Robust Metal–Organic Framework Containing Benzoselenadiazole for Highly Efficient Aerobic Cross-dehydrogenative Coupling Reactions under Visible Light

A zirconium­(IV)-based UiO-topological metal–organic framework (UiO-68Se) containing benzoselenadiazole was synthesized by an approach of the mixed dicarboxylate struts, which show highly efficient and recycalable photocatalytic activity for aerobic cross-dehydrogenative coupling reactions between t...

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Published inInorganic chemistry Vol. 55; no. 3; pp. 1005 - 1007
Main Authors Zhang, Wen-Qiang, Li, Qiu-Yan, Zhang, Quan, Lu, Yingqiao, Lu, Han, Wang, Wenguang, Zhao, Xinsheng, Wang, Xiao-Jun
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 01.02.2016
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Summary:A zirconium­(IV)-based UiO-topological metal–organic framework (UiO-68Se) containing benzoselenadiazole was synthesized by an approach of the mixed dicarboxylate struts, which show highly efficient and recycalable photocatalytic activity for aerobic cross-dehydrogenative coupling reactions between tertiary amines and various carbon nucleophiles under visible-light irradiation.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.5b02626