Negative Effects of Inorganic Salt Invasion on the Dissociation Kinetics of Silica-Confined Gas Hydrate via Thermal Stimulation
Methane hydrate dissociation kinetics can be inhibited in NaCl solutions; however, this effect is reversed by promoting bubble formation that enhances dissociation. The negative and positive effects of inorganic salt injection on gas production from hydrate-bearing sediments are still controversial....
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Published in | Energy & fuels Vol. 36; no. 12; pp. 6216 - 6228 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
16.06.2022
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Abstract | Methane hydrate dissociation kinetics can be inhibited in NaCl solutions; however, this effect is reversed by promoting bubble formation that enhances dissociation. The negative and positive effects of inorganic salt injection on gas production from hydrate-bearing sediments are still controversial. Here, molecular dynamics simulations were performed to investigate the characteristics of NaCl solution invasion into hydrate-occupied nanopores and the effects on the confined hydrate dissociation kinetics. Two initial configurations comprising liquid and silica pore phases were studied with a low or high NaCl concentration, respectively. The results show that, under the simulation conditions, salt invasion decelerated hydrate dissociation within the silica pore as NaCl invasion into the pore is stepwise. Initially, few ions can diffuse into the pore phase, and gas nanobubbles form on the solid surface mainly via confinement and surface effects, independent of NaCl solution invasion. Subsequently, gradual salt diffusion immersed the residual hydrate in the salt solution and hindered hydrate decomposition until the dissociation finished. More ions could diffuse into the pore phase at the high NaCl concentrations with a low diffusion efficiency, leading to surface nanobubble growth toward the residual hydrate and somewhat accelerated hydrate dissociation. This severely hinders the escape of released methane from the pore. This study yields molecular-level insight into the origin of the negative effect of salt invasion on hydrate dissociation, which should be avoided during gas production from hydrate reservoirs with low permeabilities via salt injection combined with thermal stimulation. |
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AbstractList | Methane hydrate dissociation kinetics can be inhibited in NaCl solutions; however, this effect is reversed by promoting bubble formation that enhances dissociation. The negative and positive effects of inorganic salt injection on gas production from hydrate-bearing sediments are still controversial. Here, molecular dynamics simulations were performed to investigate the characteristics of NaCl solution invasion into hydrate-occupied nanopores and the effects on the confined hydrate dissociation kinetics. Two initial configurations comprising liquid and silica pore phases were studied with a low or high NaCl concentration, respectively. The results show that, under the simulation conditions, salt invasion decelerated hydrate dissociation within the silica pore as NaCl invasion into the pore is stepwise. Initially, few ions can diffuse into the pore phase, and gas nanobubbles form on the solid surface mainly via confinement and surface effects, independent of NaCl solution invasion. Subsequently, gradual salt diffusion immersed the residual hydrate in the salt solution and hindered hydrate decomposition until the dissociation finished. More ions could diffuse into the pore phase at the high NaCl concentrations with a low diffusion efficiency, leading to surface nanobubble growth toward the residual hydrate and somewhat accelerated hydrate dissociation. This severely hinders the escape of released methane from the pore. This study yields molecular-level insight into the origin of the negative effect of salt invasion on hydrate dissociation, which should be avoided during gas production from hydrate reservoirs with low permeabilities via salt injection combined with thermal stimulation. |
Author | Lü, Tao Wang, Dongdong Meng, Jiuling Vlugt, Thijs J. H. Ning, Fulong Fang, Bin Fan, Bowen Ni, Yang Cheng, Liwei |
AuthorAffiliation | School of Automation Hubei Key Laboratory of Advanced Control and Intelligent Automation for Complex Systems China University of Geosciences Faculty of Engineering School of Mathematics and Physics Process and Energy Department National Center for International Research on Deep Earth Drilling and Resource Development Laboratory for Marine Mineral Resources |
AuthorAffiliation_xml | – name: Faculty of Engineering – name: School of Automation – name: Hubei Key Laboratory of Advanced Control and Intelligent Automation for Complex Systems – name: Process and Energy Department – name: National Center for International Research on Deep Earth Drilling and Resource Development – name: China University of Geosciences – name: Laboratory for Marine Mineral Resources – name: School of Mathematics and Physics |
Author_xml | – sequence: 1 givenname: Bin surname: Fang fullname: Fang, Bin organization: National Center for International Research on Deep Earth Drilling and Resource Development – sequence: 2 givenname: Tao orcidid: 0000-0002-6317-8039 surname: Lü fullname: Lü, Tao email: lvtaohn@126.com organization: Hubei Key Laboratory of Advanced Control and Intelligent Automation for Complex Systems – sequence: 3 givenname: Liwei surname: Cheng fullname: Cheng, Liwei organization: National Center for International Research on Deep Earth Drilling and Resource Development – sequence: 4 givenname: Dongdong surname: Wang fullname: Wang, Dongdong organization: National Center for International Research on Deep Earth Drilling and Resource Development – sequence: 5 givenname: Yang surname: Ni fullname: Ni, Yang organization: School of Mathematics and Physics – sequence: 6 givenname: Bowen surname: Fan fullname: Fan, Bowen organization: School of Mathematics and Physics – sequence: 7 givenname: Jiuling surname: Meng fullname: Meng, Jiuling organization: School of Mathematics and Physics – sequence: 8 givenname: Thijs J. H. orcidid: 0000-0003-3059-8712 surname: Vlugt fullname: Vlugt, Thijs J. H. organization: Process and Energy Department – sequence: 9 givenname: Fulong orcidid: 0000-0003-1236-586X surname: Ning fullname: Ning, Fulong email: nflzx@cug.edu.cn organization: Laboratory for Marine Mineral Resources |
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Title | Negative Effects of Inorganic Salt Invasion on the Dissociation Kinetics of Silica-Confined Gas Hydrate via Thermal Stimulation |
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