The Consideration of Different Effective Zeolite Based Catalysts and Heating Rate on the Pyrolysis of Styrene Butadiene Rubber (SBR) in a Stirred Reactor
The pyrolysis products as well as composition of the condensed products generated from Styrene Butadiene Rubber (SBR) degradation have been investigated with reference to different zeolite based catalysts. The effects of different catalysts containing used FCC, gallium promoted used FCC (Ga/FCC), HZ...
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Published in | Energy & fuels Vol. 31; no. 11; pp. 12358 - 12363 |
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Main Authors | , |
Format | Journal Article |
Language | English |
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American Chemical Society
16.11.2017
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Abstract | The pyrolysis products as well as composition of the condensed products generated from Styrene Butadiene Rubber (SBR) degradation have been investigated with reference to different zeolite based catalysts. The effects of different catalysts containing used FCC, gallium promoted used FCC (Ga/FCC), HZSM-5, and mordenite have been studied on the SBR degradation using a stirred semi-batch reactor. Main products obtained were light hydrocarbons within the gasoline range, though the Ga/FCC and used FCC tended to produce more condensed products with aromatics as the main product. Meanwhile, the nonisothermal mass losses of SBR were measured using a thermogravimetric analyzer (TGA) at heating rates of 5, 15, 30, 45, and 90 °C min–1 until the furnace wall temperature reached 600 °C. The TGA degradation trends of SBR were in between the TGAs of a usual plastic and polybutadiene rubber. Activation energies decreased by increasing the heating rate (154.7–131.5 kJ mol–1), although activation energy of the fast pyrolysis shows a significant decrease in comparison with the others. In slow pyrolysis, the double bonds in SBR chains could prepare the proper media for the cross-link mechanism, while phenyl groups boost the chain scission and unzipping mechanisms. In other words, the fast pyrolysis follows the chain scission and unzipping mechanisms along the most times of degradation. |
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AbstractList | The pyrolysis products as well as composition of the condensed products generated from Styrene Butadiene Rubber (SBR) degradation have been investigated with reference to different zeolite based catalysts. The effects of different catalysts containing used FCC, gallium promoted used FCC (Ga/FCC), HZSM-5, and mordenite have been studied on the SBR degradation using a stirred semi-batch reactor. Main products obtained were light hydrocarbons within the gasoline range, though the Ga/FCC and used FCC tended to produce more condensed products with aromatics as the main product. Meanwhile, the nonisothermal mass losses of SBR were measured using a thermogravimetric analyzer (TGA) at heating rates of 5, 15, 30, 45, and 90 °C min–1 until the furnace wall temperature reached 600 °C. The TGA degradation trends of SBR were in between the TGAs of a usual plastic and polybutadiene rubber. Activation energies decreased by increasing the heating rate (154.7–131.5 kJ mol–1), although activation energy of the fast pyrolysis shows a significant decrease in comparison with the others. In slow pyrolysis, the double bonds in SBR chains could prepare the proper media for the cross-link mechanism, while phenyl groups boost the chain scission and unzipping mechanisms. In other words, the fast pyrolysis follows the chain scission and unzipping mechanisms along the most times of degradation. |
Author | Nekoomanesh Haghighi, Mehdi Seifali Abbas-Abadi, Mehrdad |
AuthorAffiliation | Iran Polymer and Petrochemical Institute (IPPI) Polymerization Engineering |
AuthorAffiliation_xml | – name: Iran Polymer and Petrochemical Institute (IPPI) – name: Polymerization Engineering |
Author_xml | – sequence: 1 givenname: Mehrdad orcidid: 0000-0002-4909-3792 surname: Seifali Abbas-Abadi fullname: Seifali Abbas-Abadi, Mehrdad email: M.Seyfali@IPPI.ac.ir – sequence: 2 givenname: Mehdi surname: Nekoomanesh Haghighi fullname: Nekoomanesh Haghighi, Mehdi |
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CitedBy_id | crossref_primary_10_1002_cssc_202100889 crossref_primary_10_1007_s10973_020_09344_0 crossref_primary_10_1007_s10973_023_12364_1 crossref_primary_10_1080_15567036_2022_2136797 crossref_primary_10_1002_cssc_202200171 crossref_primary_10_1016_j_energy_2021_120381 crossref_primary_10_1016_j_fuel_2022_125236 crossref_primary_10_1016_j_energy_2021_121085 crossref_primary_10_1016_j_jaap_2018_05_001 crossref_primary_10_2139_ssrn_4109334 crossref_primary_10_1007_s10973_020_10431_5 crossref_primary_10_1016_j_jclepro_2020_120328 crossref_primary_10_1016_j_jclepro_2022_134036 crossref_primary_10_1016_j_fuel_2020_118322 crossref_primary_10_1016_j_rser_2020_109932 crossref_primary_10_1021_acs_energyfuels_9b02845 |
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Title | The Consideration of Different Effective Zeolite Based Catalysts and Heating Rate on the Pyrolysis of Styrene Butadiene Rubber (SBR) in a Stirred Reactor |
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