Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell

• Published in: Organic letters Vol. 26; no. 1; pp. 166 - 171
• Main Authors: Bityukov, Oleg V., Skokova, Ksenia V., Vil’, Vera A., Nikishin, Gennady I., Terent’ev, Alexander O.
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 12.01.2024; Amer Chemical Soc
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; TBHP; TERT; ARTEMISININ; ANODIC-OXIDATION; ALKANES

The generation of peroxy radicals from hydroperoxides with subsequent selective peroxidation of 1,3-dicarbonyls in an undivided electrochemical cell under constant current conditions is reported. The method provides a variety of peroxy-containing barbituric acids and 4-hydroxy-2­(5H)-furanones with...