Adsorption of Atrazine from Water in Metal–Organic Framework Materials

The adsorptive removal of atrazine, an agricultural herbicide, from water by three water stable MOFs, ZIF-8, UiO-66, and UiO-67, and a commercial activated carbon, F400, was investigated. UiO-67, ZIF-8, and F400 were found to remove up to 98% of the atrazine from water, whereas UiO-66 is found to be...

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Published inJournal of chemical and engineering data Vol. 63; no. 7; pp. 2368 - 2375
Main Authors Akpinar, Isil, Yazaydin, A. Ozgur
Format Journal Article
LanguageEnglish
Published American Chemical Society 12.07.2018
Online AccessGet full text
ISSN0021-9568
1520-5134
DOI10.1021/acs.jced.7b00930

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Abstract The adsorptive removal of atrazine, an agricultural herbicide, from water by three water stable MOFs, ZIF-8, UiO-66, and UiO-67, and a commercial activated carbon, F400, was investigated. UiO-67, ZIF-8, and F400 were found to remove up to 98% of the atrazine from water, whereas UiO-66 is found to be ineffective. In an exceptional performance compared to the other adsorbents considered in our study, UiO-67 removed 98% of atrazine from water within only 2 min, whereas ZIF-8 and F400 took over 40 and 50 min, respectively, to remove the same amount of atrazine. Upon regeneration of UiO-67, minimal loss of adsorption capacity was observed, affirming its effective use for atrazine removal from water.
AbstractList The adsorptive removal of atrazine, an agricultural herbicide, from water by three water stable MOFs, ZIF-8, UiO-66, and UiO-67, and a commercial activated carbon, F400, was investigated. UiO-67, ZIF-8, and F400 were found to remove up to 98% of the atrazine from water, whereas UiO-66 is found to be ineffective. In an exceptional performance compared to the other adsorbents considered in our study, UiO-67 removed 98% of atrazine from water within only 2 min, whereas ZIF-8 and F400 took over 40 and 50 min, respectively, to remove the same amount of atrazine. Upon regeneration of UiO-67, minimal loss of adsorption capacity was observed, affirming its effective use for atrazine removal from water.
Author Akpinar, Isil
Yazaydin, A. Ozgur
AuthorAffiliation University College London
Department of Chemical Engineering
AuthorAffiliation_xml – name: Department of Chemical Engineering
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  givenname: Isil
  surname: Akpinar
  fullname: Akpinar, Isil
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  givenname: A. Ozgur
  orcidid: 0000-0001-8562-723X
  surname: Yazaydin
  fullname: Yazaydin, A. Ozgur
  email: ozgur.yazaydin@ucl.ac.uk
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Snippet The adsorptive removal of atrazine, an agricultural herbicide, from water by three water stable MOFs, ZIF-8, UiO-66, and UiO-67, and a commercial activated...
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