Mössbauer study of bornite and chemical bonding in Fe-bearing sulphides
The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu 5 FeS 4 , specimen were reinvestigated between 295 and 4.2 K. There is no difference between the Neél temperature T N as determined by the Mössbauer effect or by the susceptibility measurements ( T N = 67.5 K). No additional param...
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| Published in | Physics and chemistry of minerals Vol. 45; no. 3; pp. 227 - 235 |
|---|---|
| Main Authors | , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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Berlin/Heidelberg
Springer Berlin Heidelberg
01.03.2018
Springer Nature B.V |
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| Abstract | The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu
5
FeS
4
, specimen were reinvestigated between 295 and 4.2 K. There is no difference between the Neél temperature
T
N
as determined by the Mössbauer effect or by the susceptibility measurements (
T
N
= 67.5 K). No additional paramagnetic doublet can be observed in the low-temperature MS spectra. The valence state of Fe is Fe
(3−
x
)+
caused by a partial electron transfer from the Cu
+
ions to the Fe
3+
ions which increases the shielding of the s-electrons by the d-electron density and by this increases the isomer shift to a value intermediate between tetrahedral high-spin Fe
2+
and tetrahedral high-spin Fe
3+
. |
|---|---|
| AbstractList | The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu5FeS4, specimen were reinvestigated between 295 and 4.2 K. There is no difference between the Neél temperature TN as determined by the Mössbauer effect or by the susceptibility measurements (TN = 67.5 K). No additional paramagnetic doublet can be observed in the low-temperature MS spectra. The valence state of Fe is Fe(3−x)+ caused by a partial electron transfer from the Cu+ ions to the Fe3+ ions which increases the shielding of the s-electrons by the d-electron density and by this increases the isomer shift to a value intermediate between tetrahedral high-spin Fe2+ and tetrahedral high-spin Fe3+. The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu 5 FeS 4 , specimen were reinvestigated between 295 and 4.2 K. There is no difference between the Neél temperature T N as determined by the Mössbauer effect or by the susceptibility measurements ( T N = 67.5 K). No additional paramagnetic doublet can be observed in the low-temperature MS spectra. The valence state of Fe is Fe (3− x )+ caused by a partial electron transfer from the Cu + ions to the Fe 3+ ions which increases the shielding of the s-electrons by the d-electron density and by this increases the isomer shift to a value intermediate between tetrahedral high-spin Fe 2+ and tetrahedral high-spin Fe 3+ . |
| Author | Montegrossi, G. Tippelt, G. Di Benedetto, F. Romanelli, M. Wagner, R. Khassanov, R. R. Sorace, L. Amthauer, G. Lottermoser, W. Gainov, R. R. Giaccherini, A. Borgheresi, M. Reissner, M. |
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| CitedBy_id | crossref_primary_10_1016_j_addma_2020_101035 crossref_primary_10_1039_D0RA09700D crossref_primary_10_1107_S2052520618009812 crossref_primary_10_1016_j_jallcom_2023_173280 crossref_primary_10_1021_acsomega_0c06052 crossref_primary_10_1039_D2TA00877G crossref_primary_10_1063_1_5119345 crossref_primary_10_3390_compounds3020027 |
| Cites_doi | 10.1107/S0567740875007376 10.1016/0022-4596(82)90028-7 10.1016/S0168-583X(97)00284-X 10.1016/0038-1098(96)00443-7 10.1016/0022-3697(77)90043-9 10.1007/s00269-007-0175-5 10.1016/j.elspec.2004.09.003 10.2138/am-2004-0408 10.1007/BF01163260 10.1007/s00269-003-0306-6 10.1039/C4EE02428A 10.1007/s00269-004-0430-y 10.1016/0038-1098(70)90473-4 10.1007/s00269-009-0341-z 10.1007/BF00203056 10.1103/PhysRevB.79.075115 10.1139/p81-069 10.1007/BF00401605 10.1103/PhysRevB.23.2350 10.1007/s10751-013-0980-9 |
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| Keywords | Chemical bond in sulphides Bornite Mössbauer spectroscopy Magnetic properties |
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| Snippet | The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu
5
FeS
4
, specimen were reinvestigated between 295 and 4.2 K. There is no difference... The Mössbauer spectra of a nearly stoichiometric natural bornite, Cu5FeS4, specimen were reinvestigated between 295 and 4.2 K. There is no difference between... |
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| StartPage | 227 |
| SubjectTerms | Bornite Chemical bonds Crystallography and Scattering Methods Earth and Environmental Science Earth Sciences Electron density Electron transfer Ferric ions Geochemistry Iron Low temperature Mineral Resources Mineralogy Mossbauer spectroscopy Organic chemistry Original Paper Shielding Valence |
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| Title | Mössbauer study of bornite and chemical bonding in Fe-bearing sulphides |
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