Enantioselective Construction of Bicyclic Pyran and Hydrindane Scaffolds via Intramolecular Rauhut–Currier Reactions Catalyzed by Thiourea-Phosphines

Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have been developed. By employing cyclohexadienones with a flexible ether or alkyl group linked internal enone moiety, optically enriched bicyclic pyran and hydrindane skeletons were constructed. Bifunction...

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Bibliographic Details
Published inACS catalysis Vol. 8; no. 9; pp. 8810 - 8815
Main Authors Li, Kaizhi, Jin, Zhichao, Chan, Wai-Lun, Lu, Yixin
Format Journal Article
LanguageEnglish
Published American Chemical Society 07.09.2018
Subjects
bifunctional phosphine
desymmetrization
thiourea
Rauhut−Currier reaction
hydrindane
bicyclic pyran
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