A Resonance Raman, Surface-Enhanced Resonance Raman, IR, and ab Initio Vibrational Spectroscopic Study of Nickel(II) Tetraazaannulene Complexes

• Published in: Inorganic chemistry Vol. 42; no. 11; pp. 3565 - 3575
• Main Authors: Bell, Stephen, Crayston, Joe A, Dines, Trevor J, Ellahi, Saira B, Smith, Caroline I
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 02.06.2003

The IR and resonance Raman spectra of the nickel(II) complexes of dibenzo[b,i][1,4,8,11]tetraaza[14]annulene (TAA) and 5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11]tetraaza[14]annulene (TMTAA) have been measured and compared with ab initio calculations of the vibrational wavenumbers at the B3-LYP leve...