys. Chem.
  doi: 10.1021/j100205a041
  contributor:
    fullname: Schuddeboom W.
– ident: jp0629846b00037/jp0629846b00037_1
  doi: 10.1016/S1010-6030(98)00303-7
– volume: 29
  start-page: 465
  year: 1956
  ident: jp0629846b00039/jp0629846b00039_1
  publication-title: Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.29.465
  contributor:
    fullname: Mataga N.
– volume: 250
  start-page: 428
  year: 1996
  ident: jp0629846b00008/jp0629846b00008_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/0009-2614(96)00014-0
  contributor:
    fullname: Sobolewski A. L.
– volume: 259
  start-page: 119
  year: 1996
  ident: jp0629846b00009/jp0629846b00009_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/0009-2614(96)00724-5
  contributor:
    fullname: Sobolewski A. L.
– volume: 19
  start-page: 315
  year: 1973
  ident: jp0629846b00006/jp0629846b00006_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/0009-2614(73)80367-7
  contributor:
    fullname: Rotkiewicz K.
– volume: 324
  start-page: 733
  year: 2006
  ident: jp0629846b00016/jp0629846b00016_1
  publication-title: Chem. Phys.
  doi: 10.1016/j.chemphys.2005.12.032
  contributor:
    fullname: Chakraborty A.
– volume: 112
  start-page: 527
  year: 2000
  ident: jp0629846b00030/jp0629846b00030_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.480544
  contributor:
    fullname: Cai Z. I.
– volume: 406
  start-page: 420
  year: 2005
  ident: jp0629846b00024/jp0629846b00024_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/j.cplett.2005.03.018
  contributor:
    fullname: Pal S. K.
– volume-title: Revision B.03
  year: 2003
  ident: jp0629846b00026/jp0629846b00026_1
  contributor:
    fullname: Frisch M. J.
– volume: 274
  start-page: 372
  year: 1997
  ident: jp0629846b00010/jp0629846b00010_1
  publication-title: Chem. Phys. Lett.
  doi: 10.1016/S0009-2614(97)00668-4
  contributor:
    fullname: Zachariasse K. A.
– volume: 122
  start-page: 2377
  year: 2000
  ident: jp0629846b00044/jp0629846b00044_1
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja991834o
  contributor:
    fullname: Catalan J.
– ident: jp0629846b00017/jp0629846b00017_1
  doi: 10.1016/j.jphotochem.2005.12.004
– volume: 119
  start-page: 12852
  year: 2003
  ident: jp0629846b00019/jp0629846b00019_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1627292
  contributor:
    fullname: Jodicke C. J.
– volume: 117
  start-page: 4157
  year: 2002
  ident: jp0629846b00035/jp0629846b00035_1
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1498818
  contributor:
    fullname: Jodicke C. J.
– volume: 50
  start-page: 243
  year: 1991
  ident: jp0629846b00042/jp0629846b00042_1
  publication-title: J. Lumin.
  doi: 10.1016/0022-2313(91)90048-Z
  contributor:
    fullname: Testa A. C.
SSID ssj0001324
Score 2.1537337
Snippet A donor−acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical...
A donor-acceptor substituted aromatic system (E)-3-(4-Methylamino-phenyl)-acrylic acid methyl ester (MAPAME) has been synthesized, and its photophysical...
SourceID proquest
crossref
pubmed
istex
acs
SourceType Aggregation Database
Index Database
Publisher
StartPage 12089
Title Photoinduced Intramolecular Charge Transfer Reaction in (E)-3-(4-Methylamino-phenyl)-acrylic Acid Methyl Ester:  A Fluorescence Study in Combination with TDDFT Calculation
URI http://dx.doi.org/10.1021/jp0629846
https://api.istex.fr/ark:/67375/TPS-LGVHZGWZ-P/fulltext.pdf
https://www.ncbi.nlm.nih.gov/pubmed/17078602
https://search.proquest.com/docview/68101511
Volume 110
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV1Lb9QwELZKe4AL78fyKBYg1B5c4th5mNtqH10QRSu6pVUvkePYsHRJqmxWYjlx5cfwp_glzCSbAoKCcnUSy_PZ883DM4Q8kdYLMzC7mLCexKLaMey52GOpUDqKgsh3Bi84770ORwfy5VFwtEYenxPB9_mzD6de6CtQkxfIho-Zg8h_evtnxy2YU7LJolcsAH3blg_69VVUPWb-m-rZwFX8dD6vrPXL8Arpt7d0mrSSk51Fle6Yz38WbfzX1K-Syyt-SbsNIK6RNZtfJxd7bVu3G-Tb-H1RFWCJg0wz-gJ9ux_bFrkUg-_vLK0VmLMlfWObew90mtOtwTYTbEuyPQvCBSBN84Jhhthyts20KZezqaFdM81oM4AOsAbD8-9fvtIuHc4WRVlXjjKWYu7iEj8JhxEY5jU2KDqE6aTfH05oT8_MqqvYTXIwHEx6I7bq2cC0CHjFUqVNqmMbhtaXEbItITLP-C51YDtxIS03ng6yCB_gSibkgCLtHDCrWHEnbpH1vMjtHUKFNoIDwIz0YgnETqXcedooxzMttFIdsglCTVZ7bp7U4XQfzJl21TvkUSvv5LSp3fG3QU9rJJyN0OUJJrtFQTIZ7yevdt-OjncPj5NxhzxsoZKAyDCuonNbLOYJlnQD4sQ75HaDoJ9_w1pKoeff_d9U75FLtW8H_dXqPlmvyoV9AGynSjdrtP8AC1X46g
link.rule.ids 315,786,790,2782,27109,27957,27958,57093,57143
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1Lb9QwELagPZRLedPl0VoIofbgEsd5clttd7uF3WpFt7TqJXIcB5YuSZVkJZYTV34Mf4pfwoyTtIBAoFwdx_GMPd-Mx98Q8szRlpeA28WEthwk1Q5gzQUWi0Uofd_17VThBefxoTc8dl6duqcNTQ7ehYFBlNBTaQ7xr9gF-IsPF5Znh2Atr5NV1wc_HGFQ7-hy1wWvyqmT6UPmgtltWYR-fhUtkCp_sUCrOJmf_g4vjZkZ3KzrFZkBmuyS891FFe-qz79xN_7fH9wi6w3apN1aPW6Tazq7Q9Z6bZG3u-Tb5H1e5eCXg4QTeoCR3o9twVyKR_HvNDXmLNUFfaPrWxB0ltHt_g4TbNthYw2iBrWaZTnDfLHlfIdJVSznM0W7apbQugHtIyPDy-9fvtIuHcwXeWF4pJSmmMm4xC5hawI33WgKxfAwne7tDaa0J-eqqTF2jxwP-tPekDUVHJgULq9YHEoVy0B7nrYdH7GXEIml7DROwZPiwtFcWdJNfHwAOSmPg07JNAWcFYQ8FffJSpZneoNQIZXgoG7KsQIHYF4Y89SSKkx5IoUMww7ZhEmPmhVYRuZw3Qbnpp31Dnnaij26qJk8_tTouVGIyxayOMfUN9-NppOjaLT_dni2f3IWTTpkq9WYCESGpywy0_mijJDgDWAU75AHtSJdfQ2ZlTzLfvivoW6RteF0PIpGB4evH5EbJuqDkezwMVmpioV-AjioijfNAvgBYDkBZA
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1Lb9QwELaglYAL78fyaC2EUHtwieO8zG21u-kW2rKi21L1EjmOA0uXZJXsSiwnrvwY_hS_hJk8lodAoFwdx7FnPN-Mx98Q8sQxlpeA28WEsRwk1Q5A5wKLxUIq33d9O9V4wfng0BseOy9O3dPGUcS7MDCIEnoqq0N81OpZkjYMA_zZ-5nl2RIs5kWy7mLhboRCvaPVzguelVMn1EvmgultmYR-fhWtkC5_sULrOKEf_w4xK1MTXiOvVoOsMkzOdxbzeEd_-o2_8f__4jq52qBO2q3F5Aa5YLKb5HKvLfZ2i3wdvcvnOfjnsNIJ3cOI74e2cC7FI_m3hlZmLTUFfW3q2xB0ktGtwTYTbMthBwaWHMRrkuUM88aW022mdLGcTjTt6klC6wZ0gMwMz799_kK7NJwu8qLik9KGYkbjEruELQrc9UpiKIaJ6bjfD8e0p6a6qTV2mxyHg3FvyJpKDkwJl89ZLJWOVWA8z9iOjxhMiMTSdhqn4FFx4RiuLeUmPj6AoLTHQbZUmgLeCiRPxR2yluWZuUeoUFpwEDvtWIEDcE_GPLWUlilPlFBSdsgGTHzUaGIZVYfsNjg57ax3yON26aNZzejxp0ZPK6FYtVDFOabA-W40Hh1F-7snw7PdN2fRqEM2W6mJYMnwtEVlJl-UERK9AZziHXK3FqYfX0OGJc-y7_9rqJvk0qgfRvt7hy8fkCtV8AcD2vIhWZsXC_MI4NA83qh04DudOgPe
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Photoinduced+Intramolecular+Charge+Transfer+Reaction+in+%28E%29-3-%284-Methylamino-phenyl%29-acrylic+Acid+Methyl+Ester%3A%E2%80%89+A+Fluorescence+Study+in+Combination+with+TDDFT+Calculation&rft.jtitle=The+journal+of+physical+chemistry.+A%2C+Molecules%2C+spectroscopy%2C+kinetics%2C+environment%2C+%26+general+theory&rft.au=CHAKRABORTY%2C+Amrita&rft.au=KAR%2C+Samiran&rft.au=NATH%2C+D.+N.&rft.au=GUCHHAIT%2C+Nikhil&rft.date=2006-11-09&rft.pub=American+Chemical+Society&rft.issn=1089-5639&rft.eissn=1520-5215&rft.volume=110&rft.issue=44&rft.spage=12089&rft.epage=12095&rft_id=info:doi/10.1021%2Fjp0629846&rft.externalDBID=n%2Fa&rft.externalDocID=ark_67375_TPS_LGVHZGWZ_P
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1089-5639&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1089-5639&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1089-5639&client=summon