Newly Developed Stepwise Electroless Deposition Enables a Remarkably Facile Synthesis of Highly Active and Stable Amorphous Pd Nanoparticle Electrocatalysts for Oxygen Reduction Reaction
This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode s...
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| Published in | Journal of the American Chemical Society Vol. 136; no. 14; pp. 5217 - 5220 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
09.04.2014
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| Subjects | |
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| Abstract | This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode substrate (glassy carbon, carbon cloth) was sequentially dipped for 10 s into two separate solutions of a reducing agent (sodium hypophosphite (NaH2PO2)) and Pd ions to deposit amorphous Pd nanoparticles containing phosphorus (Pd–P). By repeating the deposition cycles, the specific and mass activities of the Pd nanoparticles can be actively tuned. Owing to the nanoscale amorphous nature, the obtained Pd–P nanoparticle electrocatalysts exhibited superior specific and mass activities compared with crystalline Pd nanoparticles synthesized by another reducing agent (N2H4) and commercial Pt-loaded carbon (Pt/C) and Pd-loaded carbon (Pd/C). The specific and mass activities of the amorphous Pd–P nanoparticles were over 4.5 times and 2.6 times higher than previously reported values of Pd and Pt catalysts. |
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| AbstractList | This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode substrate (glassy carbon, carbon cloth) was sequentially dipped for 10 s into two separate solutions of a reducing agent (sodium hypophosphite (NaH2PO2)) and Pd ions to deposit amorphous Pd nanoparticles containing phosphorus (Pd–P). By repeating the deposition cycles, the specific and mass activities of the Pd nanoparticles can be actively tuned. Owing to the nanoscale amorphous nature, the obtained Pd–P nanoparticle electrocatalysts exhibited superior specific and mass activities compared with crystalline Pd nanoparticles synthesized by another reducing agent (N2H4) and commercial Pt-loaded carbon (Pt/C) and Pd-loaded carbon (Pd/C). The specific and mass activities of the amorphous Pd–P nanoparticles were over 4.5 times and 2.6 times higher than previously reported values of Pd and Pt catalysts. This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode substrate (glassy carbon, carbon cloth) was sequentially dipped for 10 s into two separate solutions of a reducing agent (sodium hypophosphite (NaH2PO2)) and Pd ions to deposit amorphous Pd nanoparticles containing phosphorus (Pd-P). By repeating the deposition cycles, the specific and mass activities of the Pd nanoparticles can be actively tuned. Owing to the nanoscale amorphous nature, the obtained Pd-P nanoparticle electrocatalysts exhibited superior specific and mass activities compared with crystalline Pd nanoparticles synthesized by another reducing agent (N2H4) and commercial Pt-loaded carbon (Pt/C) and Pd-loaded carbon (Pd/C). The specific and mass activities of the amorphous Pd-P nanoparticles were over 4.5 times and 2.6 times higher than previously reported values of Pd and Pt catalysts.This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode substrate (glassy carbon, carbon cloth) was sequentially dipped for 10 s into two separate solutions of a reducing agent (sodium hypophosphite (NaH2PO2)) and Pd ions to deposit amorphous Pd nanoparticles containing phosphorus (Pd-P). By repeating the deposition cycles, the specific and mass activities of the Pd nanoparticles can be actively tuned. Owing to the nanoscale amorphous nature, the obtained Pd-P nanoparticle electrocatalysts exhibited superior specific and mass activities compared with crystalline Pd nanoparticles synthesized by another reducing agent (N2H4) and commercial Pt-loaded carbon (Pt/C) and Pd-loaded carbon (Pd/C). The specific and mass activities of the amorphous Pd-P nanoparticles were over 4.5 times and 2.6 times higher than previously reported values of Pd and Pt catalysts. This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were synthesized by a remarkably facile and quick electroless deposition process newly developed in this study (process time <5 min). An electrode substrate (glassy carbon, carbon cloth) was sequentially dipped for 10 s into two separate solutions of a reducing agent (sodium hypophosphite (NaH₂PO₂)) and Pd ions to deposit amorphous Pd nanoparticles containing phosphorus (Pd–P). By repeating the deposition cycles, the specific and mass activities of the Pd nanoparticles can be actively tuned. Owing to the nanoscale amorphous nature, the obtained Pd–P nanoparticle electrocatalysts exhibited superior specific and mass activities compared with crystalline Pd nanoparticles synthesized by another reducing agent (N₂H₄) and commercial Pt-loaded carbon (Pt/C) and Pd-loaded carbon (Pd/C). The specific and mass activities of the amorphous Pd–P nanoparticles were over 4.5 times and 2.6 times higher than previously reported values of Pd and Pt catalysts. |
| Author | Vo, Thang D.T Poon, Kee Chun Khezri, Bahareh Webster, Richard D Tan, Desmond C. L Su, Haibin Sato, Hirotaka |
| AuthorAffiliation | Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences School of Materials Science & Engineering School of Mechanical & Aerospace Engineering Nanyang Technological University |
| AuthorAffiliation_xml | – name: Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences – name: School of Materials Science & Engineering – name: School of Mechanical & Aerospace Engineering – name: Nanyang Technological University |
| Author_xml | – sequence: 1 givenname: Kee Chun surname: Poon fullname: Poon, Kee Chun – sequence: 2 givenname: Desmond C. L surname: Tan fullname: Tan, Desmond C. L – sequence: 3 givenname: Thang D.T surname: Vo fullname: Vo, Thang D.T – sequence: 4 givenname: Bahareh surname: Khezri fullname: Khezri, Bahareh – sequence: 5 givenname: Haibin surname: Su fullname: Su, Haibin – sequence: 6 givenname: Richard D surname: Webster fullname: Webster, Richard D – sequence: 7 givenname: Hirotaka surname: Sato fullname: Sato, Hirotaka email: hirosato@ntu.edu.sg |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/24661048$$D View this record in MEDLINE/PubMed |
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| Snippet | This paper reports on highly active and stable amorphous Pd nanoparticle electrocatalysts for the oxygen reduction reaction. The amorphous catalysts were... |
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| SubjectTerms | carbon catalysts electrodes ions nanoparticles oxygen palladium phosphorus platinum reducing agents sodium |
| Title | Newly Developed Stepwise Electroless Deposition Enables a Remarkably Facile Synthesis of Highly Active and Stable Amorphous Pd Nanoparticle Electrocatalysts for Oxygen Reduction Reaction |
| URI | http://dx.doi.org/10.1021/ja500275r https://www.ncbi.nlm.nih.gov/pubmed/24661048 https://www.proquest.com/docview/1514425835 https://www.proquest.com/docview/2000373847 |
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