Photoionization of Propargyl and Bromopropargyl Radicals: A Threshold Photoelectron Spectroscopic Study
In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive intermediates were produced by flash pyrolysis of suitable precursors and ionized by VUV synchrotron radiation. The TPES of the propargyl radical was s...
Saved in:
| Published in | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 115; no. 11; pp. 2225 - 2230 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
24.03.2011
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive intermediates were produced by flash pyrolysis of suitable precursors and ionized by VUV synchrotron radiation. The TPES of the propargyl radical was simulated using data from a recent high-level computational study. An ionization energy (IE) of 8.71 ± 0.02 eV was obtained, in excellent agreement with computations, but slightly above previous experimental IEs. The pyrolysis of 1,3-dibromopropyne delivers both 1- and 3-bromopropargyl radicals that can be distinguished by their different ionization energies (8.34 and 8.16 eV). To explain the vibrational structure, a Franck−Condon simulation was performed, based on DFT calculations, which can account for all major spectral features. Bromopropargyl photoionizes dissociatively beginning at around 10.1 eV. Cationic excited states of 1- and 3-bromopropargyl were tentatively identified. The dissociative photoionization of the precursor (1,3-dibromopropyne) was also examined, delivering an AE0K (C3H2Br+/C3H2Br2) of 10.6 eV. |
|---|---|
| AbstractList | In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive intermediates were produced by flash pyrolysis of suitable precursors and ionized by VUV synchrotron radiation. The TPES of the propargyl radical was simulated using data from a recent high-level computational study. An ionization energy (IE) of 8.71 ± 0.02 eV was obtained, in excellent agreement with computations, but slightly above previous experimental IEs. The pyrolysis of 1,3-dibromopropyne delivers both 1- and 3-bromopropargyl radicals that can be distinguished by their different ionization energies (8.34 and 8.16 eV). To explain the vibrational structure, a Franck-Condon simulation was performed, based on DFT calculations, which can account for all major spectral features. Bromopropargyl photoionizes dissociatively beginning at around 10.1 eV. Cationic excited states of 1- and 3-bromopropargyl were tentatively identified. The dissociative photoionization of the precursor (1,3-dibromopropyne) was also examined, delivering an AE(0K) (C(3)H(2)Br(+)/C(3)H(2)Br(2)) of 10.6 eV. In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive intermediates were produced by flash pyrolysis of suitable precursors and ionized by VUV synchrotron radiation. The TPES of the propargyl radical was simulated using data from a recent high-level computational study. An ionization energy (IE) of 8.71 ± 0.02 eV was obtained, in excellent agreement with computations, but slightly above previous experimental IEs. The pyrolysis of 1,3-dibromopropyne delivers both 1- and 3-bromopropargyl radicals that can be distinguished by their different ionization energies (8.34 and 8.16 eV). To explain the vibrational structure, a Franck−Condon simulation was performed, based on DFT calculations, which can account for all major spectral features. Bromopropargyl photoionizes dissociatively beginning at around 10.1 eV. Cationic excited states of 1- and 3-bromopropargyl were tentatively identified. The dissociative photoionization of the precursor (1,3-dibromopropyne) was also examined, delivering an AE0K (C3H2Br+/C3H2Br2) of 10.6 eV. |
| Author | Garcia, Gustavo A Lang, Melanie Alcaraz, Christian Cunha de Miranda, Bárbara K Noller, Bastian Hemberger, Patrick Soldi-Lose, Héloïse Fischer, Ingo |
| AuthorAffiliation | Synchrotron SOLEIL Universidade Federal Fluminense University of Würzburg CNRS & Université Paris |
| AuthorAffiliation_xml | – name: University of Würzburg – name: Synchrotron SOLEIL – name: Universidade Federal Fluminense – name: CNRS & Université Paris |
| Author_xml | – sequence: 1 givenname: Patrick surname: Hemberger fullname: Hemberger, Patrick – sequence: 2 givenname: Melanie surname: Lang fullname: Lang, Melanie – sequence: 3 givenname: Bastian surname: Noller fullname: Noller, Bastian – sequence: 4 givenname: Ingo surname: Fischer fullname: Fischer, Ingo email: ingo.fischer@uni-wuerzburg.de – sequence: 5 givenname: Christian surname: Alcaraz fullname: Alcaraz, Christian – sequence: 6 givenname: Bárbara K surname: Cunha de Miranda fullname: Cunha de Miranda, Bárbara K – sequence: 7 givenname: Gustavo A surname: Garcia fullname: Garcia, Gustavo A – sequence: 8 givenname: Héloïse surname: Soldi-Lose fullname: Soldi-Lose, Héloïse |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/21366257$$D View this record in MEDLINE/PubMed https://hal.science/hal-04155800$$DView record in HAL |
| BookMark | eNptkU1LxDAQhoMo6qoH_4D0IuKhmkmatvG2Ln7Bgosf55BNUrdLt6lJK6y_3uyH9eJphuGZB2beAdqtbW0QOgV8BZjA9bwBIAB4voMOgREcMwJsN_Q45zFLKT9AA-_nGGOgJNlHBwRomhKWHaKPycy2trR1-S3bUCJbRBNnG-k-llUkax3dOruwTT96kbpUsvI30TB6mznjZ7bS0dpiKqNaFxyvzbrxyjalil7bTi-P0V4RtszJth6h9_u7t9FjPH5-eBoNx7GkSd7GUvM8VxnTkhY6VXyKlSKgAGtJmGIKTCoxh4zyTKac54bRbDotcpJkmvOsoEfocuOdyUo0rlxItxRWluJxOBarGU6AsRzjLwjsxYYN1312xrdiUXplqkrWxnZe5GkCnHCgf1YVrvLOFL0asFhFIPoIAnu2tXbThdE9-fvzAJxvAKm8mNvO1eEh_4h-AFVzj7E |
| CitedBy_id | crossref_primary_10_1039_C5CP05346C crossref_primary_10_1021_acs_jpca_1c05672 crossref_primary_10_1021_acs_jpca_5b10743 crossref_primary_10_1021_jp403158z crossref_primary_10_1063_1_3698282 crossref_primary_10_1021_jp309037d crossref_primary_10_1021_acs_jpca_8b11809 crossref_primary_10_1039_C8CP00510A crossref_primary_10_1002_admi_202200192 crossref_primary_10_1021_jp309874q crossref_primary_10_1021_jp509324w crossref_primary_10_1016_j_cplett_2015_08_055 crossref_primary_10_1016_j_cplett_2011_10_026 crossref_primary_10_1039_c1sc00247c crossref_primary_10_1039_C7CP07893E crossref_primary_10_1039_D1CP00720C crossref_primary_10_1021_acs_jpca_5b02153 crossref_primary_10_1039_C9CY02587A crossref_primary_10_1063_1_4920951 crossref_primary_10_1063_1_4861175 crossref_primary_10_1557_s43578_022_00566_6 crossref_primary_10_1063_1_3664864 crossref_primary_10_1002_chem_201702376 crossref_primary_10_1016_j_combustflame_2022_112547 crossref_primary_10_1021_acs_jpca_8b09640 crossref_primary_10_1002_chem_201903937 crossref_primary_10_1016_j_jaap_2017_02_020 crossref_primary_10_1039_C9CP06010C crossref_primary_10_1021_acs_jpca_0c01134 crossref_primary_10_1063_1_4984304 crossref_primary_10_1016_j_proci_2014_05_094 crossref_primary_10_1039_C9CP00623K crossref_primary_10_1021_acs_jpca_6b08750 crossref_primary_10_1063_1_4764306 crossref_primary_10_1063_1_4818982 crossref_primary_10_1063_1_4918634 crossref_primary_10_1021_acs_jpca_8b12244 crossref_primary_10_1039_C4CP02857K crossref_primary_10_1002_cphc_201900813 crossref_primary_10_1016_j_proci_2014_05_151 |
| Cites_doi | 10.1063/1.3079331 10.1063/1.1857475 10.1039/B301228J 10.1063/1.462569 10.1103/PhysRevB.37.785 10.1016/j.chemphys.2010.07.030 10.1063/1.464913 10.1016/S1387-3806(02)00737-6 10.1063/1.1900646 10.1116/1.1288196 10.1063/1.456153 10.1021/jp9068569 10.1039/B414163F 10.1021/ja01630a085 10.1021/jp909422q 10.1103/PhysRevB.33.8822 10.1063/1.1391268 10.1021/jp110831q 10.1016/0009-2614(94)01286-5 10.1063/1.2715917 10.1016/S0022-2860(84)87198-7 10.1039/B206170H 10.1063/1.479629 10.1063/1.470422 10.1063/1.1926274 10.1021/ja00027a014 10.1063/1.1143254 10.1021/jp052797s 10.1002/poc.1579 10.1039/b417160h 10.1021/jp104019d 10.1002/(SICI)1097-4601(1996)28:6<433::AID-KIN5>3.0.CO;2-W 10.1063/1.3237027 10.1063/1.480830 10.1039/b511343a 10.1039/B502051D 10.1016/S0301-0104(99)00218-9 10.1063/1.453520 10.1039/a907383c 10.1021/j100385a007 10.1016/j.ijms.2006.09.023 10.1016/S0010-2180(99)00163-7 10.1063/1.3298881 10.1063/1.480169 10.1063/1.1337073 10.1063/1.437352 10.1021/jp011008d 10.1016/S1387-3806(02)00592-4 10.1063/1.2168448 10.1063/1.462652 10.1016/j.cplett.2010.10.025 10.1021/ja012004p 10.1063/1.1593788 10.1016/0301-0104(96)00164-4 10.1063/1.2840350 10.1063/1.3067705 10.1063/1.2436062 10.1016/0009-2614(92)85609-E 10.1039/b915400k |
| ContentType | Journal Article |
| Copyright | Copyright © 2011 American Chemical Society Distributed under a Creative Commons Attribution 4.0 International License |
| Copyright_xml | – notice: Copyright © 2011 American Chemical Society – notice: Distributed under a Creative Commons Attribution 4.0 International License |
| DBID | NPM AAYXX CITATION 7X8 1XC |
| DOI | 10.1021/jp112110j |
| DatabaseName | PubMed CrossRef MEDLINE - Academic Hyper Article en Ligne (HAL) |
| DatabaseTitle | PubMed CrossRef MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1520-5215 |
| EndPage | 2230 |
| ExternalDocumentID | oai_HAL_hal_04155800v1 10_1021_jp112110j 21366257 f89868850 |
| Genre | Journal Article |
| GroupedDBID | - .K2 02 123 29L 4.4 53G 55A 5VS 7~N 85S 8RP AABXI ABFLS ABMVS ABPPZ ABPTK ABUCX ACGFS ACNCT ACS AEESW AENEX AFEFF ALMA_UNASSIGNED_HOLDINGS AQSVZ BAANH CJ0 CS3 D0L DU5 EBS ED ED~ EJD F20 F5P GNL IH9 IHE JG JG~ K2 LG6 PZZ RNS ROL TAE TN5 UI2 UKR UPT VF5 VG9 VQA W1F WH7 X YZZ ZHY --- -~X .DC ABJNI ABQRX ACBEA ADHLV AHGAQ CUPRZ GGK NPM XSW YQT ~02 AAYXX CITATION 7X8 1XC |
| ID | FETCH-LOGICAL-a348t-ad988c75da3fd6c9b0cc21c10da25c5c1e6a0917397a6998e537bbf8247d997f3 |
| IEDL.DBID | ACS |
| ISSN | 1089-5639 |
| IngestDate | Tue Oct 15 14:42:01 EDT 2024 Fri Aug 16 09:47:15 EDT 2024 Fri Aug 23 01:04:39 EDT 2024 Sat Sep 28 07:51:41 EDT 2024 Thu Aug 27 13:42:23 EDT 2020 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 11 |
| Language | English |
| License | Distributed under a Creative Commons Attribution 4.0 International License: http://creativecommons.org/licenses/by/4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a348t-ad988c75da3fd6c9b0cc21c10da25c5c1e6a0917397a6998e537bbf8247d997f3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0003-4844-229X 0000-0002-6816-4664 |
| PMID | 21366257 |
| PQID | 864192913 |
| PQPubID | 23479 |
| PageCount | 6 |
| ParticipantIDs | hal_primary_oai_HAL_hal_04155800v1 proquest_miscellaneous_864192913 crossref_primary_10_1021_jp112110j pubmed_primary_21366257 acs_journals_10_1021_jp112110j |
| ProviderPackageCode | JG~ 55A AABXI GNL VF5 7~N VG9 W1F ACS AEESW AFEFF .K2 ABMVS ABUCX IH9 BAANH AQSVZ ED~ UI2 |
| PublicationCentury | 2000 |
| PublicationDate | 20110324 2011-Mar-24 2011-03-24 |
| PublicationDateYYYYMMDD | 2011-03-24 |
| PublicationDate_xml | – month: 03 year: 2011 text: 20110324 day: 24 |
| PublicationDecade | 2010 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory |
| PublicationTitleAlternate | J. Phys. Chem. A |
| PublicationYear | 2011 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | Bodi A. (ref58/cit58) 2009; 11 Bodi A. (ref60/cit60) 2011; 115 Botschwina P. (ref18/cit18) 2010; 378 Orlando J. J. (ref27/cit27) 1996; 28 Clauberg H. (ref24/cit24) 1992; 114 Eisfeld W. (ref6/cit6) 2005; 7 Fischer I. (ref50/cit50) 2002; 216 Garcia G. A. (ref33/cit33) 2005; 76 Csaszar P. (ref39/cit39) 1984; 114 Fischer I. (ref51/cit51) 2007; 261 Garcia G. A. (ref29/cit29) 2009; 80 Lee C. T. (ref38/cit38) 1988; 37 D’Anna A. (ref1/cit1) 2000; 121 Hatch L. F. (ref36/cit36) 1953; 76 ref37/cit37 Jarvis G. K. (ref53/cit53) 1999; 1 Richard-Viard M. (ref28/cit28) 1996; 209 Morter C. L. (ref11/cit11) 1992; 195 Dunning T. H. (ref40/cit40) 1989; 90 Schüβler T. (ref22/cit22) 2005; 7 Tanaka K. (ref12/cit12) 1995; 103 Mercier B. (ref32/cit32) 2000; 18 Zhang T. (ref2/cit2) 2006; 124 Nahon L. (ref31/cit31) 2001; 72 Noller B. (ref35/cit35) 2007; 126 Zierhut M. (ref9/cit9) 2005; 122 Chen P. (ref21/cit21) 2009; 131 Moc J. (ref26/cit26) 1999; 247 Astholz D. C. (ref56/cit56) 1979; 70 Becke A. D. (ref45/cit45) 1993; 98 Sztáray B. (ref54/cit54) 2003; 74 Crider P. E. (ref7/cit7) 2009; 130 Marcouillé O. (ref30/cit30) 2007; 879 Song Y. (ref57/cit57) 2001; 115 Feller D. (ref43/cit43) 1992; 96 Spangenberg D. (ref47/cit47) 2003; 5 Garcia G. A. (ref59/cit59) 2001; 105 Baer T. (ref52/cit52) 2005; 7 Sumiyoshi Y. (ref13/cit13) 1994; 231 Minsek D. W. (ref19/cit19) 1990; 94 Perdev J. D. (ref46/cit46) 1986; 33 Weitzel K. M. (ref55/cit55) 1999; 111 Cunha de Miranda B. K. (ref48/cit48) 2010; 114 Roth D. (ref17/cit17) 2002; 4 Gilbert T. (ref20/cit20) 2000; 112 Kohn D. W. (ref34/cit34) 1992; 63 Lau K.-C. (ref49/cit49) 2005; 122 Tang W. (ref3/cit3) 2006; 110 Hemberger P. (ref4/cit4) 2010; 114 Deyerl H.-J. (ref5/cit5) 1999; 111 Pople J. A. (ref42/cit42) 1987; 87 Dopfer O. (ref14/cit14) 2002; 218 Kendall R. A. (ref41/cit41) 1992; 96 Taatjes C. A. (ref62/cit62) 2005; 7 Lee G. Y. (ref23/cit23) 2010; 23 Steinbauer M. (ref25/cit25) 2010; 500 Gusel’nikov L. E. (ref10/cit10) 1986; 12 Ricks A. M. (ref15/cit15) 2010; 132 Dopfer O. (ref16/cit16) 2002; 124 Goncher S. J. (ref8/cit8) 2008; 128 Hemberger P. (ref61/cit61) 2010; 114 ref44/cit44 |
| References_xml | – volume: 80 start-page: 023102 year: 2009 ident: ref29/cit29 publication-title: Rev. Sci. Instrum. doi: 10.1063/1.3079331 contributor: fullname: Garcia G. A. – volume: 122 start-page: 094302 year: 2005 ident: ref9/cit9 publication-title: J. Chem. Phys. doi: 10.1063/1.1857475 contributor: fullname: Zierhut M. – volume: 5 start-page: 2505 year: 2003 ident: ref47/cit47 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/B301228J contributor: fullname: Spangenberg D. – volume: 96 start-page: 6796 year: 1992 ident: ref41/cit41 publication-title: J. Chem. Phys. doi: 10.1063/1.462569 contributor: fullname: Kendall R. A. – volume: 37 start-page: 785 year: 1988 ident: ref38/cit38 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.37.785 contributor: fullname: Lee C. T. – volume: 378 start-page: 4 year: 2010 ident: ref18/cit18 publication-title: Chem. Phys. doi: 10.1016/j.chemphys.2010.07.030 contributor: fullname: Botschwina P. – volume: 98 start-page: 5648 year: 1993 ident: ref45/cit45 publication-title: J. Chem. Phys. doi: 10.1063/1.464913 contributor: fullname: Becke A. D. – volume: 218 start-page: 218 year: 2002 ident: ref14/cit14 publication-title: Int. J. Mass Spectrom. doi: 10.1016/S1387-3806(02)00737-6 contributor: fullname: Dopfer O. – volume: 76 start-page: 053302 year: 2005 ident: ref33/cit33 publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1900646 contributor: fullname: Garcia G. A. – volume: 18 start-page: 2533 year: 2000 ident: ref32/cit32 publication-title: J. Vac. Sci. Technol., A doi: 10.1116/1.1288196 contributor: fullname: Mercier B. – ident: ref44/cit44 – volume: 90 start-page: 1007 year: 1989 ident: ref40/cit40 publication-title: J. Chem. Phys. doi: 10.1063/1.456153 contributor: fullname: Dunning T. H. – volume: 114 start-page: 4698 year: 2010 ident: ref4/cit4 publication-title: J. Phys. Chem. A doi: 10.1021/jp9068569 contributor: fullname: Hemberger P. – volume: 7 start-page: 819 year: 2005 ident: ref22/cit22 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/B414163F contributor: fullname: Schüβler T. – volume: 76 start-page: 289 year: 1953 ident: ref36/cit36 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01630a085 contributor: fullname: Hatch L. F. – volume: 114 start-page: 4818 year: 2010 ident: ref48/cit48 publication-title: J. Phys. Chem. A doi: 10.1021/jp909422q contributor: fullname: Cunha de Miranda B. K. – volume: 33 start-page: 8822 year: 1986 ident: ref46/cit46 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.33.8822 contributor: fullname: Perdev J. D. – volume: 115 start-page: 4095 year: 2001 ident: ref57/cit57 publication-title: J. Chem. Phys. doi: 10.1063/1.1391268 contributor: fullname: Song Y. – volume: 115 start-page: 726 year: 2011 ident: ref60/cit60 publication-title: J. Phys. Chem. A doi: 10.1021/jp110831q contributor: fullname: Bodi A. – volume: 231 start-page: 569 year: 1994 ident: ref13/cit13 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(94)01286-5 contributor: fullname: Sumiyoshi Y. – volume: 126 start-page: 144302 year: 2007 ident: ref35/cit35 publication-title: J. Chem. Phys. doi: 10.1063/1.2715917 contributor: fullname: Noller B. – volume: 114 start-page: 31 year: 1984 ident: ref39/cit39 publication-title: J. Mol. Struct. doi: 10.1016/S0022-2860(84)87198-7 contributor: fullname: Csaszar P. – volume: 4 start-page: 4855 year: 2002 ident: ref17/cit17 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/B206170H contributor: fullname: Roth D. – volume: 111 start-page: 3441 year: 1999 ident: ref5/cit5 publication-title: J. Chem. Phys. doi: 10.1063/1.479629 contributor: fullname: Deyerl H.-J. – volume: 103 start-page: 6450 year: 1995 ident: ref12/cit12 publication-title: J. Chem. Phys. doi: 10.1063/1.470422 contributor: fullname: Tanaka K. – volume: 122 start-page: 224310 year: 2005 ident: ref49/cit49 publication-title: J. Chem. Phys. doi: 10.1063/1.1926274 contributor: fullname: Lau K.-C. – volume: 114 start-page: 99 year: 1992 ident: ref24/cit24 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00027a014 contributor: fullname: Clauberg H. – volume: 63 start-page: 4003 year: 1992 ident: ref34/cit34 publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1143254 contributor: fullname: Kohn D. W. – volume: 110 start-page: 2165 year: 2006 ident: ref3/cit3 publication-title: J. Phys. Chem. A doi: 10.1021/jp052797s contributor: fullname: Tang W. – volume: 23 start-page: 91 year: 2010 ident: ref23/cit23 publication-title: J. Phys. Org. Chem. doi: 10.1002/poc.1579 contributor: fullname: Lee G. Y. – volume: 7 start-page: 806 year: 2005 ident: ref62/cit62 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b417160h contributor: fullname: Taatjes C. A. – volume: 114 start-page: 11269 year: 2010 ident: ref61/cit61 publication-title: J. Phys. Chem. A doi: 10.1021/jp104019d contributor: fullname: Hemberger P. – volume: 28 start-page: 433 year: 1996 ident: ref27/cit27 publication-title: Int. J. Chem. Kinet. doi: 10.1002/(SICI)1097-4601(1996)28:6<433::AID-KIN5>3.0.CO;2-W contributor: fullname: Orlando J. J. – ident: ref37/cit37 – volume: 131 start-page: 159904 year: 2009 ident: ref21/cit21 publication-title: J. Chem. Phys. doi: 10.1063/1.3237027 contributor: fullname: Chen P. – volume: 112 start-page: 2575 year: 2000 ident: ref20/cit20 publication-title: J. Chem. Phys. doi: 10.1063/1.480830 contributor: fullname: Gilbert T. – volume: 7 start-page: 3924 year: 2005 ident: ref6/cit6 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b511343a contributor: fullname: Eisfeld W. – volume: 12 start-page: 2829 year: 1986 ident: ref10/cit10 publication-title: Russ. Chem. Bull. contributor: fullname: Gusel’nikov L. E. – volume: 7 start-page: 1507 year: 2005 ident: ref52/cit52 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/B502051D contributor: fullname: Baer T. – volume: 247 start-page: 365 year: 1999 ident: ref26/cit26 publication-title: Chem. Phys. doi: 10.1016/S0301-0104(99)00218-9 contributor: fullname: Moc J. – volume: 87 start-page: 5968 year: 1987 ident: ref42/cit42 publication-title: J. Chem. Phys. doi: 10.1063/1.453520 contributor: fullname: Pople J. A. – volume: 1 start-page: 5259 year: 1999 ident: ref53/cit53 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/a907383c contributor: fullname: Jarvis G. K. – volume: 94 start-page: 8399 year: 1990 ident: ref19/cit19 publication-title: J. Phys. Chem. doi: 10.1021/j100385a007 contributor: fullname: Minsek D. W. – volume: 261 start-page: 227 year: 2007 ident: ref51/cit51 publication-title: Int. J. Mass Spectrom. doi: 10.1016/j.ijms.2006.09.023 contributor: fullname: Fischer I. – volume: 121 start-page: 418 year: 2000 ident: ref1/cit1 publication-title: Combust. Flame doi: 10.1016/S0010-2180(99)00163-7 contributor: fullname: D’Anna A. – volume: 132 start-page: 051101 year: 2010 ident: ref15/cit15 publication-title: J. Chem. Phys. doi: 10.1063/1.3298881 contributor: fullname: Ricks A. M. – volume: 111 start-page: 8267 year: 1999 ident: ref55/cit55 publication-title: J. Chem. Phys. doi: 10.1063/1.480169 contributor: fullname: Weitzel K. M. – volume: 72 start-page: 1320 year: 2001 ident: ref31/cit31 publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1337073 contributor: fullname: Nahon L. – volume: 70 start-page: 5107 year: 1979 ident: ref56/cit56 publication-title: J. Chem. Phys. doi: 10.1063/1.437352 contributor: fullname: Astholz D. C. – volume: 105 start-page: 8296 year: 2001 ident: ref59/cit59 publication-title: J. Phys. Chem. A doi: 10.1021/jp011008d contributor: fullname: Garcia G. A. – volume: 216 start-page: 131 year: 2002 ident: ref50/cit50 publication-title: Int. J. Mass Spectrom. doi: 10.1016/S1387-3806(02)00592-4 contributor: fullname: Fischer I. – volume: 124 start-page: 074302 year: 2006 ident: ref2/cit2 publication-title: J. Chem. Phys. doi: 10.1063/1.2168448 contributor: fullname: Zhang T. – volume: 96 start-page: 6104 year: 1992 ident: ref43/cit43 publication-title: J. Chem. Phys. doi: 10.1063/1.462652 contributor: fullname: Feller D. – volume: 500 start-page: 232 year: 2010 ident: ref25/cit25 publication-title: Chem. Phys. Lett. doi: 10.1016/j.cplett.2010.10.025 contributor: fullname: Steinbauer M. – volume: 124 start-page: 494 year: 2002 ident: ref16/cit16 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja012004p contributor: fullname: Dopfer O. – volume: 74 start-page: 3763 year: 2003 ident: ref54/cit54 publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1593788 contributor: fullname: Sztáray B. – volume: 209 start-page: 159 year: 1996 ident: ref28/cit28 publication-title: Chem. Phys. doi: 10.1016/0301-0104(96)00164-4 contributor: fullname: Richard-Viard M. – volume: 128 start-page: 114303 year: 2008 ident: ref8/cit8 publication-title: J. Chem. Phys. doi: 10.1063/1.2840350 contributor: fullname: Goncher S. J. – volume: 130 start-page: 044310 year: 2009 ident: ref7/cit7 publication-title: J. Chem. Phys. doi: 10.1063/1.3067705 contributor: fullname: Crider P. E. – volume: 879 start-page: 311 year: 2007 ident: ref30/cit30 publication-title: AIP Conf. Proc. doi: 10.1063/1.2436062 contributor: fullname: Marcouillé O. – volume: 195 start-page: 316 year: 1992 ident: ref11/cit11 publication-title: Chem. Phys. Lett. doi: 10.1016/0009-2614(92)85609-E contributor: fullname: Morter C. L. – volume: 11 start-page: 11013 year: 2009 ident: ref58/cit58 publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b915400k contributor: fullname: Bodi A. |
| SSID | ssj0001324 |
| Score | 2.264213 |
| Snippet | In this Article, we present mass-selected threshold photoelectron spectra of propargyl as well as the 1- and 3-bromopropargyl radicals. The reactive... |
| SourceID | hal proquest crossref pubmed acs |
| SourceType | Open Access Repository Aggregation Database Index Database Publisher |
| StartPage | 2225 |
| SubjectTerms | A: Kinetics, Spectroscopy Chemical Sciences or physical chemistry Theoretical and |
| Title | Photoionization of Propargyl and Bromopropargyl Radicals: A Threshold Photoelectron Spectroscopic Study |
| URI | http://dx.doi.org/10.1021/jp112110j https://www.ncbi.nlm.nih.gov/pubmed/21366257 https://search.proquest.com/docview/864192913 https://hal.science/hal-04155800 |
| Volume | 115 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwhV3BTtwwEB0BPcCl0ALtthRZLddAbMdxwm27LVpVVYUKSNwi23GWAkpWm2wl-Hpmks2qFdBencSy_OzMG8_4DcBBWCCouQ0Dl5giiBKrcUspESBVkGhuI9I7oWyLH_H4Ivp2qS5X4NMzEXzBj66nnGTIwutVeCE0bgriP6Oz5e8W3amoy6JPA4X2tpcP-vNTMj2u_sv0rF5R4uNzrLK1Lieb8KW_o9Mlldwczht76O4fSzb-a-Bb8HLBLtmwWw6vYMWXr2F91Bd124bJ6VXVVHQG212_ZFXBTmfoOM8md7fMlDn7TPl502XTT9MGcupjNmTniHtN4SrW9tJX0GFUw74hVcxq-ssxyky824GLk6_no3GwqLUQGBklTWDyNEmcVrmRRR671IbOCe54mBuhnHLcxwaphUb6YmJ00byS2toiEZHO01QXchfWyqr0b4EJRFx4aY1GeqJCbqz3nnsdx0VUuNwPYB_ByBZ7pc7aMLhAN6SfrwF87HHKpp3mxpMvIYLL56SSPR5-z6iNVAcUEuHffACsBzjDiaZYiCl9Na-zJKbwd8rlAN50wC-7ElzG6BXqd_8b53vY6E6YZSCiPVhrZnP_ASlKY_fbJfoAsx7fPQ |
| link.rule.ids | 230,315,783,787,888,2772,27088,27936,27937,57066,57116 |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1Lb9QwEB71cSgXoLy6FIqFuKbEdhwnvW1XVNuyVBVspd4i23FaWpSsNlmk8us7k2yWh4rg6iSjkcfOfOMZfwPwLizQqLkNA5eYIogSq3FLKREgVJDobiPiO6Fqi9N4fB6dXKiLJU0O3YVBJWqUVLdJ_J_sAvz99YwTG1l4vQ6bSqOjJBg0-rL662JUFXXF9Gmg0O32LEK_fkoeyNW_eaD1K6p__Bu4bJ3M0aOuW1GrXltbcrO_aOy--_EHc-P_6f8YHi6xJht2i2Mb1nz5BLZGfYu3p3B5dlU1FZ3IdpcxWVWwszmG0fPL22_MlDk7pGq92Wros2nTOvUBG7IproKaklesldL302HU0b4hjsxq9tUxqlO8fQbnRx-mo3Gw7LwQGBklTWDyNEmcVrmRRR671IbOCe54mBuhnHLcxwaBhkYwY2IM2LyS2toiEZHO01QX8jlslFXpd4AJtL_w0hqNYEWF3FjvPfc6jouocLkfwB5OV7bcOXXWJsUFBiX9fA3gbW-ubNYxcNz7Ehpy9Zw4s8fDSUZjxEGgEBZ_5wNgvZ0znGjKjJjSV4s6S2JKhqdcDuBFZ_-VKMFljDGifvkvPd_A1nj6aZJNjk8_7sKD7uxZBiJ6BRvNfOFfI3hp7F67au8AJBbnog |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV1Zb9QwEB7RIgEv3MdyFAvxmhLbcZzwtiysFqjKClqpb5HPloKSaJNFKr-ecS4BAsGrE1uOZ5z5xjP-BuB57FGoVseRyZSPkkxL3FKCRQgVOJrbJPCdhGyLw3R1nLw7ESeDoxjuwuAkGhyp6YL4YVfX1g8MA_TFeU0DI1l8vgOXhaRdWHa--DT9edGzSvqE-jwSaHpHJqGfuwYrZJpfrNDOWciB_BvA7AzN8gZ8mKbY5Zd82d-2et98_4298f-_4SZcHzAnmfdKcgsuufI2XF2Mpd7uwOn6rGqrcDLbX8oklSfrDbrTm9OLr0SVlrwKWXv11PRRdeGd5iWZkyPUhiYEsUg3ylhXh4TK9m3gyqzqz4aEfMWLu3C8fHO0WEVDBYZI8SRrI2XzLDNSWMW9TU2uY2MYNTS2igkjDHWpQsAhEdSoFB03J7jU2mcskTbPpef3YLesSvcACEM9YI5rJRG0iJgq7ZyjTqapT7yxbgZ7uGTFsIOaoguOM3ROxvWawbNRZEXdM3H88SUU5vQ8cGev5gdFaAtcBALh8Tc6AzLKusCFDhESVbpq2xRZGoLiOeUzuN_rwDQUozxFX1E-_Nc8n8KV9etlcfD28P0juNYfQfOIJY9ht91s3RPEMK3e6xT3B6QV6hw |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Photoionization+of+Propargyl+and+Bromopropargyl+Radicals%3A+A+Threshold+Photoelectron+Spectroscopic+Study&rft.jtitle=The+journal+of+physical+chemistry.+A%2C+Molecules%2C+spectroscopy%2C+kinetics%2C+environment%2C+%26+general+theory&rft.au=Hemberger%2C+Patrick&rft.au=Lang%2C+Melanie&rft.au=Noller%2C+Bastian&rft.au=Fischer%2C+Ingo&rft.date=2011-03-24&rft.issn=1089-5639&rft.eissn=1520-5215&rft.volume=115&rft.issue=11&rft.spage=2225&rft.epage=2230&rft_id=info:doi/10.1021%2Fjp112110j&rft.externalDBID=n%2Fa&rft.externalDocID=10_1021_jp112110j |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1089-5639&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1089-5639&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1089-5639&client=summon |