Photochemical Oxidation of Halide Ions by a Nitratochromium(III) Complex. Kinetics, Mechanism, and Intermediates
The 266 nm laser flash photolysis of the title complex in the presence of halide ions X− (X = I, Br, and Cl) generates halogen atoms on nanosecond time scales, followed by the known X•/X– reactions to yield dihalide radical anions, X2 •−. Plots of k obs against the concentration of X− were linear wi...
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| Published in | Journal of the American Chemical Society Vol. 130; no. 16; pp. 5600 - 5605 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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American Chemical Society
23.04.2008
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| Abstract | The 266 nm laser flash photolysis of the title complex in the presence of halide ions X− (X = I, Br, and Cl) generates halogen atoms on nanosecond time scales, followed by the known X•/X– reactions to yield dihalide radical anions, X2 •−. Plots of k obs against the concentration of X− were linear with zero intercepts, but the yields of X2 •− increased with increasing concentrations of [X−]. This result suggests that a short-lived, strongly oxidizing intermediate reacts with X− to generate X• in parallel with the decomposition to CraqO2+ and •NO2, both of which were identified in steady-state photolysis experiments in the presence of selective trapping agents. Bromide was oxidized quantitatively to bromine, and a combination of molecular oxygen and methanol channeled the reaction toward superoxochromium(III) ion, CraqOO2+. In the absence of scavengers, nitrite and chromate were produced. The proposed reaction scheme draws additional support from the good agreement between the experimental product yields and those predicted by kinetic simulations. |
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| AbstractList | The 266 nm laser flash photolysis of the title complex in the presence of halide ions X(-) (X = I, Br, and Cl) generates halogen atoms on nanosecond time scales, followed by the known X(*)/X(-) reactions to yield dihalide radical anions, X2(*-). Plots of k(obs) against the concentration of X(-) were linear with zero intercepts, but the yields of X2(*-) increased with increasing concentrations of [X(-)]. This result suggests that a short-lived, strongly oxidizing intermediate reacts with X(-) to generate X(*) in parallel with the decomposition to Cr(aq)O(2+) and (*)NO2, both of which were identified in steady-state photolysis experiments in the presence of selective trapping agents. Bromide was oxidized quantitatively to bromine, and a combination of molecular oxygen and methanol channeled the reaction toward superoxochromium(III) ion, Cr(aq)OO(2+). In the absence of scavengers, nitrite and chromate were produced. The proposed reaction scheme draws additional support from the good agreement between the experimental product yields and those predicted by kinetic simulations. The 266 nm laser flash photolysis of the title complex in the presence of halide ions X− (X = I, Br, and Cl) generates halogen atoms on nanosecond time scales, followed by the known X•/X– reactions to yield dihalide radical anions, X2 •−. Plots of k obs against the concentration of X− were linear with zero intercepts, but the yields of X2 •− increased with increasing concentrations of [X−]. This result suggests that a short-lived, strongly oxidizing intermediate reacts with X− to generate X• in parallel with the decomposition to CraqO2+ and •NO2, both of which were identified in steady-state photolysis experiments in the presence of selective trapping agents. Bromide was oxidized quantitatively to bromine, and a combination of molecular oxygen and methanol channeled the reaction toward superoxochromium(III) ion, CraqOO2+. In the absence of scavengers, nitrite and chromate were produced. The proposed reaction scheme draws additional support from the good agreement between the experimental product yields and those predicted by kinetic simulations. |
| Author | Bakac, Andreja Cheng, Mingming |
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| Cites_doi | 10.1016/0010-8545(87)85032-4 10.1021/cr960111+ 10.1021/ja00050a033 10.1021/j100233a018 10.1021/ic00308a014 10.1021/ic0013577 10.1105/tpc.104.029694 10.1021/ja016840a 10.1063/1.555808 10.1007/978-1-4020-3163-2_8 10.1021/ja073609+ 10.1021/ja016747m 10.1021/ic00005a009 10.1016/S0898-8838(03)55001-2 10.1021/ic950909w 10.1021/ja00436a014 10.1016/S0065-2792(08)60080-1 10.1300/J411v15n02_03 10.1021/tx000236g 10.1039/c39760000683 10.1021/ic00179a019 10.1021/ja00993a016 10.1016/S1381-1169(03)00045-1 10.1007/s00775-007-0271-5 10.1016/S1010-6030(96)04391-2 10.1039/c39900001646 10.1007/BFb0048835 10.1021/cr00072a002 10.1021/ic00050a038 10.1039/ft9969204173 10.1021/cr00100a001 10.1021/ic00147a014 10.1021/ja030135f 10.1021/ic051310r 10.1016/S0898-8838(08)60194-4 10.1021/ja00751a064 10.1021/ja00106a066 10.1021/ja00129a010 10.1246/bcsj.66.2900 |
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| References | Mark G. (ref6/cit6) 1996; 101 Hofmann M. (ref2/cit2) 2007; 12 Buxton G. V. (ref40/cit40) 1996; 92 Kimura M. (ref27/cit27) 1993; 66 Hung M. (ref36/cit36) 2005; 44 Nemes A. (ref21/cit21) 2002; 124 Swaddle T. W. (ref23/cit23) 1967; 89 Suslick K. S. (ref9/cit9) 1991; 30 Bakac A. (ref15/cit15) 1990 Hug G. L. (ref24/cit24) 1981 Pestovsky O. (ref39/cit39) 2003; 200 Kirk A. D. (ref11/cit11) 1999; 99 Kunkely H. (ref8/cit8) 1995; 117 Huston P. (ref25/cit25) 1992; 114 Balzani V. (ref18/cit18) 1978; 75 Ferguson S. J. (ref4/cit4) 2004; 16 Madsen D. (ref5/cit5) 2003; 125 Nemes A. (ref37/cit37) 2001; 40 Pestovsky O. (ref28/cit28) 2002; 124 Endicott J. F. (ref13/cit13) 1987; 77 Bakac A. (ref35/cit35) 1995; 43 Bakac A. (ref29/cit29) 2004; 55 Linck N. J. (ref19/cit19) 1983; 87 ref10/cit10 Nauser T. (ref43/cit43) 2001; 14 Tischner R. (ref1/cit1) 2005; 15 Fischer K. (ref3/cit3) 2005; 17 Ruminski R. R. (ref17/cit17) 1989; 28 Stanbury D. M. (ref34/cit34) 1989; 33 Forster L. S. (ref12/cit12) 1990; 90 Sriram R. (ref14/cit14) 1976 Jiang P. Y. (ref33/cit33) 1992; 31 Vogler A. (ref16/cit16) 1971; 93 Neta P. (ref26/cit26) 1988; 17 Bakac A. (ref20/cit20) 1995; 117 Bakac A. (ref22/cit22) 1983; 22 Sellers R. M. (ref41/cit41) 1976; 98 Balzani V. (ref31/cit31) 1986; 86 Goldstein S. (ref42/cit42) 2007; 129 Vione D. (ref7/cit7) 2006; 35 Beckwith R. C. (ref30/cit30) 1996; 35 Wrona P. K. (ref32/cit32) 1984; 23 Stedman G. (ref38/cit38) 1979; 22 |
| References_xml | – volume: 77 start-page: 1 year: 1987 ident: ref13/cit13 publication-title: Coord. Chem. Rev. doi: 10.1016/0010-8545(87)85032-4 contributor: fullname: Endicott J. F. – volume: 99 start-page: 1607 year: 1999 ident: ref11/cit11 publication-title: Chem. Rev. doi: 10.1021/cr960111+ contributor: fullname: Kirk A. D. – volume: 114 start-page: 9510 year: 1992 ident: ref25/cit25 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00050a033 contributor: fullname: Huston P. – volume: 87 start-page: 1733 year: 1983 ident: ref19/cit19 publication-title: J. Phys. Chem. doi: 10.1021/j100233a018 contributor: fullname: Linck N. J. – volume-title: Optical Spectra of Nonmetallic Inorganic Transient Species in Aqueous Solution year: 1981 ident: ref24/cit24 contributor: fullname: Hug G. L. – volume: 28 start-page: 1666 year: 1989 ident: ref17/cit17 publication-title: Inorg. Chem. doi: 10.1021/ic00308a014 contributor: fullname: Ruminski R. R. – volume: 40 start-page: 2720 year: 2001 ident: ref37/cit37 publication-title: Inorg. Chem. doi: 10.1021/ic0013577 contributor: fullname: Nemes A. – volume: 17 start-page: 1167 year: 2005 ident: ref3/cit3 publication-title: Plant Cell doi: 10.1105/tpc.104.029694 contributor: fullname: Fischer K. – volume: 124 start-page: 421 year: 2002 ident: ref21/cit21 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja016840a contributor: fullname: Nemes A. – volume: 17 start-page: 1027 year: 1988 ident: ref26/cit26 publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.555808 contributor: fullname: Neta P. – volume: 16 start-page: 169 year: 2004 ident: ref4/cit4 publication-title: Adv. Photosynth. Respiration doi: 10.1007/978-1-4020-3163-2_8 contributor: fullname: Ferguson S. J. – volume: 129 start-page: 10597 year: 2007 ident: ref42/cit42 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja073609+ contributor: fullname: Goldstein S. – ident: ref10/cit10 – volume: 124 start-page: 1698 year: 2002 ident: ref28/cit28 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja016747m contributor: fullname: Pestovsky O. – volume: 30 start-page: 912 year: 1991 ident: ref9/cit9 publication-title: Inorg. Chem. doi: 10.1021/ic00005a009 contributor: fullname: Suslick K. S. – volume: 55 start-page: 1 year: 2004 ident: ref29/cit29 publication-title: Adv. Inorg. Chem. doi: 10.1016/S0898-8838(03)55001-2 contributor: fullname: Bakac A. – volume: 35 start-page: 995 year: 1996 ident: ref30/cit30 publication-title: Inorg. Chem. doi: 10.1021/ic950909w contributor: fullname: Beckwith R. C. – volume: 98 start-page: 6145 year: 1976 ident: ref41/cit41 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00436a014 contributor: fullname: Sellers R. M. – volume: 22 start-page: 113 year: 1979 ident: ref38/cit38 publication-title: Adv. Inorg. Chem. Radiochem. doi: 10.1016/S0065-2792(08)60080-1 contributor: fullname: Stedman G. – volume: 15 start-page: 53 year: 2005 ident: ref1/cit1 publication-title: J. Crop Improvement doi: 10.1300/J411v15n02_03 contributor: fullname: Tischner R. – volume: 14 start-page: 348 year: 2001 ident: ref43/cit43 publication-title: Chem. Res. Toxicol. doi: 10.1021/tx000236g contributor: fullname: Nauser T. – start-page: 683 year: 1976 ident: ref14/cit14 publication-title: J. Chem. Soc., Chem. Commun. doi: 10.1039/c39760000683 contributor: fullname: Sriram R. – volume: 23 start-page: 1558 year: 1984 ident: ref32/cit32 publication-title: Inorg. Chem. doi: 10.1021/ic00179a019 contributor: fullname: Wrona P. K. – volume: 43 start-page: 267 year: 1995 ident: ref35/cit35 publication-title: Prog. Inorg. Chem. contributor: fullname: Bakac A. – volume: 89 start-page: 4338 year: 1967 ident: ref23/cit23 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00993a016 contributor: fullname: Swaddle T. W. – volume: 200 start-page: 21 year: 2003 ident: ref39/cit39 publication-title: J. Mol. Catal. A doi: 10.1016/S1381-1169(03)00045-1 contributor: fullname: Pestovsky O. – volume: 12 start-page: 989 year: 2007 ident: ref2/cit2 publication-title: J. Biol. Inorg. Chem. doi: 10.1007/s00775-007-0271-5 contributor: fullname: Hofmann M. – volume: 101 start-page: 89 year: 1996 ident: ref6/cit6 publication-title: J. Photochem. Photobiol. A doi: 10.1016/S1010-6030(96)04391-2 contributor: fullname: Mark G. – start-page: 1646 year: 1990 ident: ref15/cit15 publication-title: J. Chem. Soc., Chem. Commun. doi: 10.1039/c39900001646 contributor: fullname: Bakac A. – volume: 75 start-page: 1 year: 1978 ident: ref18/cit18 publication-title: Top. Curr. Chem. doi: 10.1007/BFb0048835 contributor: fullname: Balzani V. – volume: 86 start-page: 319 year: 1986 ident: ref31/cit31 publication-title: Chem. Rev. doi: 10.1021/cr00072a002 contributor: fullname: Balzani V. – volume: 31 start-page: 5135 year: 1992 ident: ref33/cit33 publication-title: Inorg. Chem. doi: 10.1021/ic00050a038 contributor: fullname: Jiang P. Y. – volume: 92 start-page: 4173 year: 1996 ident: ref40/cit40 publication-title: J. Chem. Soc., Faraday Trans. doi: 10.1039/ft9969204173 contributor: fullname: Buxton G. V. – volume: 90 start-page: 331 year: 1990 ident: ref12/cit12 publication-title: Chem. Rev. doi: 10.1021/cr00100a001 contributor: fullname: Forster L. S. – volume: 22 start-page: 779 year: 1983 ident: ref22/cit22 publication-title: Inorg. Chem. doi: 10.1021/ic00147a014 contributor: fullname: Bakac A. – volume: 125 start-page: 15571 year: 2003 ident: ref5/cit5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja030135f contributor: fullname: Madsen D. – volume: 44 start-page: 9293 year: 2005 ident: ref36/cit36 publication-title: Inorg. Chem. doi: 10.1021/ic051310r contributor: fullname: Hung M. – volume: 33 start-page: 69 year: 1989 ident: ref34/cit34 publication-title: Adv. Inorg. Chem. doi: 10.1016/S0898-8838(08)60194-4 contributor: fullname: Stanbury D. M. – volume: 35 start-page: 441 year: 2006 ident: ref7/cit7 publication-title: Chem. Soc. Rev. contributor: fullname: Vione D. – volume: 93 start-page: 5912 year: 1971 ident: ref16/cit16 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00751a064 contributor: fullname: Vogler A. – volume: 117 start-page: 540 year: 1995 ident: ref8/cit8 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00106a066 contributor: fullname: Kunkely H. – volume: 117 start-page: 6483 year: 1995 ident: ref20/cit20 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00129a010 contributor: fullname: Bakac A. – volume: 66 start-page: 2900 year: 1993 ident: ref27/cit27 publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.66.2900 contributor: fullname: Kimura M. |
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| Title | Photochemical Oxidation of Halide Ions by a Nitratochromium(III) Complex. Kinetics, Mechanism, and Intermediates |
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