High χ–Low N Block Polymers: How Far Can We Go?

• Published in: ACS macro letters Vol. 4; no. 9; pp. 1044 - 1050
• Main Authors: Sinturel, Christophe, Bates, Frank S., Hillmyer, Marc A.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 15.09.2015

Block polymers incorporating highly incompatible segments are termed “high χ” polymers, where χ is the Flory–Huggins interaction parameter. These materials have attracted a great deal of interest because low molar mass versions allow for the formation of microphase-separated domains with very small...