Cation Exchange Capacity of Phosphoric Acid and Lime Stabilized Montmorillonitic and Kaolinitic Soils
Studies on the chemically stabilized soils have shown that the effectiveness of treatment is largely dependent on soil’s natural environment. In this research, the time-dependent changes induced in permanent cation exchange capacity of lime and phosphoric acid treated soils, comprised mainly of mont...
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Published in | Geotechnical and geological engineering Vol. 30; no. 6; pp. 1435 - 1440 |
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Main Authors | , , |
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Language | English |
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01.12.2012
Springer Nature B.V |
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Abstract | Studies on the chemically stabilized soils have shown that the effectiveness of treatment is largely dependent on soil’s natural environment. In this research, the time-dependent changes induced in permanent cation exchange capacity of lime and phosphoric acid treated soils, comprised mainly of montmorillonite and kaolinite minerals, were investigated. Also, in order to study the relationship between the exchange capacity and acidity/alkalinity of pore water, pH measurements were performed on cured samples. Based on the collected data, it was found that the pH of stabilized soils showed a tendency for reaching soil’s natural pH with increasing curing time. In addition, the increase in number of broken bonds around the edges of soil particles and also the formation of cementitious compounds that acquired negative charges contributed to achieving higher CEC
p
values at longer curing periods. Nevertheless, the kaolinite mineral with pH-dependent structural properties, showed a rather limited behavior in the acidic medium. From engineering point of view, the lime treated samples revealed the highest degree of improvement with an approximately ten-fold strength increase in comparison to the natural soil over an 8 months curing period. |
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AbstractList | Studies on the chemically stabilized soils have shown that the effectiveness of treatment is largely dependent on soil’s natural environment. In this research, the time-dependent changes induced in permanent cation exchange capacity of lime and phosphoric acid treated soils, comprised mainly of montmorillonite and kaolinite minerals, were investigated. Also, in order to study the relationship between the exchange capacity and acidity/alkalinity of pore water, pH measurements were performed on cured samples. Based on the collected data, it was found that the pH of stabilized soils showed a tendency for reaching soil’s natural pH with increasing curing time. In addition, the increase in number of broken bonds around the edges of soil particles and also the formation of cementitious compounds that acquired negative charges contributed to achieving higher CECp values at longer curing periods. Nevertheless, the kaolinite mineral with pH-dependent structural properties, showed a rather limited behavior in the acidic medium. From engineering point of view, the lime treated samples revealed the highest degree of improvement with an approximately ten-fold strength increase in comparison to the natural soil over an 8 months curing period. Studies on the chemically stabilized soils have shown that the effectiveness of treatment is largely dependent on soil’s natural environment. In this research, the time-dependent changes induced in permanent cation exchange capacity of lime and phosphoric acid treated soils, comprised mainly of montmorillonite and kaolinite minerals, were investigated. Also, in order to study the relationship between the exchange capacity and acidity/alkalinity of pore water, pH measurements were performed on cured samples. Based on the collected data, it was found that the pH of stabilized soils showed a tendency for reaching soil’s natural pH with increasing curing time. In addition, the increase in number of broken bonds around the edges of soil particles and also the formation of cementitious compounds that acquired negative charges contributed to achieving higher CEC p values at longer curing periods. Nevertheless, the kaolinite mineral with pH-dependent structural properties, showed a rather limited behavior in the acidic medium. From engineering point of view, the lime treated samples revealed the highest degree of improvement with an approximately ten-fold strength increase in comparison to the natural soil over an 8 months curing period. |
Author | Kassim, Khairul Anuar Nur, Hadi Eisazadeh, Amin |
Author_xml | – sequence: 1 givenname: Amin surname: Eisazadeh fullname: Eisazadeh, Amin email: A.Eisazadeh@yahoo.com, aeisazadeh@utm.my organization: Geotechnic and Transportation Department, Faculty of Civil Engineering, Universiti Teknologi Malaysia – sequence: 2 givenname: Khairul Anuar surname: Kassim fullname: Kassim, Khairul Anuar organization: Geotechnic and Transportation Department, Faculty of Civil Engineering, Universiti Teknologi Malaysia – sequence: 3 givenname: Hadi surname: Nur fullname: Nur, Hadi organization: Ibnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia |
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CitedBy_id | crossref_primary_10_1016_j_clay_2015_11_011 crossref_primary_10_3390_su15097160 crossref_primary_10_1016_j_conbuildmat_2017_04_115 crossref_primary_10_1007_s10706_017_0341_6 crossref_primary_10_1007_s12205_021_1081_y crossref_primary_10_1016_j_clay_2018_02_001 crossref_primary_10_17221_733_2015_PSE crossref_primary_10_1007_s12517_020_05708_w crossref_primary_10_1061__ASCE_HZ_2153_5515_0000199 crossref_primary_10_1080_1064119X_2014_953232 crossref_primary_10_1016_j_matpr_2020_04_289 crossref_primary_10_1016_j_clay_2016_03_010 crossref_primary_10_1007_s10706_021_02008_2 |
Cites_doi | 10.1007/BF00422210 10.1016/0013-7952(96)00028-2 10.1016/0016-7061(84)90065-X 10.1061/(ASCE)1090-0241(1997)123:2(183) 10.1346/CCMN.1999.0470207 10.1061/(ASCE)0733-9410(1996)122:5(329) 10.1201/9781482274769 |
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Keywords | Phosphoric acid Lime Cation exchange capacity Stabilization Bentonite pH Kaolinite |
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References | CR2 Medina, Guida (CR11) 1995; 13 CR3 Mathew, Narasimha (CR10) 1997; 123 CR5 Ingles, Metcalf (CR8) 1972 Tan, Dowling (CR17) 1984; 32 Grim (CR6) 1968 Ma, Eggleton (CR9) 1999; 47 CR14 Tan (CR16) 2005 Narasimha, Rajasekaran (CR13) 1996; 122 Bell (CR1) 1996; 42 Ross (CR15) 1989 Mitchell, Soga (CR12) 2005 Grim, Guven (CR7) 1978 RE Grim (9553_CR7) 1978 J Medina (9553_CR11) 1995; 13 KH Tan (9553_CR16) 2005 9553_CR2 RE Grim (9553_CR6) 1968 9553_CR3 KH Tan (9553_CR17) 1984; 32 C Ma (9553_CR9) 1999; 47 RS Narasimha (9553_CR13) 1996; 122 OG Ingles (9553_CR8) 1972 JK Mitchell (9553_CR12) 2005 9553_CR14 PK Mathew (9553_CR10) 1997; 123 S Ross (9553_CR15) 1989 9553_CR5 FG Bell (9553_CR1) 1996; 42 |
References_xml | – volume: 13 start-page: 199 year: 1995 end-page: 216 ident: CR11 article-title: Stabilization of Lateritic soils with phosphoric acid publication-title: J Geotech Geol Eng doi: 10.1007/BF00422210 contributor: fullname: Guida – volume: 42 start-page: 223 issue: 4 year: 1996 end-page: 237 ident: CR1 article-title: Lime stabilization of clay minerals and soils publication-title: Eng Geol doi: 10.1016/0013-7952(96)00028-2 contributor: fullname: Bell – volume: 32 start-page: 89 year: 1984 end-page: 101 ident: CR17 article-title: Effect of organic matter on CEC due to permanent and variable charges in selected temperate region soils publication-title: Geoderma doi: 10.1016/0016-7061(84)90065-X contributor: fullname: Dowling – volume: 123 start-page: 183 issue: 2 year: 1997 end-page: 185 ident: CR10 article-title: Effect of lime on cation exchange capacity of marine clay publication-title: J Geotech Geoenviron Eng doi: 10.1061/(ASCE)1090-0241(1997)123:2(183) contributor: fullname: Narasimha – ident: CR3 – ident: CR14 – ident: CR2 – volume: 47 start-page: 174 issue: 2 year: 1999 end-page: 180 ident: CR9 article-title: Cation exchange capacity of kaolinite publication-title: Clays Clay Minerals doi: 10.1346/CCMN.1999.0470207 contributor: fullname: Eggleton – year: 2005 ident: CR12 publication-title: Fundamentals of soil behavior contributor: fullname: Soga – year: 1968 ident: CR6 publication-title: Clay Mineralogy contributor: fullname: Grim – start-page: 229 year: 1978 end-page: 232 ident: CR7 publication-title: Bentonites—geology, mineralogy, properties and uses contributor: fullname: Guven – ident: CR5 – year: 1989 ident: CR15 publication-title: Soil processes contributor: fullname: Ross – year: 1972 ident: CR8 publication-title: Soil stabilization—principles and practice contributor: fullname: Metcalf – year: 2005 ident: CR16 publication-title: Soil sampling, preparation and analysis contributor: fullname: Tan – volume: 122 start-page: 329 year: 1996 end-page: 336 ident: CR13 article-title: Reaction products formed in lime-stabilized marine clays publication-title: J Geotech Eng doi: 10.1061/(ASCE)0733-9410(1996)122:5(329) contributor: fullname: Rajasekaran – start-page: 229 volume-title: Bentonites—geology, mineralogy, properties and uses year: 1978 ident: 9553_CR7 contributor: fullname: RE Grim – volume: 42 start-page: 223 issue: 4 year: 1996 ident: 9553_CR1 publication-title: Eng Geol doi: 10.1016/0013-7952(96)00028-2 contributor: fullname: FG Bell – volume: 32 start-page: 89 year: 1984 ident: 9553_CR17 publication-title: Geoderma doi: 10.1016/0016-7061(84)90065-X contributor: fullname: KH Tan – volume: 123 start-page: 183 issue: 2 year: 1997 ident: 9553_CR10 publication-title: J Geotech Geoenviron Eng doi: 10.1061/(ASCE)1090-0241(1997)123:2(183) contributor: fullname: PK Mathew – volume-title: Fundamentals of soil behavior year: 2005 ident: 9553_CR12 contributor: fullname: JK Mitchell – volume-title: Soil processes year: 1989 ident: 9553_CR15 contributor: fullname: S Ross – volume: 13 start-page: 199 year: 1995 ident: 9553_CR11 publication-title: J Geotech Geol Eng doi: 10.1007/BF00422210 contributor: fullname: J Medina – volume-title: Soil stabilization—principles and practice year: 1972 ident: 9553_CR8 contributor: fullname: OG Ingles – ident: 9553_CR14 – volume: 122 start-page: 329 year: 1996 ident: 9553_CR13 publication-title: J Geotech Eng doi: 10.1061/(ASCE)0733-9410(1996)122:5(329) contributor: fullname: RS Narasimha – volume: 47 start-page: 174 issue: 2 year: 1999 ident: 9553_CR9 publication-title: Clays Clay Minerals doi: 10.1346/CCMN.1999.0470207 contributor: fullname: C Ma – volume-title: Clay Mineralogy year: 1968 ident: 9553_CR6 contributor: fullname: RE Grim – ident: 9553_CR2 – ident: 9553_CR5 – volume-title: Soil sampling, preparation and analysis year: 2005 ident: 9553_CR16 doi: 10.1201/9781482274769 contributor: fullname: KH Tan – ident: 9553_CR3 |
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SubjectTerms | Acidic soils Acidity Alkalinity Cation exchange Cation exchanging Cations Civil Engineering Curing Curing (processing) Earth and Environmental Science Earth Sciences Exchange capacity Geotechnical Engineering & Applied Earth Sciences Hydrogeology Ions Kaolinite Lime Lime soil stabilization Minerals Montmorillonite Montmorillonites Organic chemistry pH effects Phosphoric acid Pore water Soil Soil chemistry Soil investigations Soil lime Soil stabilization Soil treatment Technical Note Terrestrial Pollution Time dependence Waste Management/Waste Technology |
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Title | Cation Exchange Capacity of Phosphoric Acid and Lime Stabilized Montmorillonitic and Kaolinitic Soils |
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