Seed-Assisted Synthesis of Hierarchically Structured Nano-Sized Ti‑β Zeolites for the Efficient Epoxidation Reaction of Alkenes

The development of nano-sized titanosilicate zeolites with hierarchical structures is crucial in promoting the efficient epoxidation of alkenes. In the present work, nano-sized hierarchical Ti-β (*BEA) zeolites with high crystal yield are prepared by a one-pot nanoseed-assisted approach. The influen...

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Published inInorganic chemistry Vol. 61; no. 12; pp. 4887 - 4894
Main Authors Yang, Guoju, Qiu, Ziyi, Peng, Sainan, Nan, Maiyan, Li, Lin, Hou, Ying, Chen, Xiaoxin
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 28.03.2022
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Abstract The development of nano-sized titanosilicate zeolites with hierarchical structures is crucial in promoting the efficient epoxidation of alkenes. In the present work, nano-sized hierarchical Ti-β (*BEA) zeolites with high crystal yield are prepared by a one-pot nanoseed-assisted approach. The influence of seed size on the resultant Ti-β zeolites is investigated by complementary characterizations, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), N2 adsorption/desorption, UV–vis diffuse reflectance spectroscopy (DRS), and UV Raman spectroscopy. The possible process for the formation of hierarchical Ti-β nanocrystals with the assistance of nanoseeds in the synthesis gel is proposed. Consequentially, the nano-sized hierarchical material prepared by the nanoseed-assisted method shows excellent mass transportation and accessibility to active sites by reducing particle size and constructing hierarchical porosity, hence showing a remarkably enhanced catalytic activity and selectivity in the epoxidation reaction of alkenes. This work will shed light on the efficient preparation of nano-sized titanosilicate zeolites.
AbstractList The development of nano-sized titanosilicate zeolites with hierarchical structures is crucial in promoting the efficient epoxidation of alkenes. In the present work, nano-sized hierarchical Ti-β ( ) zeolites with high crystal yield are prepared by a one-pot nanoseed-assisted approach. The influence of seed size on the resultant Ti-β zeolites is investigated by complementary characterizations, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), N adsorption/desorption, UV-vis diffuse reflectance spectroscopy (DRS), and UV Raman spectroscopy. The possible process for the formation of hierarchical Ti-β nanocrystals with the assistance of nanoseeds in the synthesis gel is proposed. Consequentially, the nano-sized hierarchical material prepared by the nanoseed-assisted method shows excellent mass transportation and accessibility to active sites by reducing particle size and constructing hierarchical porosity, hence showing a remarkably enhanced catalytic activity and selectivity in the epoxidation reaction of alkenes. This work will shed light on the efficient preparation of nano-sized titanosilicate zeolites.
The development of nano-sized titanosilicate zeolites with hierarchical structures is crucial in promoting the efficient epoxidation of alkenes. In the present work, nano-sized hierarchical Ti-β (*BEA) zeolites with high crystal yield are prepared by a one-pot nanoseed-assisted approach. The influence of seed size on the resultant Ti-β zeolites is investigated by complementary characterizations, including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), N2 adsorption/desorption, UV–vis diffuse reflectance spectroscopy (DRS), and UV Raman spectroscopy. The possible process for the formation of hierarchical Ti-β nanocrystals with the assistance of nanoseeds in the synthesis gel is proposed. Consequentially, the nano-sized hierarchical material prepared by the nanoseed-assisted method shows excellent mass transportation and accessibility to active sites by reducing particle size and constructing hierarchical porosity, hence showing a remarkably enhanced catalytic activity and selectivity in the epoxidation reaction of alkenes. This work will shed light on the efficient preparation of nano-sized titanosilicate zeolites.
Author Nan, Maiyan
Li, Lin
Yang, Guoju
Hou, Ying
Chen, Xiaoxin
Peng, Sainan
Qiu, Ziyi
AuthorAffiliation Jilin University
Electron Microscopy Center
State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry
School of Chemistry and Environmental Engineering
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Title Seed-Assisted Synthesis of Hierarchically Structured Nano-Sized Ti‑β Zeolites for the Efficient Epoxidation Reaction of Alkenes
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