Growth, Stability, and Electronic Decoupling of Pt Clusters on h‑BN/Ir(111)
Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron nitride (h-BN) with Ir(111). Using X-ray photoelectron spectroscopy, scanning tunneling microscopy, and scanning tunneling spectroscopy, we...
Saved in:
Published in | Journal of physical chemistry. C Vol. 125; no. 7; pp. 3880 - 3889 |
---|---|
Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
25.02.2021
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron nitride (h-BN) with Ir(111). Using X-ray photoelectron spectroscopy, scanning tunneling microscopy, and scanning tunneling spectroscopy, we provide a comprehensive picture for the mechanism of cluster binding, the thermal stability of clusters, cluster superlattice decay, the morphological evolution of cluster shape with size, and finally Pt cluster decoupling and internal electronic structure. The key findings are that the Pt cluster superlattices on h-BN on Ir(111) are thermally more stable than any other Pt cluster superlattice, are well decoupled from their substrate, and display a discrete cluster height-dependent electronic structure. |
---|---|
AbstractList | Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron nitride (h-BN) with Ir(111). Using X-ray photoelectron spectroscopy, scanning tunneling microscopy, and scanning tunneling spectroscopy, we provide a comprehensive picture for the mechanism of cluster binding, the thermal stability of clusters, cluster superlattice decay, the morphological evolution of cluster shape with size, and finally Pt cluster decoupling and internal electronic structure. The key findings are that the Pt cluster superlattices on h-BN on Ir(111) are thermally more stable than any other Pt cluster superlattice, are well decoupled from their substrate, and display a discrete cluster height-dependent electronic structure. Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron nitride (h-BN) with Ir(111). Using X-ray photoelectron spectroscopy, scanning tunneling microscopy, and scanning tunneling spectroscopy, we provide a comprehensive picture for the mechanism of cluster binding, the thermal stability of clusters, cluster superlattice decay, the morphological evolution of cluster shape with size, and finally Pt cluster decoupling and internal electronic structure. The key findings are that the Pt cluster superlattices on h-BN on Ir(111) are thermally more stable than any other Pt cluster superlattice, are well decoupled from their substrate, and display a discrete cluster height-dependent electronic structure. |
Author | Knudsen, Jan Michely, Thomas Hartl, Tobias Boix de la Cruz, Virginia Lacovig, Paolo Lizzit, Silvano Will, Moritz Bampoulis, Pantelis |
AuthorAffiliation | Elettra-Sincrotrone Trieste S.C.p.A Lund University MAX IV Laboratory Division of Synchrotron Radiation Research II. Physikalisches Institut |
AuthorAffiliation_xml | – name: II. Physikalisches Institut – name: Division of Synchrotron Radiation Research – name: MAX IV Laboratory – name: Lund University – name: Elettra-Sincrotrone Trieste S.C.p.A |
Author_xml | – sequence: 1 givenname: Moritz orcidid: 0000-0003-4822-9122 surname: Will fullname: Will, Moritz email: will@ph2.uni-koeln.de organization: II. Physikalisches Institut – sequence: 2 givenname: Tobias surname: Hartl fullname: Hartl, Tobias email: hartl@ph2.uni-koeln.de organization: II. Physikalisches Institut – sequence: 3 givenname: Virginia orcidid: 0000-0002-1152-8201 surname: Boix de la Cruz fullname: Boix de la Cruz, Virginia organization: Lund University – sequence: 4 givenname: Paolo orcidid: 0000-0001-7001-7930 surname: Lacovig fullname: Lacovig, Paolo organization: Elettra-Sincrotrone Trieste S.C.p.A – sequence: 5 givenname: Silvano orcidid: 0000-0003-1620-7228 surname: Lizzit fullname: Lizzit, Silvano organization: Elettra-Sincrotrone Trieste S.C.p.A – sequence: 6 givenname: Jan surname: Knudsen fullname: Knudsen, Jan organization: Lund University – sequence: 7 givenname: Thomas surname: Michely fullname: Michely, Thomas organization: II. Physikalisches Institut – sequence: 8 givenname: Pantelis orcidid: 0000-0002-2347-5223 surname: Bampoulis fullname: Bampoulis, Pantelis organization: II. Physikalisches Institut |
BackLink | https://lup.lub.lu.se/record/89697040-f95f-475e-9c3c-5803d283385f$$DView record from Swedish Publication Index |
BookMark | eNp1kM1OwzAQhC1UJNrCnaOPIDWtHcdxfIRSSqXyIwFny3YcmirEkZ2o6o1X4BV5Elxa9cZhtSvtzCfNDECvtrUB4BKjMUYxnkjtx-tG6zHSGGGSnoA-5iSOWEJp73gn7AwMvF8jRElQ9cHj3NlNuxrB11aqsirb7QjKOoezyujW2brU8M5o2zVVWX9AW8CXFk6rzrfGeWhruPr5-r59mizcFcb4-hycFrLy5uKwh-D9fvY2fYiWz_PF9GYZSZLwNspZyrBSOueYM6WJRNpkSYrTmNA0Nxk3LEgkUbQgGcaGMJTEKQlJcqa4LsgQLPdcvzFNp0Tjyk_ptsLKUlRdE0aFEd6IjKc8uJEoOC1EwqgRXBMtaIZIHmeEZHSHQ3ucdtZ7Z4ojECOxa1eEdsWuXXFoN1hGe8vfx3auDnn_l_8C4Mp9pg |
CitedBy_id | crossref_primary_10_1016_j_surfrep_2023_100586 crossref_primary_10_1016_j_surfrep_2024_100637 crossref_primary_10_1103_PhysRevB_104_115417 crossref_primary_10_1021_acs_jpcc_3c07123 crossref_primary_10_1016_j_apsusc_2023_157041 crossref_primary_10_1021_acs_jpcc_1c06829 crossref_primary_10_1088_1674_1056_ac70c1 crossref_primary_10_1021_acs_jpcc_3c03896 crossref_primary_10_1021_acs_jpcc_2c00694 crossref_primary_10_1021_acs_jpcc_2c02266 crossref_primary_10_1002_chem_202102590 |
Cites_doi | 10.1039/b303244b 10.1126/science.aac6368 10.1103/physrevb.44.1646 10.1016/s0009-2614(00)00305-5 10.1039/c9cp04095a 10.1016/j.cplett.2018.08.026 10.1021/acsanm.9b01522 10.1021/jp207571n 10.1021/acs.jpcc.8b01589 10.1007/s10562-014-1402-6 10.1021/jp036985z 10.1063/1.3427246 10.1007/s10562-016-1925-0 10.1016/j.cplett.2012.03.080 10.1021/acsnano.8b02127 10.1103/physrevb.85.035407 10.1016/j.susc.2008.04.040 10.1021/acs.jpcc.6b07828 10.1021/acs.jpcc.9b05109 10.1103/physrevb.89.235429 10.1595/147106706x129088 10.1088/1367-2630/11/10/103045 10.1021/acscatal.5b00245 10.1103/physrevb.86.075409 10.1021/acsnano.6b05819 10.1038/srep30449 10.1016/0040-6090(88)90008-9 10.1080/01614940.2011.596430 10.1063/1.3246166 10.1595/147106710x493124 10.1103/PhysRevLett.97.215501 10.1126/science.1085721 10.1088/0022-3727/33/11/201 10.1007/s100510070019 10.1038/495453a 10.1038/ncomms9662 10.1063/1.2432410 10.1021/jacs.7b07093 10.1007/s11244-015-0407-8 10.1126/sciadv.aay4289 10.1016/s0021-9517(02)00112-4 10.1063/5.0011616 10.1103/physrevlett.110.086111 10.1147/rd.321.0144 10.1021/nn301675f |
ContentType | Journal Article |
Copyright | 2021 American Chemical Society |
Copyright_xml | – notice: 2021 American Chemical Society |
DBID | AAYXX CITATION ADTPV AOWAS D95 |
DOI | 10.1021/acs.jpcc.0c10136 |
DatabaseName | CrossRef SwePub SwePub Articles SWEPUB Lunds universitet |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1932-7455 |
EndPage | 3889 |
ExternalDocumentID | oai_lup_lub_lu_se_89697040_f95f_475e_9c3c_5803d283385f 10_1021_acs_jpcc_0c10136 c18509140 |
GroupedDBID | .K2 55A 5GY 5VS 7~N 85S 8RP AABXI ABFLS ABMVS ABPPZ ABUCX ACGFS ACNCT ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CS3 D0L DU5 EBS ED ED~ F5P GNL IH9 IHE JG JG~ K2 RNS ROL UI2 UKR VF5 VG9 VQA W1F 4.4 53G AAYXX ABJNI ABQRX ADHLV AHGAQ CITATION CUPRZ GGK 186 6TJ ADTPV AFFNX ANTXH AOWAS D95 EJD LG6 UQL ZCG |
ID | FETCH-LOGICAL-a349t-d7671bbcd9197bc3a0ce846162356de89e7d76a3b5f3811e3704263455d7b9cf3 |
IEDL.DBID | ACS |
ISSN | 1932-7447 |
IngestDate | Sat Aug 24 00:50:22 EDT 2024 Fri Aug 23 01:15:12 EDT 2024 Sat Feb 27 03:12:56 EST 2021 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 7 |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-a349t-d7671bbcd9197bc3a0ce846162356de89e7d76a3b5f3811e3704263455d7b9cf3 |
ORCID | 0000-0001-7001-7930 0000-0003-1620-7228 0000-0002-2347-5223 0000-0003-4822-9122 0000-0002-1152-8201 |
PageCount | 10 |
ParticipantIDs | swepub_primary_oai_lup_lub_lu_se_89697040_f95f_475e_9c3c_5803d283385f crossref_primary_10_1021_acs_jpcc_0c10136 acs_journals_10_1021_acs_jpcc_0c10136 |
ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 |
PublicationCentury | 2000 |
PublicationDate | 2021-02-25 |
PublicationDateYYYYMMDD | 2021-02-25 |
PublicationDate_xml | – month: 02 year: 2021 text: 2021-02-25 day: 25 |
PublicationDecade | 2020 |
PublicationTitle | Journal of physical chemistry. C |
PublicationTitleAlternate | J. Phys. Chem. C |
PublicationYear | 2021 |
Publisher | American Chemical Society |
Publisher_xml | – name: American Chemical Society |
References | ref9/cit9 ref45/cit45 ref6/cit6 ref36/cit36 ref3/cit3 ref27/cit27 ref18/cit18 Heinzel T. (ref40/cit40) 2003; 3 ref11/cit11 ref25/cit25 ref16/cit16 ref29/cit29 ref32/cit32 ref23/cit23 ref39/cit39 ref14/cit14 ref8/cit8 ref5/cit5 ref31/cit31 ref2/cit2 ref43/cit43 ref34/cit34 ref37/cit37 ref28/cit28 ref20/cit20 ref17/cit17 ref10/cit10 ref26/cit26 ref35/cit35 ref19/cit19 ref21/cit21 ref12/cit12 ref15/cit15 ref42/cit42 ref46/cit46 ref41/cit41 ref22/cit22 ref13/cit13 ref33/cit33 ref4/cit4 ref30/cit30 ref1/cit1 ref24/cit24 ref38/cit38 ref44/cit44 ref7/cit7 |
References_xml | – ident: ref7/cit7 doi: 10.1039/b303244b – ident: ref9/cit9 doi: 10.1126/science.aac6368 – ident: ref38/cit38 doi: 10.1103/physrevb.44.1646 – ident: ref46/cit46 doi: 10.1016/s0009-2614(00)00305-5 – ident: ref25/cit25 doi: 10.1039/c9cp04095a – ident: ref22/cit22 doi: 10.1016/j.cplett.2018.08.026 – ident: ref26/cit26 doi: 10.1021/acsanm.9b01522 – ident: ref31/cit31 doi: 10.1021/jp207571n – ident: ref23/cit23 doi: 10.1021/acs.jpcc.8b01589 – ident: ref4/cit4 doi: 10.1007/s10562-014-1402-6 – ident: ref12/cit12 doi: 10.1021/jp036985z – ident: ref14/cit14 doi: 10.1063/1.3427246 – ident: ref5/cit5 doi: 10.1007/s10562-016-1925-0 – ident: ref15/cit15 doi: 10.1016/j.cplett.2012.03.080 – ident: ref28/cit28 doi: 10.1021/acsnano.8b02127 – ident: ref16/cit16 doi: 10.1103/physrevb.85.035407 – ident: ref8/cit8 doi: 10.1016/j.susc.2008.04.040 – ident: ref20/cit20 doi: 10.1021/acs.jpcc.6b07828 – ident: ref19/cit19 doi: 10.1021/acs.jpcc.9b05109 – ident: ref36/cit36 doi: 10.1103/physrevb.89.235429 – ident: ref33/cit33 doi: 10.1595/147106706x129088 – ident: ref17/cit17 doi: 10.1088/1367-2630/11/10/103045 – ident: ref21/cit21 doi: 10.1021/acscatal.5b00245 – ident: ref45/cit45 doi: 10.1103/physrevb.86.075409 – volume: 3 volume-title: Mesoscopic Electronics in Solid State Nanostructures year: 2003 ident: ref40/cit40 contributor: fullname: Heinzel T. – ident: ref29/cit29 doi: 10.1021/acsnano.6b05819 – ident: ref41/cit41 doi: 10.1038/srep30449 – ident: ref44/cit44 doi: 10.1016/0040-6090(88)90008-9 – ident: ref13/cit13 doi: 10.1080/01614940.2011.596430 – ident: ref18/cit18 doi: 10.1063/1.3246166 – ident: ref32/cit32 doi: 10.1595/147106710x493124 – ident: ref6/cit6 doi: 10.1103/PhysRevLett.97.215501 – ident: ref10/cit10 doi: 10.1126/science.1085721 – ident: ref3/cit3 doi: 10.1088/0022-3727/33/11/201 – ident: ref35/cit35 doi: 10.1007/s100510070019 – ident: ref1/cit1 doi: 10.1038/495453a – ident: ref42/cit42 doi: 10.1038/ncomms9662 – ident: ref30/cit30 doi: 10.1063/1.2432410 – ident: ref11/cit11 doi: 10.1021/jacs.7b07093 – ident: ref24/cit24 doi: 10.1007/s11244-015-0407-8 – ident: ref39/cit39 doi: 10.1126/sciadv.aay4289 – ident: ref2/cit2 doi: 10.1016/s0021-9517(02)00112-4 – ident: ref27/cit27 doi: 10.1063/5.0011616 – ident: ref34/cit34 doi: 10.1103/physrevlett.110.086111 – ident: ref37/cit37 doi: 10.1147/rd.321.0144 – ident: ref43/cit43 doi: 10.1021/nn301675f |
SSID | ssj0053013 |
Score | 2.4530363 |
Snippet | Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron... Motivated by the relevance of Pt clusters in heterogeneous catalysis, ordered Pt cluster superlattices are templated by the moiré of monolayer hexagonal boron... |
SourceID | swepub crossref acs |
SourceType | Open Access Repository Aggregation Database Publisher |
StartPage | 3880 |
SubjectTerms | C: Chemical and Catalytic Reactivity at Interfaces Condensed Matter Physics Den kondenserade materiens fysik Fysik Natural Sciences Naturvetenskap Physical Sciences |
Title | Growth, Stability, and Electronic Decoupling of Pt Clusters on h‑BN/Ir(111) |
URI | http://dx.doi.org/10.1021/acs.jpcc.0c10136 https://lup.lub.lu.se/record/89697040-f95f-475e-9c3c-5803d283385f |
Volume | 125 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1PTxUxEG8UD3pRVAyokB40kYR9bLfttj3C4yGQQEyEhFvTvxAk-17Y3YOe_Ap8RT6J0919GMAYDr1sJpvJdLbzm53pbxD6xKUlwhqS-ehkxmLJM2OYzCwTuVUsKt790D88KvdO2MEpP_1Lk3O_gl-QTePq0cXMuVHuSCIYe4qeFamBMMGg8ff5qcvBUWlfQQbEyJgYSpL_ekMKRK6-E4ju0IR2oWX3VT-jqO4YCVNHyY9R29iR-_WQr_ERWi-ilwPCxFu9S7xGT0L1Bj0fzwe7vUWHXyH1bs43MADNrjX25wY2lceT24k4eAeS0jbd1T3D04i_NXh82SZGhRpPK3x-8_t6-2hz_-oLnGDrS-hkd3I83suGqQqZoUw1mRelINY6r4gS1lGTuwAghAAO4qUPUgUBIoZaHiGak0BFSrMo49wLq1yk79BCNa3CMsK2DMQLQBSFKZiwpZTcWUjJSPAhRMtW0Gewgx6-ilp3Be-C6O4hGEcPxllB6_Ot0LOeZOM_spN-r24lE0H2ZTuDZWHpOmipSgVa5xpcLWomeNDKUae5zKkHPEUlj-8fqdsH9KJIbSzpFjv_iBaaqzasAg5p7FrngH8AVRTVlw |
link.rule.ids | 230,315,786,790,891,2782,27109,27957,27958,57093,57143 |
linkProvider | American Chemical Society |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1Lb9QwEB6VcigX3qjl6QNIVGq28dqO7SMsW7bQXSFopd6s-EUFVXbVJAc48Rf4i_wSxtnsoiKE4OCLNbJG44nnm8z4M8BToSyVtqSZj05lPBYiK0uuMstlbjWPWnQ_9KezYnLC35yK0w2gq7swqESNK9VdEf8XuwDdT3OfFs4NckcTz9gVuCokpuMJDY0-rA5fgf7KloVkBI6cy74y-acVUjxy9aV4dIkttIswBzfg_Vq3rrHk86Bt7MB9_Y228b-UvwnXe7xJXiwd5BZshOo2bI1Wz7zdgelrTMSbsz2CsLNrlP2yR8rKk_H6fRzyClPUNt3c_UjmkbxryOi8TfwKNZlX5OzHt-8vZ_uHF8_xPNu9CycH4-PRJOvfWMhKxnWTeVlIaq3zmmppHStzFxCSUERFovBB6SBRpGRWRIztNDCZki7GhfDSahfZPdis5lXYBmKLQL1EfDEsh1zaQinhLCZoNPgQouU78AztYPpvpDZd-XtITTeJxjG9cXZgd7UjZrGk3PiL7Hi5ZWvJRJd93i5wWBymDkbpQqPWuUHHi4ZLEYx2zBmhcuYRXTEl4v1_1O0JbE2Op0fm6HD29gFcG6YGl3S_XTyEzeaiDY8QoTT2ceeTPwHir94C |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV3NbtQwEB6VIgEX_hEFCj6ARKVmG6_t2D62211aoKtKUNSbFf9RQZVdNckBTrwCr8iTdJzNrlSEEBx8sSxrYo8932TG3wC8FMpSaUua-ehUxmMhsrLkKrNc5lbzqEX3Q_9oWhyc8Len4nQNxPItDApR40x1F8RPp3ruY88wQHdS_5e5c4Pc0cQ1dg2ui1S_OyGi0YflBSxQZ9kimIzgkXPZRyf_NEOySa6-YpOuMIZ2VmZyBz6t5OuSS74O2sYO3PffqBv_-wPuwu0ed5LdhaLcg7VQ3Yebo2W5twdw9AYd8uZsmyD87BJmv22TsvJkvKqTQ_bRVW3TC97PZBbJcUNG523iWajJrCJnv3783JvuHF68xntt6yGcTMYfRwdZX2shKxnXTeZlIam1zmuqpXWszF1AaEIRHYnCB6WDxCElsyKijaeByeR8MS6El1a7yB7BejWrwmMgtgjUS8QZw3LIpS2UEs6io0aDDyFavgGvcB1Mf1Zq04XBh9R0nbg4pl-cDdha7oqZL6g3_jJ2vNi21chEm33ezrFZbKYORulCo9S5QQWMhksRjHbMGaFy5hFlMSXik3-U7QXcON6fmPeH03dP4dYw5bmkZ-7iGaw3F23YRKDS2OedWl4CK3_gfA |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Growth%2C+Stability%2C+and+Electronic+Decoupling+of+Pt+Clusters+on+h%E2%80%91BN%2FIr%28111%29&rft.jtitle=Journal+of+physical+chemistry.+C&rft.au=Will%2C+Moritz&rft.au=Hartl%2C+Tobias&rft.au=Boix+de+la+Cruz%2C+Virginia&rft.au=Lacovig%2C+Paolo&rft.date=2021-02-25&rft.pub=American+Chemical+Society&rft.issn=1932-7447&rft.eissn=1932-7455&rft.volume=125&rft.issue=7&rft.spage=3880&rft.epage=3889&rft_id=info:doi/10.1021%2Facs.jpcc.0c10136&rft.externalDocID=c18509140 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1932-7447&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1932-7447&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1932-7447&client=summon |