Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology

• Published in: Inorganic chemistry Vol. 56; no. 22; pp. 14198 - 14205
• Main Authors: Lin, Jian, Qie, Meiying, Zhang, Linjuan, Wang, Xiaomei, Lin, Yuejian, Liu, Wei, Bao, Hongliang, Wang, Jianqiang
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 20.11.2017

Systematic control of the molar ratio between thorium hydroxides and selenic acid and their reaction temperature under hydrothermal conditions results in four novel thorium-based selenate complexes, namely, [Th8O4(OH)8­(SeO4)6(H2O)16]·(SeO4)2·13H2O (Th-1), [Th8O4(OH)8­(SeO4)8(H2O)13]·7H2O (Th-2), Th...