Conductive Leaflike Cobalt Metal–Organic Framework Nanoarray on Carbon Cloth as a Flexible and Versatile Anode toward Both Electrocatalytic Glucose and Water Oxidation

• Published in: Inorganic chemistry Vol. 57; no. 14; pp. 8422 - 8428
• Main Authors: Wei, Ziyi, Zhu, Wenxin, Li, Yinge, Ma, Yiyue, Wang, Jing, Hu, Na, Suo, Yourui, Wang, Jianlong
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 16.07.2018
• Subjects: Carbon - chemistry; Catalysis; Cobalt - chemistry; Electrochemical Techniques - instrumentation; Electrodes; Glucose - analysis; Glucose - chemistry; Limit of Detection; Metal-Organic Frameworks - chemical synthesis; Metal-Organic Frameworks - chemistry; Oxidation-Reduction; Water - chemistry
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/acs.inorgchem.8b01106

Transition metal–organic frameworks (MOFs), on account of their unique inherent properties of large pore volume, high specific surface area, tunable pores, and good catalytic activity, have been highly regarded as superior catalysts recently for water electrolysis, supercapacitors, batteries, sensors, and so on. Herein, we report on a cobalt MOF phase with 3D well-aligned nanosheets array architecture on carbon cloth (Co-MOF NS/CC), fabricated by a facile ambient liquid-phase deposition, could serve as a self-standing Janus catalytic electrode toward both glucose and water oxidation. It shows good glucose-sensing performance with low determination limit and large detection range. Also, it exhibits high water-oxidation efficiency with low overpotential and good durability. This work demonstrates the potential of utilizing transition-metal based well-aligned MOF nanoarrays for electrocatalytic oxidation.