Soret Coefficients in Some Water−Methanol, Water−Ethanol, and Water−Isopropanol Systems
In this article, we re-examine the published experimental values of the Soret coefficients of a few water−alcohol systems at a mean temperature of 37.5 °C, because we feel that these published values (including microgravity values) are doubtful. The main technique applied is the use of thermogravita...
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| Published in | The journal of physical chemistry. B Vol. 111; no. 39; pp. 11524 - 11530 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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United States
American Chemical Society
04.10.2007
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| Abstract | In this article, we re-examine the published experimental values of the Soret coefficients of a few water−alcohol systems at a mean temperature of 37.5 °C, because we feel that these published values (including microgravity values) are doubtful. The main technique applied is the use of thermogravitational columns to determine the thermodiffusion coefficient. The obtained values did not agree with the published values; worse, sometimes the sign was different. |
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| AbstractList | In this article, we re-examine the published experimental values of the Soret coefficients of a few water−alcohol systems at a mean temperature of 37.5 °C, because we feel that these published values (including microgravity values) are doubtful. The main technique applied is the use of thermogravitational columns to determine the thermodiffusion coefficient. The obtained values did not agree with the published values; worse, sometimes the sign was different. In this article, we re-examine the published experimental values of the Soret coefficients of a few water-alcohol systems at a mean temperature of 37.5 degrees C, because we feel that these published values (including microgravity values) are doubtful. The main technique applied is the use of thermogravitational columns to determine the thermodiffusion coefficient. The obtained values did not agree with the published values; worse, sometimes the sign was different. |
| Author | Santamaria, C Platten, J. K Blanco, P Bou-Ali, M. M Madariaga, J. A |
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| Title | Soret Coefficients in Some Water−Methanol, Water−Ethanol, and Water−Isopropanol Systems |
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