Biomimetic Silver-Containing Colloids of Poly(2-methacryloyloxyethyl phosphorylcholine) and Their Film-Formation Properties
The synthesis of stable dispersions of hybrid colloids comprising copolymers of biocompatible 2-hydroxyethyl methacrylate (HEMA) and zwitterionic, biomimetic 2-methacryloyloxyethyl phosphorylcholine (MPC) incorporating antibacterial AgBF4 by inverse miniemulsion is described. The prepared hybrid col...
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Published in | Langmuir Vol. 28; no. 11; pp. 4974 - 4983 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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American Chemical Society
20.03.2012
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Abstract | The synthesis of stable dispersions of hybrid colloids comprising copolymers of biocompatible 2-hydroxyethyl methacrylate (HEMA) and zwitterionic, biomimetic 2-methacryloyloxyethyl phosphorylcholine (MPC) incorporating antibacterial AgBF4 by inverse miniemulsion is described. The prepared hybrid colloids were designed to provide both antibacterial and antifouling properties for the formation of interesting, multifunctional films. The obtained particles had sizes in the range of 130–160 nm with two different weight ratios of MPC to HEMA (1:10 and 2:5) and AgBF4 contents between 0% and 15%. The silver salt takes on the role of the lipophobe in stabilizing the miniemulsion droplets against Ostwald ripening and is reduced after polymerization to Ag nanoparticles by gaseous hydrazine. Subsequently, the hybrid particles are transformed into smooth and stable films with thicknesses between 145 and 225 nm by simple drop casting and solvent annealing. The dispersions and films were thoroughly characterized by DLS, TEM, SEM, EDX, TGA, UV–vis spectroscopy, ICP-OES, XRD, AFM, and contact angle measurements. After immersion into water, the films did not show detectable leakage of silver, so they could be employed as dual-functional antifouling and antibacterial coatings. |
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AbstractList | The synthesis of stable dispersions of hybrid colloids comprising copolymers of biocompatible 2-hydroxyethyl methacrylate (HEMA) and zwitterionic, biomimetic 2-methacryloyloxyethyl phosphorylcholine (MPC) incorporating antibacterial AgBF(4) by inverse miniemulsion is described. The prepared hybrid colloids were designed to provide both antibacterial and antifouling properties for the formation of interesting, multifunctional films. The obtained particles had sizes in the range of 130-160 nm with two different weight ratios of MPC to HEMA (1:10 and 2:5) and AgBF(4) contents between 0% and 15%. The silver salt takes on the role of the lipophobe in stabilizing the miniemulsion droplets against Ostwald ripening and is reduced after polymerization to Ag nanoparticles by gaseous hydrazine. Subsequently, the hybrid particles are transformed into smooth and stable films with thicknesses between 145 and 225 nm by simple drop casting and solvent annealing. The dispersions and films were thoroughly characterized by DLS, TEM, SEM, EDX, TGA, UV-vis spectroscopy, ICP-OES, XRD, AFM, and contact angle measurements. After immersion into water, the films did not show detectable leakage of silver, so they could be employed as dual-functional antifouling and antibacterial coatings. The synthesis of stable dispersions of hybrid colloids comprising copolymers of biocompatible 2-hydroxyethyl methacrylate (HEMA) and zwitterionic, biomimetic 2-methacryloyloxyethyl phosphorylcholine (MPC) incorporating antibacterial AgBF4 by inverse miniemulsion is described. The prepared hybrid colloids were designed to provide both antibacterial and antifouling properties for the formation of interesting, multifunctional films. The obtained particles had sizes in the range of 130–160 nm with two different weight ratios of MPC to HEMA (1:10 and 2:5) and AgBF4 contents between 0% and 15%. The silver salt takes on the role of the lipophobe in stabilizing the miniemulsion droplets against Ostwald ripening and is reduced after polymerization to Ag nanoparticles by gaseous hydrazine. Subsequently, the hybrid particles are transformed into smooth and stable films with thicknesses between 145 and 225 nm by simple drop casting and solvent annealing. The dispersions and films were thoroughly characterized by DLS, TEM, SEM, EDX, TGA, UV–vis spectroscopy, ICP-OES, XRD, AFM, and contact angle measurements. After immersion into water, the films did not show detectable leakage of silver, so they could be employed as dual-functional antifouling and antibacterial coatings. |
Author | Walter, Constanze Fuchs, Adrian V Landfester, Katharina Ziener, Ulrich |
AuthorAffiliation | Max Planck Institute for Polymer Research University of Ulm |
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Author_xml | – sequence: 1 givenname: Adrian V surname: Fuchs fullname: Fuchs, Adrian V – sequence: 2 givenname: Constanze surname: Walter fullname: Walter, Constanze – sequence: 3 givenname: Katharina surname: Landfester fullname: Landfester, Katharina – sequence: 4 givenname: Ulrich surname: Ziener fullname: Ziener, Ulrich email: ulrich.ziener@uni-ulm.de |
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Cites_doi | 10.1016/S0001-8686(02)00004-0 10.1016/j.reactfunctpolym.2010.10.013 10.1021/la904346j 10.1016/j.biomaterials.2007.12.032 10.1002/app.1969.070130815 10.1002/(SICI)1097-4636(199821)43:1<15::AID-JBM2>3.0.CO;2-P 10.1021/la1028004 10.1021/ma00009a064 10.1007/s11426-008-0106-4 10.1016/j.nantod.2010.12.009 10.1016/S1468-6996(03)00010-X 10.1292/jvms.70.167 10.1021/la0340807 10.1002/jbm.820261202 10.1088/0957-4484/16/10/059 10.1163/156856299X00658 10.1021/la202116s 10.1002/pat.637 10.1080/15321799208018377 10.1021/la701966d 10.1002/mawe.200700240 10.1007/12_2010_61 10.1021/la904380k 10.1016/j.colsurfb.2008.04.006 10.1002/9783527638482.ch28 10.1021/ma0356358 |
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Keywords | Water Atomic force microscopy Particle size Film Nanoparticle Immersion Design Particle Hema Synthesis Ostwald ripening Inverse Copolymer Hydrazine Scanning electron microscopy Annealing Thermogravimetry Polymerization Transition metal Contact angle Droplet X ray diffraction Colloid Dispersion Drop Thickness Silver Transmission electron microscopy Antibacterial agent Ultraviolet visible spectrometry |
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SubjectTerms | Biocompatible Materials Biomimetics Chemistry Colloidal state and disperse state Colloids Exact sciences and technology General and physical chemistry Methacrylates - chemistry Microscopy, Electron, Scanning Microscopy, Electron, Transmission Phosphorylcholine - analogs & derivatives Phosphorylcholine - chemistry Physical and chemical studies. Granulometry. Electrokinetic phenomena Polymethacrylic Acids Powder Diffraction Silver - chemistry Solid-liquid interface Surface physical chemistry Thermogravimetry |
Title | Biomimetic Silver-Containing Colloids of Poly(2-methacryloyloxyethyl phosphorylcholine) and Their Film-Formation Properties |
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